Preparation, Structure and Properties of Urethane-Containing Elastomers Based on Epoxy Terminal Oligomers

The effect of polyester oligoethylene adipate molecular weight, diisocyanate structure, and chain extender on the properties of epoxyurethane-based oligomer elastomers was studied in this research. Oligoethylene adipates were obtained via polycondensation of adipic acid and ethylene glycol. Epoxyure...

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Main Authors: Alexey Slobodinyuk, Vladimir Strelnikov, Valeriy Yu Senichev, Daria Slobodinyuk
Format: Article
Language:English
Published: MDPI AG 2022-01-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/3/524
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author Alexey Slobodinyuk
Vladimir Strelnikov
Valeriy Yu Senichev
Daria Slobodinyuk
author_facet Alexey Slobodinyuk
Vladimir Strelnikov
Valeriy Yu Senichev
Daria Slobodinyuk
author_sort Alexey Slobodinyuk
collection DOAJ
description The effect of polyester oligoethylene adipate molecular weight, diisocyanate structure, and chain extender on the properties of epoxyurethane-based oligomer elastomers was studied in this research. Oligoethylene adipates were obtained via polycondensation of adipic acid and ethylene glycol. Epoxyurethane oligomers were synthesized according to a two-step route with an oligodiisocyanate as an intermediate product. The elastomers with hard urethane hydroxyl blocks were synthesized from oligodiisocyanates. The deformation and strength properties of the elastomers were studied.
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spelling doaj.art-37d18525733a463fa71ab0884d6fea462023-11-23T17:35:15ZengMDPI AGPolymers2073-43602022-01-0114352410.3390/polym14030524Preparation, Structure and Properties of Urethane-Containing Elastomers Based on Epoxy Terminal OligomersAlexey Slobodinyuk0Vladimir Strelnikov1Valeriy Yu Senichev2Daria Slobodinyuk3Institute of Technical Chemistry Ural Branch of the Russian Academy of Sciences, Ac. Korolev 3, 614130 Perm, RussiaInstitute of Technical Chemistry Ural Branch of the Russian Academy of Sciences, Ac. Korolev 3, 614130 Perm, RussiaInstitute of Technical Chemistry Ural Branch of the Russian Academy of Sciences, Ac. Korolev 3, 614130 Perm, RussiaInstitute of Technical Chemistry Ural Branch of the Russian Academy of Sciences, Ac. Korolev 3, 614130 Perm, RussiaThe effect of polyester oligoethylene adipate molecular weight, diisocyanate structure, and chain extender on the properties of epoxyurethane-based oligomer elastomers was studied in this research. Oligoethylene adipates were obtained via polycondensation of adipic acid and ethylene glycol. Epoxyurethane oligomers were synthesized according to a two-step route with an oligodiisocyanate as an intermediate product. The elastomers with hard urethane hydroxyl blocks were synthesized from oligodiisocyanates. The deformation and strength properties of the elastomers were studied.https://www.mdpi.com/2073-4360/14/3/524epoxy terminal oligomersurethane elastomersstructurehard and soft segmentsFTIRNMR
spellingShingle Alexey Slobodinyuk
Vladimir Strelnikov
Valeriy Yu Senichev
Daria Slobodinyuk
Preparation, Structure and Properties of Urethane-Containing Elastomers Based on Epoxy Terminal Oligomers
Polymers
epoxy terminal oligomers
urethane elastomers
structure
hard and soft segments
FTIR
NMR
title Preparation, Structure and Properties of Urethane-Containing Elastomers Based on Epoxy Terminal Oligomers
title_full Preparation, Structure and Properties of Urethane-Containing Elastomers Based on Epoxy Terminal Oligomers
title_fullStr Preparation, Structure and Properties of Urethane-Containing Elastomers Based on Epoxy Terminal Oligomers
title_full_unstemmed Preparation, Structure and Properties of Urethane-Containing Elastomers Based on Epoxy Terminal Oligomers
title_short Preparation, Structure and Properties of Urethane-Containing Elastomers Based on Epoxy Terminal Oligomers
title_sort preparation structure and properties of urethane containing elastomers based on epoxy terminal oligomers
topic epoxy terminal oligomers
urethane elastomers
structure
hard and soft segments
FTIR
NMR
url https://www.mdpi.com/2073-4360/14/3/524
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