Poly[μ6-adipato-diaquadi-μ2-oxalato-digadolinium(III)]
In the centrosymmetric title compound, [Gd2(C6H8O4)(C2O4)2(H2O)2]n, the Gd3+ cations are each coordinated by nine O atoms, three from adipate anions, two from oxalate anions and one from an aqua ligand, completing a distorted tricapped trigonal-prismatic geometry. These tricapped trigonal prisms are...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810036111 |
| _version_ | 1818945563557625856 |
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| author | Chun-Xiang Wang Zhi-Feng Li |
| author_facet | Chun-Xiang Wang Zhi-Feng Li |
| author_sort | Chun-Xiang Wang |
| collection | DOAJ |
| description | In the centrosymmetric title compound, [Gd2(C6H8O4)(C2O4)2(H2O)2]n, the Gd3+ cations are each coordinated by nine O atoms, three from adipate anions, two from oxalate anions and one from an aqua ligand, completing a distorted tricapped trigonal-prismatic geometry. These tricapped trigonal prisms are bridged by the adipate ligands, generating layers lying parallel to (010). The coordination polymer layers are linked into a three-dimensional framework by the rigid oxalate ligands. The adipate and oxalate ions are all located on centers of inversion. A part of the adipate anion is disordered over two positions in a 0.75:0.25 ratio. |
| first_indexed | 2024-12-20T08:01:06Z |
| format | Article |
| id | doaj.art-37d48979890f4c46af26d65f9097707b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T08:01:06Z |
| publishDate | 2010-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-37d48979890f4c46af26d65f9097707b2022-12-21T19:47:31ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1263m126310.1107/S1600536810036111Poly[μ6-adipato-diaquadi-μ2-oxalato-digadolinium(III)]Chun-Xiang WangZhi-Feng LiIn the centrosymmetric title compound, [Gd2(C6H8O4)(C2O4)2(H2O)2]n, the Gd3+ cations are each coordinated by nine O atoms, three from adipate anions, two from oxalate anions and one from an aqua ligand, completing a distorted tricapped trigonal-prismatic geometry. These tricapped trigonal prisms are bridged by the adipate ligands, generating layers lying parallel to (010). The coordination polymer layers are linked into a three-dimensional framework by the rigid oxalate ligands. The adipate and oxalate ions are all located on centers of inversion. A part of the adipate anion is disordered over two positions in a 0.75:0.25 ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536810036111 |
| spellingShingle | Chun-Xiang Wang Zhi-Feng Li Poly[μ6-adipato-diaquadi-μ2-oxalato-digadolinium(III)] Acta Crystallographica Section E |
| title | Poly[μ6-adipato-diaquadi-μ2-oxalato-digadolinium(III)] |
| title_full | Poly[μ6-adipato-diaquadi-μ2-oxalato-digadolinium(III)] |
| title_fullStr | Poly[μ6-adipato-diaquadi-μ2-oxalato-digadolinium(III)] |
| title_full_unstemmed | Poly[μ6-adipato-diaquadi-μ2-oxalato-digadolinium(III)] |
| title_short | Poly[μ6-adipato-diaquadi-μ2-oxalato-digadolinium(III)] |
| title_sort | poly amp 956 6 adipato diaquadi amp 956 2 oxalato digadolinium iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810036111 |
| work_keys_str_mv | AT chunxiangwang polyamp9566adipatodiaquadiamp9562oxalatodigadoliniumiii AT zhifengli polyamp9566adipatodiaquadiamp9562oxalatodigadoliniumiii |