Effect of shear flow on optical anisotropic film of chromonic liquid crystal

The effect of shear flow on an optical anisotropic film of chromonic liquid crystal by use of applicator was investigated. Some chromonic dyes form a rod like aggregation in an aqueous solution and change to a chromonic liquid crystal in a certain concentration and temperature of the solution. When...

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Main Authors: Yumiko YOSHITAKE, Tsutomu TAKAHASHI
Format: Article
Language:Japanese
Published: The Japan Society of Mechanical Engineers 2015-03-01
Series:Nihon Kikai Gakkai ronbunshu
Subjects:
Online Access:https://www.jstage.jst.go.jp/article/transjsme/81/823/81_14-00616/_pdf/-char/en
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author Yumiko YOSHITAKE
Tsutomu TAKAHASHI
author_facet Yumiko YOSHITAKE
Tsutomu TAKAHASHI
author_sort Yumiko YOSHITAKE
collection DOAJ
description The effect of shear flow on an optical anisotropic film of chromonic liquid crystal by use of applicator was investigated. Some chromonic dyes form a rod like aggregation in an aqueous solution and change to a chromonic liquid crystal in a certain concentration and temperature of the solution. When the chromonic liquid crystal is applied to a glass substrate by an applicator, the aggregates in the chromonic liquid crystal are oriented in one direction in the thin film, and it exhibits an optical anisotropy such as birefringence and dicrhoism. The orientation process of the aggregates during application, however, is still unknown in detail. The application process, especially shear region, was considered to be important to make the optical anisotropy film having a uniform and high dichroism. The shear flow would have the multi-domain collapsed and transformed to mono-domain. In the present experiment, small texture disappeared when the chromonic liquid crystal under the shear flow was observed by microscope, however the optically measured dichroism and birefringence by the laser did not vary even though the shear rate changed widely. The birefringence is ten times larger at the exit of applicator, which is elongation region, than the one just under the applicator. The shear flow shows limited effectiveness against the molecular orientation. It would be the elongation flow that is more effective to produce a good optical anisotropic film.
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spelling doaj.art-37d7176f70a945c2aabe1427342b8c442022-12-22T04:35:29ZjpnThe Japan Society of Mechanical EngineersNihon Kikai Gakkai ronbunshu2187-97612015-03-018182314-0061614-0061610.1299/transjsme.14-00616transjsmeEffect of shear flow on optical anisotropic film of chromonic liquid crystalYumiko YOSHITAKE0Tsutomu TAKAHASHI1Department of Mechanical Engineering, Nagaoka University of TechnologyDepartment of Mechanical Engineering, Nagaoka University of TechnologyThe effect of shear flow on an optical anisotropic film of chromonic liquid crystal by use of applicator was investigated. Some chromonic dyes form a rod like aggregation in an aqueous solution and change to a chromonic liquid crystal in a certain concentration and temperature of the solution. When the chromonic liquid crystal is applied to a glass substrate by an applicator, the aggregates in the chromonic liquid crystal are oriented in one direction in the thin film, and it exhibits an optical anisotropy such as birefringence and dicrhoism. The orientation process of the aggregates during application, however, is still unknown in detail. The application process, especially shear region, was considered to be important to make the optical anisotropy film having a uniform and high dichroism. The shear flow would have the multi-domain collapsed and transformed to mono-domain. In the present experiment, small texture disappeared when the chromonic liquid crystal under the shear flow was observed by microscope, however the optically measured dichroism and birefringence by the laser did not vary even though the shear rate changed widely. The birefringence is ten times larger at the exit of applicator, which is elongation region, than the one just under the applicator. The shear flow shows limited effectiveness against the molecular orientation. It would be the elongation flow that is more effective to produce a good optical anisotropic film.https://www.jstage.jst.go.jp/article/transjsme/81/823/81_14-00616/_pdf/-char/enapplicationchromonic liquid rystalpolarized filmshear flowoptical anisotropy
spellingShingle Yumiko YOSHITAKE
Tsutomu TAKAHASHI
Effect of shear flow on optical anisotropic film of chromonic liquid crystal
Nihon Kikai Gakkai ronbunshu
application
chromonic liquid rystal
polarized film
shear flow
optical anisotropy
title Effect of shear flow on optical anisotropic film of chromonic liquid crystal
title_full Effect of shear flow on optical anisotropic film of chromonic liquid crystal
title_fullStr Effect of shear flow on optical anisotropic film of chromonic liquid crystal
title_full_unstemmed Effect of shear flow on optical anisotropic film of chromonic liquid crystal
title_short Effect of shear flow on optical anisotropic film of chromonic liquid crystal
title_sort effect of shear flow on optical anisotropic film of chromonic liquid crystal
topic application
chromonic liquid rystal
polarized film
shear flow
optical anisotropy
url https://www.jstage.jst.go.jp/article/transjsme/81/823/81_14-00616/_pdf/-char/en
work_keys_str_mv AT yumikoyoshitake effectofshearflowonopticalanisotropicfilmofchromonicliquidcrystal
AT tsutomutakahashi effectofshearflowonopticalanisotropicfilmofchromonicliquidcrystal