Modelling Spectral Unmixing of Geological Mixtures: An Experimental Study Using Rock Samples

Spectral unmixing of geological mixtures, such as rocks, is a challenging inversion problem because of nonlinear interactions of light with the intimately mixed minerals at a microscopic scale. The fine-scale mixing of minerals in rocks limits the sensor’s ability to identify pure mineral endmembers...

Full description

Bibliographic Details
Main Authors: Maitreya Mohan Sahoo, R. Kalimuthu, Arun PV, Alok Porwal, Shibu K. Mathew
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Remote Sensing
Subjects:
Online Access:https://www.mdpi.com/2072-4292/15/13/3300
_version_ 1827734548646985728
author Maitreya Mohan Sahoo
R. Kalimuthu
Arun PV
Alok Porwal
Shibu K. Mathew
author_facet Maitreya Mohan Sahoo
R. Kalimuthu
Arun PV
Alok Porwal
Shibu K. Mathew
author_sort Maitreya Mohan Sahoo
collection DOAJ
description Spectral unmixing of geological mixtures, such as rocks, is a challenging inversion problem because of nonlinear interactions of light with the intimately mixed minerals at a microscopic scale. The fine-scale mixing of minerals in rocks limits the sensor’s ability to identify pure mineral endmembers and spectrally resolve these constituents within a given spatial resolution. In this study, we attempt to model the spectral unmixing of two rocks, namely, serpentinite and granite, by acquiring their hyperspectral images in a controlled environment, having uniform illumination, using a laboratory-based imaging spectroradiometer. The endmember spectra of each rock were identified by comparing a limited set of pure hyperspectral image pixels with the constituent minerals of the rocks based on their diagnostic spectral features. A series of spectral unmixing paradigms for explaining geological mixtures, including those ranging from simple physics-based light interaction models (linear, bilinear, and polynomial models) to classification-based models (support vector machines (SVMs) and half Siamese network (HSN)), were tested to estimate the fractional abundances of the endmembers at each pixel position of the image. The analysis of the results of the spectral unmixing algorithms using the ground truth abundance maps and actual mineralogical composition of the rock samples (estimated using X-ray diffraction (XRD) analysis) indicate a better performance of the pure pixel-guided HSN model in comparison to the linear, bilinear, polynomial, and SVM-based unmixing approaches. The HSN-based approach yielded reduced errors of abundance estimation, image reconstruction, and mineralogical composition for serpentinite and granite. With its ability to train using limited pure pixels, the half-Siamese network model has a scope for spectrally unmixing rock samples of varying mineralogical composition and grain sizes. Hence, HSN-based approaches effectively address the modelling of nonlinear mixing in geological mixtures.
first_indexed 2024-03-11T01:30:10Z
format Article
id doaj.art-380285b09190478a96b4f58fcab5b30c
institution Directory Open Access Journal
issn 2072-4292
language English
last_indexed 2024-03-11T01:30:10Z
publishDate 2023-06-01
publisher MDPI AG
record_format Article
series Remote Sensing
spelling doaj.art-380285b09190478a96b4f58fcab5b30c2023-11-18T17:24:15ZengMDPI AGRemote Sensing2072-42922023-06-011513330010.3390/rs15133300Modelling Spectral Unmixing of Geological Mixtures: An Experimental Study Using Rock SamplesMaitreya Mohan Sahoo0R. Kalimuthu1Arun PV2Alok Porwal3Shibu K. Mathew4Centre of Studies in Resources Engineering, Indian Institute of Technology Bombay, Mumbai 400076, IndiaCentre of Studies in Resources Engineering, Indian Institute of Technology Bombay, Mumbai 400076, IndiaIndian Institute of Information Technology, Sri City 517646, IndiaCentre of Studies in Resources Engineering, Indian Institute of Technology Bombay, Mumbai 400076, IndiaUdaipur Solar Observatory, Physical Research Laboratory, Udaipur 313001, IndiaSpectral unmixing of geological mixtures, such as rocks, is a challenging inversion problem because of nonlinear interactions of light with the intimately mixed minerals at a microscopic scale. The fine-scale mixing of minerals in rocks limits the sensor’s ability to identify pure mineral endmembers and spectrally resolve these constituents within a given spatial resolution. In this study, we attempt to model the spectral unmixing of two rocks, namely, serpentinite and granite, by acquiring their hyperspectral images in a controlled environment, having uniform illumination, using a laboratory-based imaging spectroradiometer. The endmember spectra of each rock were identified by comparing a limited set of pure hyperspectral image pixels with the constituent minerals of the rocks based on their diagnostic spectral features. A series of spectral unmixing paradigms for explaining geological mixtures, including those ranging from simple physics-based light interaction models (linear, bilinear, and polynomial models) to classification-based models (support vector machines (SVMs) and half Siamese network (HSN)), were tested to estimate the fractional abundances of the endmembers at each pixel position of the image. The analysis of the results of the spectral unmixing algorithms using the ground truth abundance maps and actual mineralogical composition of the rock samples (estimated using X-ray diffraction (XRD) analysis) indicate a better performance of the pure pixel-guided HSN model in comparison to the linear, bilinear, polynomial, and SVM-based unmixing approaches. The HSN-based approach yielded reduced errors of abundance estimation, image reconstruction, and mineralogical composition for serpentinite and granite. With its ability to train using limited pure pixels, the half-Siamese network model has a scope for spectrally unmixing rock samples of varying mineralogical composition and grain sizes. Hence, HSN-based approaches effectively address the modelling of nonlinear mixing in geological mixtures.https://www.mdpi.com/2072-4292/15/13/3300spectral unmixinggeological mixturesrockslimited pure pixels
spellingShingle Maitreya Mohan Sahoo
R. Kalimuthu
Arun PV
Alok Porwal
Shibu K. Mathew
Modelling Spectral Unmixing of Geological Mixtures: An Experimental Study Using Rock Samples
Remote Sensing
spectral unmixing
geological mixtures
rocks
limited pure pixels
title Modelling Spectral Unmixing of Geological Mixtures: An Experimental Study Using Rock Samples
title_full Modelling Spectral Unmixing of Geological Mixtures: An Experimental Study Using Rock Samples
title_fullStr Modelling Spectral Unmixing of Geological Mixtures: An Experimental Study Using Rock Samples
title_full_unstemmed Modelling Spectral Unmixing of Geological Mixtures: An Experimental Study Using Rock Samples
title_short Modelling Spectral Unmixing of Geological Mixtures: An Experimental Study Using Rock Samples
title_sort modelling spectral unmixing of geological mixtures an experimental study using rock samples
topic spectral unmixing
geological mixtures
rocks
limited pure pixels
url https://www.mdpi.com/2072-4292/15/13/3300
work_keys_str_mv AT maitreyamohansahoo modellingspectralunmixingofgeologicalmixturesanexperimentalstudyusingrocksamples
AT rkalimuthu modellingspectralunmixingofgeologicalmixturesanexperimentalstudyusingrocksamples
AT arunpv modellingspectralunmixingofgeologicalmixturesanexperimentalstudyusingrocksamples
AT alokporwal modellingspectralunmixingofgeologicalmixturesanexperimentalstudyusingrocksamples
AT shibukmathew modellingspectralunmixingofgeologicalmixturesanexperimentalstudyusingrocksamples