A formulação ab-initio da segunda lei da termodinâmica The ab-initio formulation of the second law of thermodynamics

<abstract language="eng">This paper deals with Carathédory's formulation of the second law of thermodynamics. The material is presented in a didatical way, which allows a second year undergraduate student to follow the formalism. An application is made to an ideal gas with two i...

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Bibliographic Details
Main Author: J. P. Braga
Format: Article
Language:English
Published: Sociedade Brasileira de Química 1998-07-01
Series:Química Nova
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421998000400023
Description
Summary:<abstract language="eng">This paper deals with Carathédory's formulation of the second law of thermodynamics. The material is presented in a didatical way, which allows a second year undergraduate student to follow the formalism. An application is made to an ideal gas with two independent variables. A criticism to Carnot formulation of the second law and an investigation of the historical origins of the Carathéodory formalism are also presented.
ISSN:0100-4042
1678-7064