Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) diheptanoate dihydrate
The CuII atom in the title salt, [Cu(C10H24N4)(H2O)2][CH3(CH2)5CO2]2·2H2O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a tetragonally Jahn–Teller-distorted octahedral geometry. The Cu...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810025687 |
| _version_ | 1818776250626342912 |
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| author | Nur Syamimi Ahmad Tajidi Norbani Abdullah Zainudin Arifin Kong Wai Tan Seik Weng Ng |
| author_facet | Nur Syamimi Ahmad Tajidi Norbani Abdullah Zainudin Arifin Kong Wai Tan Seik Weng Ng |
| author_sort | Nur Syamimi Ahmad Tajidi |
| collection | DOAJ |
| description | The CuII atom in the title salt, [Cu(C10H24N4)(H2O)2][CH3(CH2)5CO2]2·2H2O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a tetragonally Jahn–Teller-distorted octahedral geometry. The CuII atom lies on a center of inversion. The cations, anions and uncoordinated water molecules are linked by N—H...O and O—H...O hydrogen bonds, forming a layer structure parallel to (100). The alkyl chain of the anion is disordered over two positions in a 0.82 (1):0.18 (1) ratio. |
| first_indexed | 2024-12-18T11:09:57Z |
| format | Article |
| id | doaj.art-387be95bf2eb43beb8bdc09590575daa |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T11:09:57Z |
| publishDate | 2010-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-387be95bf2eb43beb8bdc09590575daa2022-12-21T21:10:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m887m88710.1107/S1600536810025687Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) diheptanoate dihydrateNur Syamimi Ahmad TajidiNorbani AbdullahZainudin ArifinKong Wai TanSeik Weng NgThe CuII atom in the title salt, [Cu(C10H24N4)(H2O)2][CH3(CH2)5CO2]2·2H2O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a tetragonally Jahn–Teller-distorted octahedral geometry. The CuII atom lies on a center of inversion. The cations, anions and uncoordinated water molecules are linked by N—H...O and O—H...O hydrogen bonds, forming a layer structure parallel to (100). The alkyl chain of the anion is disordered over two positions in a 0.82 (1):0.18 (1) ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536810025687 |
| spellingShingle | Nur Syamimi Ahmad Tajidi Norbani Abdullah Zainudin Arifin Kong Wai Tan Seik Weng Ng Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) diheptanoate dihydrate Acta Crystallographica Section E |
| title | Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) diheptanoate dihydrate |
| title_full | Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) diheptanoate dihydrate |
| title_fullStr | Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) diheptanoate dihydrate |
| title_full_unstemmed | Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) diheptanoate dihydrate |
| title_short | Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) diheptanoate dihydrate |
| title_sort | diaqua 1 4 8 11 tetraazacyclotetradecane amp 954 4n1 n4 n8 n11 copper ii diheptanoate dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810025687 |
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