Designed Synthesis of Three-Dimensional Covalent Organic Frameworks: A Mini Review
Covalent organic frameworks are porous crystals of polymers with two categories based on their covalent linkages: layered structures with two dimensions and networks with three-dimensional structures. Three-dimensional covalent organic frameworks are porous, have large surface areas, and have highly...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-02-01
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| Series: | Polymers |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2073-4360/15/4/887 |
| _version_ | 1797618494573903872 |
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| author | Pham Thi Phan Qui Thanh Hoai Ta Phan Khanh Thinh Nguyen |
| author_facet | Pham Thi Phan Qui Thanh Hoai Ta Phan Khanh Thinh Nguyen |
| author_sort | Pham Thi Phan |
| collection | DOAJ |
| description | Covalent organic frameworks are porous crystals of polymers with two categories based on their covalent linkages: layered structures with two dimensions and networks with three-dimensional structures. Three-dimensional covalent organic frameworks are porous, have large surface areas, and have highly ordered structures. Since covalent bonds are responsible for the formation of three-dimensional covalent organic frameworks, their synthesis has been a challenge and different structures are generated during the synthesis. Moreover, initially, their topologies have been limited to dia, ctn, and bor which are formed by the condensation of triangular or linear units with tetrahedral units. There are very few building units available for their synthesis. Finally, the future perspective of 3D COFs has been designated for the future development of three-dimensional covalent organic frameworks. |
| first_indexed | 2024-03-11T08:13:35Z |
| format | Article |
| id | doaj.art-388c3336bb504dc6bd1869c536c6645b |
| institution | Directory Open Access Journal |
| issn | 2073-4360 |
| language | English |
| last_indexed | 2024-03-11T08:13:35Z |
| publishDate | 2023-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Polymers |
| spelling | doaj.art-388c3336bb504dc6bd1869c536c6645b2023-11-16T22:51:17ZengMDPI AGPolymers2073-43602023-02-0115488710.3390/polym15040887Designed Synthesis of Three-Dimensional Covalent Organic Frameworks: A Mini ReviewPham Thi Phan0Qui Thanh Hoai Ta1Phan Khanh Thinh Nguyen2Faculty of Food Science and Engineering, Lac Hong University, Bien Hoa 810000, VietnamDepartment of Physics, Gachon University, 1342 Seongnamdaero, Sujeong-gu, Seongnam-si 13120, Gyeonggi-do, Republic of KoreaDepartment of Chemical and Biological Engineering, Gachon University, 1342 Seongnamdaero, Sujeong-gu, Seongnam-si 13120, Gyeonggi-do, Republic of KoreaCovalent organic frameworks are porous crystals of polymers with two categories based on their covalent linkages: layered structures with two dimensions and networks with three-dimensional structures. Three-dimensional covalent organic frameworks are porous, have large surface areas, and have highly ordered structures. Since covalent bonds are responsible for the formation of three-dimensional covalent organic frameworks, their synthesis has been a challenge and different structures are generated during the synthesis. Moreover, initially, their topologies have been limited to dia, ctn, and bor which are formed by the condensation of triangular or linear units with tetrahedral units. There are very few building units available for their synthesis. Finally, the future perspective of 3D COFs has been designated for the future development of three-dimensional covalent organic frameworks.https://www.mdpi.com/2073-4360/15/4/887covalent organic frameworksbuilding blocksoctahedral unitsgrowth mechanism |
| spellingShingle | Pham Thi Phan Qui Thanh Hoai Ta Phan Khanh Thinh Nguyen Designed Synthesis of Three-Dimensional Covalent Organic Frameworks: A Mini Review Polymers covalent organic frameworks building blocks octahedral units growth mechanism |
| title | Designed Synthesis of Three-Dimensional Covalent Organic Frameworks: A Mini Review |
| title_full | Designed Synthesis of Three-Dimensional Covalent Organic Frameworks: A Mini Review |
| title_fullStr | Designed Synthesis of Three-Dimensional Covalent Organic Frameworks: A Mini Review |
| title_full_unstemmed | Designed Synthesis of Three-Dimensional Covalent Organic Frameworks: A Mini Review |
| title_short | Designed Synthesis of Three-Dimensional Covalent Organic Frameworks: A Mini Review |
| title_sort | designed synthesis of three dimensional covalent organic frameworks a mini review |
| topic | covalent organic frameworks building blocks octahedral units growth mechanism |
| url | https://www.mdpi.com/2073-4360/15/4/887 |
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