Geochemical Characteristics of Typical Karst Soil Profiles in Anhui Province, Southeastern China

The geographical distributions of Cd and several other heavy metals (HMs) (Hg, Cu, Ni, Pb, Zn, Cr, As, Co, and V) were characterized in 90 (<i>p</i> > 0.05) terra rossa samples across the Anhui karst area. Significant enrichment of HM was observed in this soil, mainly associated with...

Full description

Bibliographic Details
Main Authors: Wenbing Ji, Yuanyuan Lu, Min Yang, Jian Wang, Xiaoyu Zhang, Caiyi Zhao, Bing Xia, Yunjin Wu, Rongrong Ying
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Agronomy
Subjects:
Online Access:https://www.mdpi.com/2073-4395/13/4/1067
_version_ 1827746244592664576
author Wenbing Ji
Yuanyuan Lu
Min Yang
Jian Wang
Xiaoyu Zhang
Caiyi Zhao
Bing Xia
Yunjin Wu
Rongrong Ying
author_facet Wenbing Ji
Yuanyuan Lu
Min Yang
Jian Wang
Xiaoyu Zhang
Caiyi Zhao
Bing Xia
Yunjin Wu
Rongrong Ying
author_sort Wenbing Ji
collection DOAJ
description The geographical distributions of Cd and several other heavy metals (HMs) (Hg, Cu, Ni, Pb, Zn, Cr, As, Co, and V) were characterized in 90 (<i>p</i> > 0.05) terra rossa samples across the Anhui karst area. Significant enrichment of HM was observed in this soil, mainly associated with the weathering of Cd-enriched carbonate rocks. Then, this enrichment was developed in 31 profiles. Our investigations revealed pedogenic processes as the dominant factors accounting for the enrichment of Hg, Cu, Ni, As, Co, and V. We also observed that all soil samples had a silty clay texture, with a pH scope of 4.08–8.04 and a median value of 6.50. In addition, the soil samples had relatively high saturation, with basic cations over 6.68%. The enrichment of the HMs based on their distinct factors were as follows: Cd (3.92) > As (2.55) > Zn (1.62) > Ni (1.50) > Cu (1.47) > Pb (1.47) > V (1.43) > Cr (1.23) > Co (1.19) > Hg (1.12). Finally, terra rossa samples derived from carbonate rocks were categorized as Cambisols, Luvisols, and Regosols. The soil profiles of Cambisols and Luvisolsis were less developed, so the HM concentrations were relatively low. The Regosols profile contained the highest total Cd concentration and exhibited a higher capacity to immobilize Cd compared with other soil profiles. Regosols are also characterized by high pH values (scope of 7.05 to 8.22, with an average value of 7.56). The contents of HM also exhibited minor changes across the Regosol, Cambisol, and Luvisol profiles, implying that the karst development degrees of weathering in Anhui were relatively low.
first_indexed 2024-03-11T05:19:43Z
format Article
id doaj.art-3891b6b516f349f1b649ab070411028f
institution Directory Open Access Journal
issn 2073-4395
language English
last_indexed 2024-03-11T05:19:43Z
publishDate 2023-04-01
publisher MDPI AG
record_format Article
series Agronomy
spelling doaj.art-3891b6b516f349f1b649ab070411028f2023-11-17T17:57:07ZengMDPI AGAgronomy2073-43952023-04-01134106710.3390/agronomy13041067Geochemical Characteristics of Typical Karst Soil Profiles in Anhui Province, Southeastern ChinaWenbing Ji0Yuanyuan Lu1Min Yang2Jian Wang3Xiaoyu Zhang4Caiyi Zhao5Bing Xia6Yunjin Wu7Rongrong Ying8Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, ChinaNanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, ChinaNanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, ChinaNanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, ChinaNanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, ChinaNanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, ChinaNanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, ChinaNanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, ChinaNanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, ChinaThe geographical distributions of Cd and several other heavy metals (HMs) (Hg, Cu, Ni, Pb, Zn, Cr, As, Co, and V) were characterized in 90 (<i>p</i> > 0.05) terra rossa samples across the Anhui karst area. Significant enrichment of HM was observed in this soil, mainly associated with the weathering of Cd-enriched carbonate rocks. Then, this enrichment was developed in 31 profiles. Our investigations revealed pedogenic processes as the dominant factors accounting for the enrichment of Hg, Cu, Ni, As, Co, and V. We also observed that all soil samples had a silty clay texture, with a pH scope of 4.08–8.04 and a median value of 6.50. In addition, the soil samples had relatively high saturation, with basic cations over 6.68%. The enrichment of the HMs based on their distinct factors were as follows: Cd (3.92) > As (2.55) > Zn (1.62) > Ni (1.50) > Cu (1.47) > Pb (1.47) > V (1.43) > Cr (1.23) > Co (1.19) > Hg (1.12). Finally, terra rossa samples derived from carbonate rocks were categorized as Cambisols, Luvisols, and Regosols. The soil profiles of Cambisols and Luvisolsis were less developed, so the HM concentrations were relatively low. The Regosols profile contained the highest total Cd concentration and exhibited a higher capacity to immobilize Cd compared with other soil profiles. Regosols are also characterized by high pH values (scope of 7.05 to 8.22, with an average value of 7.56). The contents of HM also exhibited minor changes across the Regosol, Cambisol, and Luvisol profiles, implying that the karst development degrees of weathering in Anhui were relatively low.https://www.mdpi.com/2073-4395/13/4/1067karst areasAnhui Provinceheavy metals (HM)geochemical characteristicsenrichment factors
spellingShingle Wenbing Ji
Yuanyuan Lu
Min Yang
Jian Wang
Xiaoyu Zhang
Caiyi Zhao
Bing Xia
Yunjin Wu
Rongrong Ying
Geochemical Characteristics of Typical Karst Soil Profiles in Anhui Province, Southeastern China
Agronomy
karst areas
Anhui Province
heavy metals (HM)
geochemical characteristics
enrichment factors
title Geochemical Characteristics of Typical Karst Soil Profiles in Anhui Province, Southeastern China
title_full Geochemical Characteristics of Typical Karst Soil Profiles in Anhui Province, Southeastern China
title_fullStr Geochemical Characteristics of Typical Karst Soil Profiles in Anhui Province, Southeastern China
title_full_unstemmed Geochemical Characteristics of Typical Karst Soil Profiles in Anhui Province, Southeastern China
title_short Geochemical Characteristics of Typical Karst Soil Profiles in Anhui Province, Southeastern China
title_sort geochemical characteristics of typical karst soil profiles in anhui province southeastern china
topic karst areas
Anhui Province
heavy metals (HM)
geochemical characteristics
enrichment factors
url https://www.mdpi.com/2073-4395/13/4/1067
work_keys_str_mv AT wenbingji geochemicalcharacteristicsoftypicalkarstsoilprofilesinanhuiprovincesoutheasternchina
AT yuanyuanlu geochemicalcharacteristicsoftypicalkarstsoilprofilesinanhuiprovincesoutheasternchina
AT minyang geochemicalcharacteristicsoftypicalkarstsoilprofilesinanhuiprovincesoutheasternchina
AT jianwang geochemicalcharacteristicsoftypicalkarstsoilprofilesinanhuiprovincesoutheasternchina
AT xiaoyuzhang geochemicalcharacteristicsoftypicalkarstsoilprofilesinanhuiprovincesoutheasternchina
AT caiyizhao geochemicalcharacteristicsoftypicalkarstsoilprofilesinanhuiprovincesoutheasternchina
AT bingxia geochemicalcharacteristicsoftypicalkarstsoilprofilesinanhuiprovincesoutheasternchina
AT yunjinwu geochemicalcharacteristicsoftypicalkarstsoilprofilesinanhuiprovincesoutheasternchina
AT rongrongying geochemicalcharacteristicsoftypicalkarstsoilprofilesinanhuiprovincesoutheasternchina