Photoredox Catalyzed Dealkylative Aromatic Halogen Substitution with Tertiary Amines

Photoredox Catalyzed Dealkylative Aromatic Halogen Substitution with Tertiary Amines

A reaction of aromatic halides bearing electron-withdrawing groups with tertiary amines in the presence of an iridium catalyst under blue light irradiation is described. Products of the aromatic substitution of the halide by the dialkylamino fragment are obtained. The interaction of aryl radicals wi...

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Bibliographic Details
Main Authors: Dmitry L. Lipilin, Alexander E. Frumkin, Alexey Y. Tyurin, Vitalij V. Levin, Alexander D. Dilman
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Molecules
Subjects:
aromatic substitution
tertiary amines
photoredox catalysis
radical reactions
Online Access:https://www.mdpi.com/1420-3049/26/11/3323

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