Selective Oxidation of Alcohols through Fe3O4@SiO2/K2CO3‐Glycerin Deep Eutectic Solvent as a Heterogeneous Catalytic System
Abstract K2CO3/Glycerin as a deep eutectic solvent (DES) was anchored covalently onto functionalized magnetic nanoparticles and showed a significant activity towards the oxidation of various alcohols under mild conditions with a short reaction time and good to high yield. A combination of the magnet...
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2022-12-01
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| Series: | ChemistryOpen |
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| Online Access: | https://doi.org/10.1002/open.202200172 |
| _version_ | 1797954157034864640 |
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| author | Sepideh Abbasi Prof. Mohammad Reza Naimi‐Jamal Prof. Shahrzad Javanshir Prof. Akbar Heydari |
| author_facet | Sepideh Abbasi Prof. Mohammad Reza Naimi‐Jamal Prof. Shahrzad Javanshir Prof. Akbar Heydari |
| author_sort | Sepideh Abbasi |
| collection | DOAJ |
| description | Abstract K2CO3/Glycerin as a deep eutectic solvent (DES) was anchored covalently onto functionalized magnetic nanoparticles and showed a significant activity towards the oxidation of various alcohols under mild conditions with a short reaction time and good to high yield. A combination of the magnetic nanoparticles and deep eutectic solvent offers a novel, green, reusable catalyst with easy separation. Also, the catalyst structure was well characterized using techniques such as FT‐IR spectroscopy, XRD, SEM, TGA, BET, VSM, TEM, and energy‐dispersive X‐ray spectroscopy (EDS). |
| first_indexed | 2024-04-10T23:14:14Z |
| format | Article |
| id | doaj.art-38a29bb42c404925ad6dc6e797579f3f |
| institution | Directory Open Access Journal |
| issn | 2191-1363 |
| language | English |
| last_indexed | 2024-04-10T23:14:14Z |
| publishDate | 2022-12-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | ChemistryOpen |
| spelling | doaj.art-38a29bb42c404925ad6dc6e797579f3f2023-01-13T01:50:53ZengWiley-VCHChemistryOpen2191-13632022-12-011112n/an/a10.1002/open.202200172Selective Oxidation of Alcohols through Fe3O4@SiO2/K2CO3‐Glycerin Deep Eutectic Solvent as a Heterogeneous Catalytic SystemSepideh Abbasi0Prof. Mohammad Reza Naimi‐Jamal1Prof. Shahrzad Javanshir2Prof. Akbar Heydari3Research Laboratory of Green Organic Synthesis & Polymers Department of Chemistry Iran University of Science and Technology (IUST) 16846-13114 Tehran IranResearch Laboratory of Green Organic Synthesis & Polymers Department of Chemistry Iran University of Science and Technology (IUST) 16846-13114 Tehran IranHeterocyclic Chemistry Research Laboratory Chemistry Department Iran University of Science and Technology 16846-13114 Tehran IranChemistry Department Tarbiat Modares University 14155-4838 Tehran IranAbstract K2CO3/Glycerin as a deep eutectic solvent (DES) was anchored covalently onto functionalized magnetic nanoparticles and showed a significant activity towards the oxidation of various alcohols under mild conditions with a short reaction time and good to high yield. A combination of the magnetic nanoparticles and deep eutectic solvent offers a novel, green, reusable catalyst with easy separation. Also, the catalyst structure was well characterized using techniques such as FT‐IR spectroscopy, XRD, SEM, TGA, BET, VSM, TEM, and energy‐dispersive X‐ray spectroscopy (EDS).https://doi.org/10.1002/open.202200172alcohol oxidationdeep eutectic solventgreen chemistryheterogeneous catalystmagnetic nanoparticles |
| spellingShingle | Sepideh Abbasi Prof. Mohammad Reza Naimi‐Jamal Prof. Shahrzad Javanshir Prof. Akbar Heydari Selective Oxidation of Alcohols through Fe3O4@SiO2/K2CO3‐Glycerin Deep Eutectic Solvent as a Heterogeneous Catalytic System ChemistryOpen alcohol oxidation deep eutectic solvent green chemistry heterogeneous catalyst magnetic nanoparticles |
| title | Selective Oxidation of Alcohols through Fe3O4@SiO2/K2CO3‐Glycerin Deep Eutectic Solvent as a Heterogeneous Catalytic System |
| title_full | Selective Oxidation of Alcohols through Fe3O4@SiO2/K2CO3‐Glycerin Deep Eutectic Solvent as a Heterogeneous Catalytic System |
| title_fullStr | Selective Oxidation of Alcohols through Fe3O4@SiO2/K2CO3‐Glycerin Deep Eutectic Solvent as a Heterogeneous Catalytic System |
| title_full_unstemmed | Selective Oxidation of Alcohols through Fe3O4@SiO2/K2CO3‐Glycerin Deep Eutectic Solvent as a Heterogeneous Catalytic System |
| title_short | Selective Oxidation of Alcohols through Fe3O4@SiO2/K2CO3‐Glycerin Deep Eutectic Solvent as a Heterogeneous Catalytic System |
| title_sort | selective oxidation of alcohols through fe3o4 sio2 k2co3 glycerin deep eutectic solvent as a heterogeneous catalytic system |
| topic | alcohol oxidation deep eutectic solvent green chemistry heterogeneous catalyst magnetic nanoparticles |
| url | https://doi.org/10.1002/open.202200172 |
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