Pheophorbide a effect upon dark- and photooxidation of olefins

Peculiarities of pheophorbide’s a behavior in conditions of photosensitized and dark oxidation of natural olefin limonene have been analyzed. It is shown that phaeophorbide a is the photosensitizer of limonene oxidation, but it does not act upon its dark oxidation and it does not interreact with per...

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Main Authors: O. V. Kradenova, D. A. Krugovov, E. A. Larkina, E. P. Tkachevskaya, O. T. Kasaikina
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2006-08-01
Series:Тонкие химические технологии
Online Access:https://www.finechem-mirea.ru/jour/article/view/1426
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author O. V. Kradenova
D. A. Krugovov
E. A. Larkina
E. P. Tkachevskaya
O. T. Kasaikina
author_facet O. V. Kradenova
D. A. Krugovov
E. A. Larkina
E. P. Tkachevskaya
O. T. Kasaikina
author_sort O. V. Kradenova
collection DOAJ
description Peculiarities of pheophorbide’s a behavior in conditions of photosensitized and dark oxidation of natural olefin limonene have been analyzed. It is shown that phaeophorbide a is the photosensitizer of limonene oxidation, but it does not act upon its dark oxidation and it does not interreact with peroxides. Although pheophorbide is spent in reactions with radicals formed under H2O2 catalyzed decomposition, and it forms complexes with compounds including zinc and cobalt
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spelling doaj.art-38c7a13ca5d44b719f4ca5e42715e0742023-03-13T07:25:27ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752006-08-011444491421Pheophorbide a effect upon dark- and photooxidation of olefinsO. V. Kradenova0D. A. Krugovov1E. A. Larkina2E. P. Tkachevskaya3O. T. Kasaikina4M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571ИХФ им. Н.Н. Семенова РАНM.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571ИХФ им. Н.Н. Семенова РАНPeculiarities of pheophorbide’s a behavior in conditions of photosensitized and dark oxidation of natural olefin limonene have been analyzed. It is shown that phaeophorbide a is the photosensitizer of limonene oxidation, but it does not act upon its dark oxidation and it does not interreact with peroxides. Although pheophorbide is spent in reactions with radicals formed under H2O2 catalyzed decomposition, and it forms complexes with compounds including zinc and cobalthttps://www.finechem-mirea.ru/jour/article/view/1426
spellingShingle O. V. Kradenova
D. A. Krugovov
E. A. Larkina
E. P. Tkachevskaya
O. T. Kasaikina
Pheophorbide a effect upon dark- and photooxidation of olefins
Тонкие химические технологии
title Pheophorbide a effect upon dark- and photooxidation of olefins
title_full Pheophorbide a effect upon dark- and photooxidation of olefins
title_fullStr Pheophorbide a effect upon dark- and photooxidation of olefins
title_full_unstemmed Pheophorbide a effect upon dark- and photooxidation of olefins
title_short Pheophorbide a effect upon dark- and photooxidation of olefins
title_sort pheophorbide a effect upon dark and photooxidation of olefins
url https://www.finechem-mirea.ru/jour/article/view/1426
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AT ealarkina pheophorbideaeffectupondarkandphotooxidationofolefins
AT eptkachevskaya pheophorbideaeffectupondarkandphotooxidationofolefins
AT otkasaikina pheophorbideaeffectupondarkandphotooxidationofolefins