Multi-Component-Multiphase Flash Calculations for Systems Containing Gas Hydrates by Direct Minimization of Gibbs Free Energy
The Michelsen stability and multiphase flash calculation by direct minimization of Gibbs free energy of the system at constant temperature and pressure, was used for systems containing gas hydrates. The solid hydrate phase was treated as a solid solution. The fugacities of all components of the hydr...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
2006-09-01
|
Series: | Iranian Journal of Chemistry & Chemical Engineering |
Subjects: | |
Online Access: | http://www.ijcce.ac.ir/article_8046_6c41b132434b08ff918634a7791c6683.pdf |
_version_ | 1818143952963895296 |
---|---|
author | Amir Abbas Izadpanah Mohsen Vafaie Sefti Farshad Varaminian |
author_facet | Amir Abbas Izadpanah Mohsen Vafaie Sefti Farshad Varaminian |
author_sort | Amir Abbas Izadpanah |
collection | DOAJ |
description | The Michelsen stability and multiphase flash calculation by direct minimization of Gibbs free energy of the system at constant temperature and pressure, was used for systems containing gas hydrates. The solid hydrate phase was treated as a solid solution. The fugacities of all components of the hydrate phase were calculated as a function of compositions by the rearranged model of van der Waals and Platteeuw. Using this rearranged model enables the use of multiphase flash algorithm for systems containing gas hydrates. Based on this calculation for hydrate phases, we can determine amounts of hydrate formed and structure stability based on a minimum Gibbs free energy criterion. |
first_indexed | 2024-12-11T11:39:51Z |
format | Article |
id | doaj.art-38fc29786a33479e99f0b8d6f274971e |
institution | Directory Open Access Journal |
issn | 1021-9986 1021-9986 |
language | English |
last_indexed | 2024-12-11T11:39:51Z |
publishDate | 2006-09-01 |
publisher | Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR |
record_format | Article |
series | Iranian Journal of Chemistry & Chemical Engineering |
spelling | doaj.art-38fc29786a33479e99f0b8d6f274971e2022-12-22T01:08:39ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99862006-09-0125327348046Multi-Component-Multiphase Flash Calculations for Systems Containing Gas Hydrates by Direct Minimization of Gibbs Free EnergyAmir Abbas Izadpanah0Mohsen Vafaie Sefti1Farshad Varaminian2Department of Chemical Engineering, Tarbiat Modarres University, Tehran, I.R. IRANDepartment of Chemical Engineering, Tarbiat Modarres University, Tehran, I.R. IRANDepartment of Chemical Engineering, Engineering Faculty, Semnan University, Semnan, I.R. IRANThe Michelsen stability and multiphase flash calculation by direct minimization of Gibbs free energy of the system at constant temperature and pressure, was used for systems containing gas hydrates. The solid hydrate phase was treated as a solid solution. The fugacities of all components of the hydrate phase were calculated as a function of compositions by the rearranged model of van der Waals and Platteeuw. Using this rearranged model enables the use of multiphase flash algorithm for systems containing gas hydrates. Based on this calculation for hydrate phases, we can determine amounts of hydrate formed and structure stability based on a minimum Gibbs free energy criterion.http://www.ijcce.ac.ir/article_8046_6c41b132434b08ff918634a7791c6683.pdfflash calculationminimizationgibbs free energyequation of stategas hydrate |
spellingShingle | Amir Abbas Izadpanah Mohsen Vafaie Sefti Farshad Varaminian Multi-Component-Multiphase Flash Calculations for Systems Containing Gas Hydrates by Direct Minimization of Gibbs Free Energy Iranian Journal of Chemistry & Chemical Engineering flash calculation minimization gibbs free energy equation of state gas hydrate |
title | Multi-Component-Multiphase Flash Calculations for Systems Containing Gas Hydrates by Direct Minimization of Gibbs Free Energy |
title_full | Multi-Component-Multiphase Flash Calculations for Systems Containing Gas Hydrates by Direct Minimization of Gibbs Free Energy |
title_fullStr | Multi-Component-Multiphase Flash Calculations for Systems Containing Gas Hydrates by Direct Minimization of Gibbs Free Energy |
title_full_unstemmed | Multi-Component-Multiphase Flash Calculations for Systems Containing Gas Hydrates by Direct Minimization of Gibbs Free Energy |
title_short | Multi-Component-Multiphase Flash Calculations for Systems Containing Gas Hydrates by Direct Minimization of Gibbs Free Energy |
title_sort | multi component multiphase flash calculations for systems containing gas hydrates by direct minimization of gibbs free energy |
topic | flash calculation minimization gibbs free energy equation of state gas hydrate |
url | http://www.ijcce.ac.ir/article_8046_6c41b132434b08ff918634a7791c6683.pdf |
work_keys_str_mv | AT amirabbasizadpanah multicomponentmultiphaseflashcalculationsforsystemscontaininggashydratesbydirectminimizationofgibbsfreeenergy AT mohsenvafaiesefti multicomponentmultiphaseflashcalculationsforsystemscontaininggashydratesbydirectminimizationofgibbsfreeenergy AT farshadvaraminian multicomponentmultiphaseflashcalculationsforsystemscontaininggashydratesbydirectminimizationofgibbsfreeenergy |