Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous Solutions
Nanomaterials have gained much attention in the field of environmental remediation, largely due to their high surface area-to-volume ratio and other unique physical, chemical, and biological characteristics that emerge due to its size effects. Metallic nanoparticles are traditionally manufactured us...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2022-05-01
|
Series: | Crystals |
Subjects: | |
Online Access: | https://www.mdpi.com/2073-4352/12/5/662 |
_version_ | 1797500493260390400 |
---|---|
author | Madiha Batool Walid M. Daoush Muhammad Khalid Hussain |
author_facet | Madiha Batool Walid M. Daoush Muhammad Khalid Hussain |
author_sort | Madiha Batool |
collection | DOAJ |
description | Nanomaterials have gained much attention in the field of environmental remediation, largely due to their high surface area-to-volume ratio and other unique physical, chemical, and biological characteristics that emerge due to its size effects. Metallic nanoparticles are traditionally manufactured using wet chemical processes; however, the chemicals utilized are generally hazardous and combustible. The biosynthesis of nanoparticles using a variety of plant resources is considered a green technology because it does not use toxic chemicals. This work focuses on the green synthesis of biogenetic silver nanoparticles and their use in the sequestration of colorants from aqueous solution. The extract of aquatic macrophyte <i>Salvinia molesta</i> (water hyacinth) has been employed to prepare silver nanoparticles by chemical reduction reaction. In the UV-visible spectrum of the synthesized silver nanoparticles, the absorbance peak was detected in the 420–430 nm range. The synthesized silver nanoparticles were used to sequester methylene blue (MB) dye in aqueous solution. About 121.04 mg/g was found as the highest adsorption capacity of methylene blue dye on the silver nanoparticles according to the Langmuir isotherm. It was observed that the experimental results and the pseudo-second order kinetics are in good agreement. As a result, the biosynthesized silver nanoparticle might be a potential adsorbent material in the field of environmental rehabilitation and cleanup. |
first_indexed | 2024-03-10T03:04:37Z |
format | Article |
id | doaj.art-390c8ea1395f40efb5f6acd4f21729c3 |
institution | Directory Open Access Journal |
issn | 2073-4352 |
language | English |
last_indexed | 2024-03-10T03:04:37Z |
publishDate | 2022-05-01 |
publisher | MDPI AG |
record_format | Article |
series | Crystals |
spelling | doaj.art-390c8ea1395f40efb5f6acd4f21729c32023-11-23T10:35:08ZengMDPI AGCrystals2073-43522022-05-0112566210.3390/cryst12050662Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous SolutionsMadiha Batool0Walid M. Daoush1Muhammad Khalid Hussain2Department of Chemistry, GC University, Lahore 54000, PakistanDepartment of Production Technology, Faculty of Technology and Education, Helwan University, Cairo 11281, EgyptDepartment of Physics, Hafiz Hayat Campus, University of Gujrat, Gujrat 50700, PakistanNanomaterials have gained much attention in the field of environmental remediation, largely due to their high surface area-to-volume ratio and other unique physical, chemical, and biological characteristics that emerge due to its size effects. Metallic nanoparticles are traditionally manufactured using wet chemical processes; however, the chemicals utilized are generally hazardous and combustible. The biosynthesis of nanoparticles using a variety of plant resources is considered a green technology because it does not use toxic chemicals. This work focuses on the green synthesis of biogenetic silver nanoparticles and their use in the sequestration of colorants from aqueous solution. The extract of aquatic macrophyte <i>Salvinia molesta</i> (water hyacinth) has been employed to prepare silver nanoparticles by chemical reduction reaction. In the UV-visible spectrum of the synthesized silver nanoparticles, the absorbance peak was detected in the 420–430 nm range. The synthesized silver nanoparticles were used to sequester methylene blue (MB) dye in aqueous solution. About 121.04 mg/g was found as the highest adsorption capacity of methylene blue dye on the silver nanoparticles according to the Langmuir isotherm. It was observed that the experimental results and the pseudo-second order kinetics are in good agreement. As a result, the biosynthesized silver nanoparticle might be a potential adsorbent material in the field of environmental rehabilitation and cleanup.https://www.mdpi.com/2073-4352/12/5/662silver nanoparticlesgreen synthesisadsorptioncolorantsmethylene blue dye |
spellingShingle | Madiha Batool Walid M. Daoush Muhammad Khalid Hussain Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous Solutions Crystals silver nanoparticles green synthesis adsorption colorants methylene blue dye |
title | Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous Solutions |
title_full | Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous Solutions |
title_fullStr | Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous Solutions |
title_full_unstemmed | Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous Solutions |
title_short | Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous Solutions |
title_sort | dye sequestration using biosynthesized silver nanoparticles adsorbent in aqueous solutions |
topic | silver nanoparticles green synthesis adsorption colorants methylene blue dye |
url | https://www.mdpi.com/2073-4352/12/5/662 |
work_keys_str_mv | AT madihabatool dyesequestrationusingbiosynthesizedsilvernanoparticlesadsorbentinaqueoussolutions AT walidmdaoush dyesequestrationusingbiosynthesizedsilvernanoparticlesadsorbentinaqueoussolutions AT muhammadkhalidhussain dyesequestrationusingbiosynthesizedsilvernanoparticlesadsorbentinaqueoussolutions |