Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous Solutions

Nanomaterials have gained much attention in the field of environmental remediation, largely due to their high surface area-to-volume ratio and other unique physical, chemical, and biological characteristics that emerge due to its size effects. Metallic nanoparticles are traditionally manufactured us...

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Main Authors: Madiha Batool, Walid M. Daoush, Muhammad Khalid Hussain
Format: Article
Language:English
Published: MDPI AG 2022-05-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/12/5/662
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author Madiha Batool
Walid M. Daoush
Muhammad Khalid Hussain
author_facet Madiha Batool
Walid M. Daoush
Muhammad Khalid Hussain
author_sort Madiha Batool
collection DOAJ
description Nanomaterials have gained much attention in the field of environmental remediation, largely due to their high surface area-to-volume ratio and other unique physical, chemical, and biological characteristics that emerge due to its size effects. Metallic nanoparticles are traditionally manufactured using wet chemical processes; however, the chemicals utilized are generally hazardous and combustible. The biosynthesis of nanoparticles using a variety of plant resources is considered a green technology because it does not use toxic chemicals. This work focuses on the green synthesis of biogenetic silver nanoparticles and their use in the sequestration of colorants from aqueous solution. The extract of aquatic macrophyte <i>Salvinia molesta</i> (water hyacinth) has been employed to prepare silver nanoparticles by chemical reduction reaction. In the UV-visible spectrum of the synthesized silver nanoparticles, the absorbance peak was detected in the 420–430 nm range. The synthesized silver nanoparticles were used to sequester methylene blue (MB) dye in aqueous solution. About 121.04 mg/g was found as the highest adsorption capacity of methylene blue dye on the silver nanoparticles according to the Langmuir isotherm. It was observed that the experimental results and the pseudo-second order kinetics are in good agreement. As a result, the biosynthesized silver nanoparticle might be a potential adsorbent material in the field of environmental rehabilitation and cleanup.
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spelling doaj.art-390c8ea1395f40efb5f6acd4f21729c32023-11-23T10:35:08ZengMDPI AGCrystals2073-43522022-05-0112566210.3390/cryst12050662Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous SolutionsMadiha Batool0Walid M. Daoush1Muhammad Khalid Hussain2Department of Chemistry, GC University, Lahore 54000, PakistanDepartment of Production Technology, Faculty of Technology and Education, Helwan University, Cairo 11281, EgyptDepartment of Physics, Hafiz Hayat Campus, University of Gujrat, Gujrat 50700, PakistanNanomaterials have gained much attention in the field of environmental remediation, largely due to their high surface area-to-volume ratio and other unique physical, chemical, and biological characteristics that emerge due to its size effects. Metallic nanoparticles are traditionally manufactured using wet chemical processes; however, the chemicals utilized are generally hazardous and combustible. The biosynthesis of nanoparticles using a variety of plant resources is considered a green technology because it does not use toxic chemicals. This work focuses on the green synthesis of biogenetic silver nanoparticles and their use in the sequestration of colorants from aqueous solution. The extract of aquatic macrophyte <i>Salvinia molesta</i> (water hyacinth) has been employed to prepare silver nanoparticles by chemical reduction reaction. In the UV-visible spectrum of the synthesized silver nanoparticles, the absorbance peak was detected in the 420–430 nm range. The synthesized silver nanoparticles were used to sequester methylene blue (MB) dye in aqueous solution. About 121.04 mg/g was found as the highest adsorption capacity of methylene blue dye on the silver nanoparticles according to the Langmuir isotherm. It was observed that the experimental results and the pseudo-second order kinetics are in good agreement. As a result, the biosynthesized silver nanoparticle might be a potential adsorbent material in the field of environmental rehabilitation and cleanup.https://www.mdpi.com/2073-4352/12/5/662silver nanoparticlesgreen synthesisadsorptioncolorantsmethylene blue dye
spellingShingle Madiha Batool
Walid M. Daoush
Muhammad Khalid Hussain
Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous Solutions
Crystals
silver nanoparticles
green synthesis
adsorption
colorants
methylene blue dye
title Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous Solutions
title_full Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous Solutions
title_fullStr Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous Solutions
title_full_unstemmed Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous Solutions
title_short Dye Sequestration Using Biosynthesized Silver Nanoparticles Adsorbent in Aqueous Solutions
title_sort dye sequestration using biosynthesized silver nanoparticles adsorbent in aqueous solutions
topic silver nanoparticles
green synthesis
adsorption
colorants
methylene blue dye
url https://www.mdpi.com/2073-4352/12/5/662
work_keys_str_mv AT madihabatool dyesequestrationusingbiosynthesizedsilvernanoparticlesadsorbentinaqueoussolutions
AT walidmdaoush dyesequestrationusingbiosynthesizedsilvernanoparticlesadsorbentinaqueoussolutions
AT muhammadkhalidhussain dyesequestrationusingbiosynthesizedsilvernanoparticlesadsorbentinaqueoussolutions