Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione
12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione (quinone 2) served as the dienophile in numerous intermolecular Diels-Alder reactions. These cycloadditions were conducted either thermally (including microwave heating) or with Lewis acid activation. While most dienes reacted...
| Main Authors: | , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2013-06-01
|
| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/18/6/6969 |
| _version_ | 1818081150000693248 |
|---|---|
| author | Shougang Hu Yangyang Wang Yang Li Ge Zou Xinrong Tian Yong Zhang George Majetich Eric Huddleston |
| author_facet | Shougang Hu Yangyang Wang Yang Li Ge Zou Xinrong Tian Yong Zhang George Majetich Eric Huddleston |
| author_sort | Shougang Hu |
| collection | DOAJ |
| description | 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione (quinone 2) served as the dienophile in numerous intermolecular Diels-Alder reactions. These cycloadditions were conducted either thermally (including microwave heating) or with Lewis acid activation. While most dienes reacted with quinone 2 in good chemical yield, others were incompatible under the experimental conditions used. |
| first_indexed | 2024-12-10T19:01:37Z |
| format | Article |
| id | doaj.art-392b99ee68f94bb88b5c8cf054901672 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-10T19:01:37Z |
| publishDate | 2013-06-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-392b99ee68f94bb88b5c8cf0549016722022-12-22T01:36:59ZengMDPI AGMolecules1420-30492013-06-011866969698910.3390/molecules18066969Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dioneShougang HuYangyang WangYang LiGe ZouXinrong TianYong ZhangGeorge MajetichEric Huddleston12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione (quinone 2) served as the dienophile in numerous intermolecular Diels-Alder reactions. These cycloadditions were conducted either thermally (including microwave heating) or with Lewis acid activation. While most dienes reacted with quinone 2 in good chemical yield, others were incompatible under the experimental conditions used.http://www.mdpi.com/1420-3049/18/6/6969Diels-Alder reactioncascade processone-pot reactionLewis acid catalysis |
| spellingShingle | Shougang Hu Yangyang Wang Yang Li Ge Zou Xinrong Tian Yong Zhang George Majetich Eric Huddleston Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione Molecules Diels-Alder reaction cascade process one-pot reaction Lewis acid catalysis |
| title | Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione |
| title_full | Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione |
| title_fullStr | Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione |
| title_full_unstemmed | Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione |
| title_short | Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione |
| title_sort | diels alder reactions of 12 hydroxy 9 10 r 20 5ah abeo abieta 1 10 8 9 12 13 triene 11 14 dione |
| topic | Diels-Alder reaction cascade process one-pot reaction Lewis acid catalysis |
| url | http://www.mdpi.com/1420-3049/18/6/6969 |
| work_keys_str_mv | AT shouganghu dielsalderreactionsof12hydroxy910205ahabeoabieta110891213triene1114dione AT yangyangwang dielsalderreactionsof12hydroxy910205ahabeoabieta110891213triene1114dione AT yangli dielsalderreactionsof12hydroxy910205ahabeoabieta110891213triene1114dione AT gezou dielsalderreactionsof12hydroxy910205ahabeoabieta110891213triene1114dione AT xinrongtian dielsalderreactionsof12hydroxy910205ahabeoabieta110891213triene1114dione AT yongzhang dielsalderreactionsof12hydroxy910205ahabeoabieta110891213triene1114dione AT georgemajetich dielsalderreactionsof12hydroxy910205ahabeoabieta110891213triene1114dione AT erichuddleston dielsalderreactionsof12hydroxy910205ahabeoabieta110891213triene1114dione |