Dependence of Photocatalytic Activity of TiO2-SiO2 Nanopowders

Structural properties and chemical composition change the photocatalytic activity in TiO2-SiO2 nanopowder composite. The SiO2-TiO2 nanostructure is synthesized based on sol–gel method. The nanoparticles are characterized by x-ray fluorescents (XRF), x- ray diffraction (XRD), tunneling electron micro...

Full description

Bibliographic Details
Main Author: M. Riazian
Format: Article
Language:English
Published: Nanoscience and Nanotechnology Research Center, University of Kashan 2014-10-01
Series:Journal of Nanostructures
Subjects:
Online Access:http://jns.kashanu.ac.ir/article_8488_b376680cbbf13eb7de103d7ee2266992.pdf
_version_ 1818331260416688128
author M. Riazian
author_facet M. Riazian
author_sort M. Riazian
collection DOAJ
description Structural properties and chemical composition change the photocatalytic activity in TiO2-SiO2 nanopowder composite. The SiO2-TiO2 nanostructure is synthesized based on sol–gel method. The nanoparticles are characterized by x-ray fluorescents (XRF), x- ray diffraction (XRD), tunneling electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), UV-vis. Spectrophotometer and furrier transmission create infrared absorption (FTIR) techniques. The rate constant k for the degradation of methylen blue in its aqueous solution under UV irradiation is determined as a measure of photocatalytic activity. Dependence between photocatalytic activity and SiO2 content in the composite is determined. Rate constant k is found dependent on the content of SiO2 in the composite that calcined at 900 oC. The addition of low composition SiO2 to the TiO2 matrix (lower than 45%) enhances the photocatalytic activity due to thermal stability and increasing in the surface area. The effects of chemical compositions on the surface topography and the crystallization of phases are studied.
first_indexed 2024-12-13T13:17:01Z
format Article
id doaj.art-393b2e626f554398a3cd2b97dbd13a5c
institution Directory Open Access Journal
issn 2251-7871
2251-788X
language English
last_indexed 2024-12-13T13:17:01Z
publishDate 2014-10-01
publisher Nanoscience and Nanotechnology Research Center, University of Kashan
record_format Article
series Journal of Nanostructures
spelling doaj.art-393b2e626f554398a3cd2b97dbd13a5c2022-12-21T23:44:30ZengNanoscience and Nanotechnology Research Center, University of KashanJournal of Nanostructures2251-78712251-788X2014-10-014443344110.7508/jns.2014.04.0058488Dependence of Photocatalytic Activity of TiO2-SiO2 NanopowdersM. Riazian0Department of Engineering, Tonekabon branch, Islamic Azad University, Tonekabon, Iran.Structural properties and chemical composition change the photocatalytic activity in TiO2-SiO2 nanopowder composite. The SiO2-TiO2 nanostructure is synthesized based on sol–gel method. The nanoparticles are characterized by x-ray fluorescents (XRF), x- ray diffraction (XRD), tunneling electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), UV-vis. Spectrophotometer and furrier transmission create infrared absorption (FTIR) techniques. The rate constant k for the degradation of methylen blue in its aqueous solution under UV irradiation is determined as a measure of photocatalytic activity. Dependence between photocatalytic activity and SiO2 content in the composite is determined. Rate constant k is found dependent on the content of SiO2 in the composite that calcined at 900 oC. The addition of low composition SiO2 to the TiO2 matrix (lower than 45%) enhances the photocatalytic activity due to thermal stability and increasing in the surface area. The effects of chemical compositions on the surface topography and the crystallization of phases are studied.http://jns.kashanu.ac.ir/article_8488_b376680cbbf13eb7de103d7ee2266992.pdfNanostructurePhotocatalytic activitySiO2-TiO2Sol-gel method
spellingShingle M. Riazian
Dependence of Photocatalytic Activity of TiO2-SiO2 Nanopowders
Journal of Nanostructures
Nanostructure
Photocatalytic activity
SiO2-TiO2
Sol-gel method
title Dependence of Photocatalytic Activity of TiO2-SiO2 Nanopowders
title_full Dependence of Photocatalytic Activity of TiO2-SiO2 Nanopowders
title_fullStr Dependence of Photocatalytic Activity of TiO2-SiO2 Nanopowders
title_full_unstemmed Dependence of Photocatalytic Activity of TiO2-SiO2 Nanopowders
title_short Dependence of Photocatalytic Activity of TiO2-SiO2 Nanopowders
title_sort dependence of photocatalytic activity of tio2 sio2 nanopowders
topic Nanostructure
Photocatalytic activity
SiO2-TiO2
Sol-gel method
url http://jns.kashanu.ac.ir/article_8488_b376680cbbf13eb7de103d7ee2266992.pdf
work_keys_str_mv AT mriazian dependenceofphotocatalyticactivityoftio2sio2nanopowders