Room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C60 molecules

Abstract A carbon nanobelt (CNB) is a loop of fused benzene rings and a C60 molecule is a football shaped fullerene composed of 60 carbon atoms. In this study, we synthesize uniform spherical particles composed of (6,6)CNBs and C60 molecules in 1,2-dichlorobenzene at room temperature via bottom-up s...

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Main Authors: Sieun Choi, Shunji Kurosu, Yuta Mashiko, Takanobu Minakawa, Toru Maekawa
Format: Article
Language:English
Published: Nature Portfolio 2022-09-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-022-19475-z
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author Sieun Choi
Shunji Kurosu
Yuta Mashiko
Takanobu Minakawa
Toru Maekawa
author_facet Sieun Choi
Shunji Kurosu
Yuta Mashiko
Takanobu Minakawa
Toru Maekawa
author_sort Sieun Choi
collection DOAJ
description Abstract A carbon nanobelt (CNB) is a loop of fused benzene rings and a C60 molecule is a football shaped fullerene composed of 60 carbon atoms. In this study, we synthesize uniform spherical particles composed of (6,6)CNBs and C60 molecules in 1,2-dichlorobenzene at room temperature via bottom-up self-assembly, setting the molar concentrations of (6,6)CNBs and C60 molecules at appropriate values, and find that the particles are monodisperse even in water. The present room temperature synthetic methodology may well be applied to the creation of nano/micro structures/materials using basic carbon nano units such as cycloparaphenylene (CPP, carbon nanorings) and fullerenes; e.g., C60, C70 and C59N.
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spelling doaj.art-395f3dafec504244a618c0facdc544b62022-12-22T03:12:58ZengNature PortfolioScientific Reports2045-23222022-09-011211610.1038/s41598-022-19475-zRoom temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C60 moleculesSieun Choi0Shunji Kurosu1Yuta Mashiko2Takanobu Minakawa3Toru Maekawa4Graduate School of Interdisciplinary New Science, Toyo UniversityBio-Nano Electronics Research Centre, Toyo UniversityGraduate School of Interdisciplinary New Science, Toyo UniversityGraduate School of Interdisciplinary New Science, Toyo UniversityGraduate School of Interdisciplinary New Science, Toyo UniversityAbstract A carbon nanobelt (CNB) is a loop of fused benzene rings and a C60 molecule is a football shaped fullerene composed of 60 carbon atoms. In this study, we synthesize uniform spherical particles composed of (6,6)CNBs and C60 molecules in 1,2-dichlorobenzene at room temperature via bottom-up self-assembly, setting the molar concentrations of (6,6)CNBs and C60 molecules at appropriate values, and find that the particles are monodisperse even in water. The present room temperature synthetic methodology may well be applied to the creation of nano/micro structures/materials using basic carbon nano units such as cycloparaphenylene (CPP, carbon nanorings) and fullerenes; e.g., C60, C70 and C59N.https://doi.org/10.1038/s41598-022-19475-z
spellingShingle Sieun Choi
Shunji Kurosu
Yuta Mashiko
Takanobu Minakawa
Toru Maekawa
Room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C60 molecules
Scientific Reports
title Room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C60 molecules
title_full Room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C60 molecules
title_fullStr Room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C60 molecules
title_full_unstemmed Room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C60 molecules
title_short Room temperature synthesis of water-soluble spherical particles of a uniform diameter composed of carbon nanobelts and C60 molecules
title_sort room temperature synthesis of water soluble spherical particles of a uniform diameter composed of carbon nanobelts and c60 molecules
url https://doi.org/10.1038/s41598-022-19475-z
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