Low-cost composites based on porous titania–apatite surfaces for the removal of patent blue V from water: Effect of chemical structure of dye

Hydroxyapatite/titania nanocomposites (TiHAp) were synthesized from a mixture of a titanium alkoxide solution and dissolution products of a Moroccan natural phosphate. The simultaneous gelation and precipitation processes occurring at room temperature led to the formation of TiHAp nanocomposites. X-...

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Main Authors: C. El Bekkali, H. Bouyarmane, S. Saoiabi, M. El Karbane, A. Rami, A. Saoiabi, M. Boujtita, A. Laghzizil
Format: Article
Language:English
Published: Elsevier 2016-11-01
Series:Journal of Advanced Research
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2090123216300352
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author C. El Bekkali
H. Bouyarmane
S. Saoiabi
M. El Karbane
A. Rami
A. Saoiabi
M. Boujtita
A. Laghzizil
author_facet C. El Bekkali
H. Bouyarmane
S. Saoiabi
M. El Karbane
A. Rami
A. Saoiabi
M. Boujtita
A. Laghzizil
author_sort C. El Bekkali
collection DOAJ
description Hydroxyapatite/titania nanocomposites (TiHAp) were synthesized from a mixture of a titanium alkoxide solution and dissolution products of a Moroccan natural phosphate. The simultaneous gelation and precipitation processes occurring at room temperature led to the formation of TiHAp nanocomposites. X-ray diffraction results indicated that hydroxyapatite and anatase (TiO2) were the major crystalline phases. The specific surface area of the nanocomposites increased with the TiO2 content. Resulting TiHAp powders were assessed for the removal of the patent blue V dye from water. Kinetic experiments suggested that a sequence of adsorption and photodegradation is responsible for discoloration of dye solutions. These results suggest that such hydroxyapatite/titania nanocomposites constitute attractive low-cost materials for the removal of dyes from industrial textile effluent.
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spelling doaj.art-3962453a90dc4768b22e4984220cfa7f2022-12-21T23:26:01ZengElsevierJournal of Advanced Research2090-12322090-12242016-11-01761009101710.1016/j.jare.2016.05.001Low-cost composites based on porous titania–apatite surfaces for the removal of patent blue V from water: Effect of chemical structure of dyeC. El Bekkali0H. Bouyarmane1S. Saoiabi2M. El Karbane3A. Rami4A. Saoiabi5M. Boujtita6A. Laghzizil7Laboratoire de Chimie Physique Générale, Faculté des Sciences, Université Mohammed V, Av. Ibn Batouta, B.P. 1014 Rabat, MoroccoLaboratoire de Chimie Physique Générale, Faculté des Sciences, Université Mohammed V, Av. Ibn Batouta, B.P. 1014 Rabat, MoroccoLaboratoire de Chimie Physique Générale, Faculté des Sciences, Université Mohammed V, Av. Ibn Batouta, B.P. 1014 Rabat, MoroccoLaboratoire National du Contrôle des Médicaments, Rue Lamfaddal Cherkaoui, B.P. 6206 Rabat, MoroccoLaboratoire National du Contrôle des Médicaments, Rue Lamfaddal Cherkaoui, B.P. 6206 Rabat, MoroccoLaboratoire de Chimie Physique Générale, Faculté des Sciences, Université Mohammed V, Av. Ibn Batouta, B.P. 1014 Rabat, MoroccoChimie Interdisciplinarité: Synthèse, Analyse, Modélisation CNRS (CEISAM), Faculté des Sciences et Techniques, Université de Nantes – UBL, B.P. 92208, 44322 Nantes Cedex 03, FranceLaboratoire de Chimie Physique Générale, Faculté des Sciences, Université Mohammed V, Av. Ibn Batouta, B.P. 1014 Rabat, MoroccoHydroxyapatite/titania nanocomposites (TiHAp) were synthesized from a mixture of a titanium alkoxide solution and dissolution products of a Moroccan natural phosphate. The simultaneous gelation and precipitation processes occurring at room temperature led to the formation of TiHAp nanocomposites. X-ray diffraction results indicated that hydroxyapatite and anatase (TiO2) were the major crystalline phases. The specific surface area of the nanocomposites increased with the TiO2 content. Resulting TiHAp powders were assessed for the removal of the patent blue V dye from water. Kinetic experiments suggested that a sequence of adsorption and photodegradation is responsible for discoloration of dye solutions. These results suggest that such hydroxyapatite/titania nanocomposites constitute attractive low-cost materials for the removal of dyes from industrial textile effluent.http://www.sciencedirect.com/science/article/pii/S2090123216300352Apatite/titaniaPatent blueAdsorptionDegradationPhotocatalysisKinetic modeling
spellingShingle C. El Bekkali
H. Bouyarmane
S. Saoiabi
M. El Karbane
A. Rami
A. Saoiabi
M. Boujtita
A. Laghzizil
Low-cost composites based on porous titania–apatite surfaces for the removal of patent blue V from water: Effect of chemical structure of dye
Journal of Advanced Research
Apatite/titania
Patent blue
Adsorption
Degradation
Photocatalysis
Kinetic modeling
title Low-cost composites based on porous titania–apatite surfaces for the removal of patent blue V from water: Effect of chemical structure of dye
title_full Low-cost composites based on porous titania–apatite surfaces for the removal of patent blue V from water: Effect of chemical structure of dye
title_fullStr Low-cost composites based on porous titania–apatite surfaces for the removal of patent blue V from water: Effect of chemical structure of dye
title_full_unstemmed Low-cost composites based on porous titania–apatite surfaces for the removal of patent blue V from water: Effect of chemical structure of dye
title_short Low-cost composites based on porous titania–apatite surfaces for the removal of patent blue V from water: Effect of chemical structure of dye
title_sort low cost composites based on porous titania apatite surfaces for the removal of patent blue v from water effect of chemical structure of dye
topic Apatite/titania
Patent blue
Adsorption
Degradation
Photocatalysis
Kinetic modeling
url http://www.sciencedirect.com/science/article/pii/S2090123216300352
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