Designing safer lithium-based batteries with nonflammable electrolytes: A review

Lithium-based batteries have had a profound impact on modern society through their extensive use in portable electronic devices, electric vehicles, and energy storage systems. However, battery safety issues such as thermal runaway, fire, and explosion hinder their practical application, especially f...

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Main Authors: Shichao Zhang, Siyuan Li, Yingying Lu
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2021-12-01
Series:eScience
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2667141721000501
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author Shichao Zhang
Siyuan Li
Yingying Lu
author_facet Shichao Zhang
Siyuan Li
Yingying Lu
author_sort Shichao Zhang
collection DOAJ
description Lithium-based batteries have had a profound impact on modern society through their extensive use in portable electronic devices, electric vehicles, and energy storage systems. However, battery safety issues such as thermal runaway, fire, and explosion hinder their practical application, especially for using metal anode. These problems are closely related to the high flammability of conventional electrolytes and have prompted the study of flame-retardant and nonflammable electrolytes. Here, we review the recent research on nonflammable electrolytes used in lithium-based batteries, including phosphates, fluorides, fluorinated phosphazenes, ionic liquids, deep eutectic solvents, aqueous electrolytes, and solid-state electrolytes. Their flame-retardant mechanisms and efficiency are discussed, as well as their influence on cell electrochemical performance. We conclude with a summary of future prospects for the design of nonflammable electrolytes and the construction of safer lithium-based batteries.
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spelling doaj.art-3962e65cb2fc4023a8b77357feeda6e92022-12-22T03:53:03ZengKeAi Communications Co. Ltd.eScience2667-14172021-12-0112163177Designing safer lithium-based batteries with nonflammable electrolytes: A reviewShichao Zhang0Siyuan Li1Yingying Lu2State Key Laboratory of Chemical Engineering, Institute of Pharmaceutical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, China; ZJU-Hangzhou Global Scientific and Technological Innovation Center, Hangzhou, 311215, ChinaState Key Laboratory of Chemical Engineering, Institute of Pharmaceutical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, China; ZJU-Hangzhou Global Scientific and Technological Innovation Center, Hangzhou, 311215, ChinaState Key Laboratory of Chemical Engineering, Institute of Pharmaceutical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, China; ZJU-Hangzhou Global Scientific and Technological Innovation Center, Hangzhou, 311215, China; Corresponding author.Lithium-based batteries have had a profound impact on modern society through their extensive use in portable electronic devices, electric vehicles, and energy storage systems. However, battery safety issues such as thermal runaway, fire, and explosion hinder their practical application, especially for using metal anode. These problems are closely related to the high flammability of conventional electrolytes and have prompted the study of flame-retardant and nonflammable electrolytes. Here, we review the recent research on nonflammable electrolytes used in lithium-based batteries, including phosphates, fluorides, fluorinated phosphazenes, ionic liquids, deep eutectic solvents, aqueous electrolytes, and solid-state electrolytes. Their flame-retardant mechanisms and efficiency are discussed, as well as their influence on cell electrochemical performance. We conclude with a summary of future prospects for the design of nonflammable electrolytes and the construction of safer lithium-based batteries.http://www.sciencedirect.com/science/article/pii/S2667141721000501Nonflammable electrolyteFlame retardantsLithium-based batterySafety
spellingShingle Shichao Zhang
Siyuan Li
Yingying Lu
Designing safer lithium-based batteries with nonflammable electrolytes: A review
eScience
Nonflammable electrolyte
Flame retardants
Lithium-based battery
Safety
title Designing safer lithium-based batteries with nonflammable electrolytes: A review
title_full Designing safer lithium-based batteries with nonflammable electrolytes: A review
title_fullStr Designing safer lithium-based batteries with nonflammable electrolytes: A review
title_full_unstemmed Designing safer lithium-based batteries with nonflammable electrolytes: A review
title_short Designing safer lithium-based batteries with nonflammable electrolytes: A review
title_sort designing safer lithium based batteries with nonflammable electrolytes a review
topic Nonflammable electrolyte
Flame retardants
Lithium-based battery
Safety
url http://www.sciencedirect.com/science/article/pii/S2667141721000501
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AT yingyinglu designingsaferlithiumbasedbatterieswithnonflammableelectrolytesareview