Characterization of terpenoids and norisoprenoids from base and retail Qingke Baijiu by GC × GC-TOFMS and multivariate statistical analysis
Qingke (highland barley) Baijiu is a special Chinese Baijiu which is mainly produced from Qinghai-Tibet Plateau. Since the pine board is used as the bottom of the fermentation pit, we deduced that the terpenoids and norisoprenoids in pine board might be introduced into Qingke Baijiu. Thus, the terpe...
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| Format: | Article |
| Language: | English |
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Tsinghua University Press
2023-01-01
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| Series: | Food Science and Human Wellness |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2213453022001161 |
| _version_ | 1797705111074504704 |
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| author | Xinlei Wang Lin Zhu Xuebo Song Si Jing Fuping Zheng Mingquan Huang Shengbao Feng Luzhong La |
| author_facet | Xinlei Wang Lin Zhu Xuebo Song Si Jing Fuping Zheng Mingquan Huang Shengbao Feng Luzhong La |
| author_sort | Xinlei Wang |
| collection | DOAJ |
| description | Qingke (highland barley) Baijiu is a special Chinese Baijiu which is mainly produced from Qinghai-Tibet Plateau. Since the pine board is used as the bottom of the fermentation pit, we deduced that the terpenoids and norisoprenoids in pine board might be introduced into Qingke Baijiu. Thus, the terpenoids and norisoprenoids in Qingke Baijiu were investigated by headspace solid phase microextraction (HS-SPME) combined with comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry (GC × GC-TOFMS). The results showed that γ-terpinene (0.70–530.72 μg/L), α-phellandrene (0.34–256.66 μg/L), longicyclene (0–38.55 μg/L), α-pinene (1.21–35.54 μg/L) and limonene (0.93–23.69 μg/L) were the top 5 terpenoids/norisoprenoids in Qingke Baijiu. Pulegone was detected and reported for the first time in Baijiu, and the concentrations in Qingke Baijiu were 0.78 μg/L (fresh) and 3.90 μg/L (7 years old). According to the principal component analysis (PCA) plot, young, aged, and retail Qingke Baijiu could be differentiated clearly. Fold change (FC) and t-tests analysis indicated that β-pinene, γ-terpinene, and α-selinene were the most different terpenoids/norisoprenoids between young and aged Qingke Baijiu, and longifolene was the most different terpenoids/norisoprenoids between base and retail Qingke Baijiu. The terpenoids and norisoprenoids, such as (E)-β-ionone, isoborneol and β-cyclocitral, could be potential markers indicating the ageing process of Qingke Baijiu. |
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| format | Article |
| id | doaj.art-3967e775e92e4ce5907105ca02d60f55 |
| institution | Directory Open Access Journal |
| issn | 2213-4530 |
| language | English |
| last_indexed | 2024-03-12T05:32:18Z |
| publishDate | 2023-01-01 |
| publisher | Tsinghua University Press |
| record_format | Article |
| series | Food Science and Human Wellness |
| spelling | doaj.art-3967e775e92e4ce5907105ca02d60f552023-09-03T06:50:04ZengTsinghua University PressFood Science and Human Wellness2213-45302023-01-01121192199Characterization of terpenoids and norisoprenoids from base and retail Qingke Baijiu by GC × GC-TOFMS and multivariate statistical analysisXinlei Wang0Lin Zhu1Xuebo Song2Si Jing3Fuping Zheng4Mingquan Huang5Shengbao Feng6Luzhong La7Beijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Technology and Business University, Beijing 100048, China; Beijing Laboratory of Food Quality and Safety, Beijing Technology and Business University, Beijing 100048, China; Key Laboratory of Brewing Molecular Engineering of China Light Industry, Beijing Technology and Business University, Beijing 100048, ChinaBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Technology and Business University, Beijing 100048, China; Beijing Laboratory of Food Quality and Safety, Beijing Technology and Business University, Beijing 100048, China; Key Laboratory of Brewing Molecular Engineering of China Light Industry, Beijing Technology and Business University, Beijing 100048, ChinaBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Technology and Business University, Beijing 100048, China; Beijing Laboratory of Food Quality and Safety, Beijing Technology and Business University, Beijing 100048, China; Key Laboratory of Brewing Molecular Engineering of China Light Industry, Beijing Technology and Business University, Beijing 100048, ChinaBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Technology and Business University, Beijing 100048, China; Beijing Laboratory of Food Quality and Safety, Beijing Technology and Business University, Beijing 100048, China; Key Laboratory of Brewing Molecular Engineering of China Light Industry, Beijing Technology and Business University, Beijing 100048, ChinaBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Technology and Business University, Beijing 100048, China; Beijing Laboratory of Food Quality and Safety, Beijing Technology and Business University, Beijing 100048, China; Key Laboratory of Brewing Molecular Engineering of China Light Industry, Beijing Technology and Business University, Beijing 100048, China; Corresponding author at: Beijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Technology and Business University, Beijing 100048, China.Beijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Technology and Business University, Beijing 100048, China; Beijing Laboratory of Food Quality and Safety, Beijing Technology and Business University, Beijing 100048, China; Key Laboratory of Brewing Molecular Engineering of China Light Industry, Beijing Technology and Business University, Beijing 100048, ChinaQinghai Huzhu Highland Barley Wine Co., Ltd., Huzhu 810500, ChinaQinghai Huzhu Highland Barley Wine Co., Ltd., Huzhu 810500, ChinaQingke (highland barley) Baijiu is a special Chinese Baijiu which is mainly produced from Qinghai-Tibet Plateau. Since the pine board is used as the bottom of the fermentation pit, we deduced that the terpenoids and norisoprenoids in pine board might be introduced into Qingke Baijiu. Thus, the terpenoids and norisoprenoids in Qingke Baijiu were investigated by headspace solid phase microextraction (HS-SPME) combined with comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry (GC × GC-TOFMS). The results showed that γ-terpinene (0.70–530.72 μg/L), α-phellandrene (0.34–256.66 μg/L), longicyclene (0–38.55 μg/L), α-pinene (1.21–35.54 μg/L) and limonene (0.93–23.69 μg/L) were the top 5 terpenoids/norisoprenoids in Qingke Baijiu. Pulegone was detected and reported for the first time in Baijiu, and the concentrations in Qingke Baijiu were 0.78 μg/L (fresh) and 3.90 μg/L (7 years old). According to the principal component analysis (PCA) plot, young, aged, and retail Qingke Baijiu could be differentiated clearly. Fold change (FC) and t-tests analysis indicated that β-pinene, γ-terpinene, and α-selinene were the most different terpenoids/norisoprenoids between young and aged Qingke Baijiu, and longifolene was the most different terpenoids/norisoprenoids between base and retail Qingke Baijiu. The terpenoids and norisoprenoids, such as (E)-β-ionone, isoborneol and β-cyclocitral, could be potential markers indicating the ageing process of Qingke Baijiu.http://www.sciencedirect.com/science/article/pii/S2213453022001161TerpenoidsNorisoprenoidsQingke BaijiuHS-SPMEGC × GC-TOFMSPCA |
| spellingShingle | Xinlei Wang Lin Zhu Xuebo Song Si Jing Fuping Zheng Mingquan Huang Shengbao Feng Luzhong La Characterization of terpenoids and norisoprenoids from base and retail Qingke Baijiu by GC × GC-TOFMS and multivariate statistical analysis Food Science and Human Wellness Terpenoids Norisoprenoids Qingke Baijiu HS-SPME GC × GC-TOFMS PCA |
| title | Characterization of terpenoids and norisoprenoids from base and retail Qingke Baijiu by GC × GC-TOFMS and multivariate statistical analysis |
| title_full | Characterization of terpenoids and norisoprenoids from base and retail Qingke Baijiu by GC × GC-TOFMS and multivariate statistical analysis |
| title_fullStr | Characterization of terpenoids and norisoprenoids from base and retail Qingke Baijiu by GC × GC-TOFMS and multivariate statistical analysis |
| title_full_unstemmed | Characterization of terpenoids and norisoprenoids from base and retail Qingke Baijiu by GC × GC-TOFMS and multivariate statistical analysis |
| title_short | Characterization of terpenoids and norisoprenoids from base and retail Qingke Baijiu by GC × GC-TOFMS and multivariate statistical analysis |
| title_sort | characterization of terpenoids and norisoprenoids from base and retail qingke baijiu by gc gc tofms and multivariate statistical analysis |
| topic | Terpenoids Norisoprenoids Qingke Baijiu HS-SPME GC × GC-TOFMS PCA |
| url | http://www.sciencedirect.com/science/article/pii/S2213453022001161 |
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