Study on Thermodynamic Properties of HFCs Refrigerant Mixtures

To calculate thermodynamic properties of ternary refrigerant mixtures,the binary interaction parameter of the NRTL excess Gibbs free-energy model for ten groups of HFC (hydrofluorocarbon) refrigerant mixtures were correlated by the vapor liquid equilibrium experimental data with the P-R equation of...

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Format: Article
Language:zho
Published: Journal of Refrigeration Magazines Agency Co., Ltd. 2003-01-01
Series:Zhileng xuebao
Online Access:http://www.zhilengxuebao.com/thesisDetails#10.3969/j.issn.0253-4339.2003.02.005
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collection DOAJ
description To calculate thermodynamic properties of ternary refrigerant mixtures,the binary interaction parameter of the NRTL excess Gibbs free-energy model for ten groups of HFC (hydrofluorocarbon) refrigerant mixtures were correlated by the vapor liquid equilibrium experimental data with the P-R equation of state and the Huron-Vidal original mixture rules in the study. At the same time,the vapor-liquid equilibrium of ternary refrigerant mixtures of R32/R125/R134a and R125/R143a/R134a has been predicted with determined interaction parameters.Calculated results showed a good agreement with the experimental data,especially the average deviations of bubble point pressure were less than 0.42%.At last,the characteristics of the refrigeration cycle with R32/R125 and R407c are analyzed and discussed.
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spelling doaj.art-3977a0cf4b8540ab902f5551eefa91cc2025-03-04T09:40:08ZzhoJournal of Refrigeration Magazines Agency Co., Ltd.Zhileng xuebao0253-43392003-01-012471524054Study on Thermodynamic Properties of HFCs Refrigerant MixturesTo calculate thermodynamic properties of ternary refrigerant mixtures,the binary interaction parameter of the NRTL excess Gibbs free-energy model for ten groups of HFC (hydrofluorocarbon) refrigerant mixtures were correlated by the vapor liquid equilibrium experimental data with the P-R equation of state and the Huron-Vidal original mixture rules in the study. At the same time,the vapor-liquid equilibrium of ternary refrigerant mixtures of R32/R125/R134a and R125/R143a/R134a has been predicted with determined interaction parameters.Calculated results showed a good agreement with the experimental data,especially the average deviations of bubble point pressure were less than 0.42%.At last,the characteristics of the refrigeration cycle with R32/R125 and R407c are analyzed and discussed.http://www.zhilengxuebao.com/thesisDetails#10.3969/j.issn.0253-4339.2003.02.005
spellingShingle Study on Thermodynamic Properties of HFCs Refrigerant Mixtures
Zhileng xuebao
title Study on Thermodynamic Properties of HFCs Refrigerant Mixtures
title_full Study on Thermodynamic Properties of HFCs Refrigerant Mixtures
title_fullStr Study on Thermodynamic Properties of HFCs Refrigerant Mixtures
title_full_unstemmed Study on Thermodynamic Properties of HFCs Refrigerant Mixtures
title_short Study on Thermodynamic Properties of HFCs Refrigerant Mixtures
title_sort study on thermodynamic properties of hfcs refrigerant mixtures
url http://www.zhilengxuebao.com/thesisDetails#10.3969/j.issn.0253-4339.2003.02.005