Recent progress in atomically precise Ag/Cu-based hydride clusters
Owing to advantages in synthesis, separation, structure determination, and low cost (compared to noble metal nanoclusters), Ag/Cu hydride clusters (and their alloys) have received increasing research interest in recent decades and have shown great potential in mediating reduction reactions and H2 st...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Tsinghua University Press
2024-06-01
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| Series: | Polyoxometalates |
| Subjects: | |
| Online Access: | https://www.sciopen.com/article/10.26599/POM.2023.9140050 |
| _version_ | 1797202588630777856 |
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| author | Ying Lv Tingting Jiang Qianli Zhang Haizhu Yu Manzhou Zhu |
| author_facet | Ying Lv Tingting Jiang Qianli Zhang Haizhu Yu Manzhou Zhu |
| author_sort | Ying Lv |
| collection | DOAJ |
| description | Owing to advantages in synthesis, separation, structure determination, and low cost (compared to noble metal nanoclusters), Ag/Cu hydride clusters (and their alloys) have received increasing research interest in recent decades and have shown great potential in mediating reduction reactions and H2 storage applications. The atomic precision of the Ag/Cu hydride clusters with the combination of single-crystal X-ray diffraction, 1/2H nuclear magnetic resonance, electrospray ionization mass spectrometry, density functional theory, and particularly, single-crystal neutron diffraction, has provided pivotal information regarding its structural characteristics, facilitating a deep understanding of the inherent bonding principles therein. This review summarizes the research progress of atomically precise Ag/Cu hydride clusters (and their alloys) over the past three years (2021–2023), mainly focusing on the synthesis, structure analysis, and catalytic applications of the hydride clusters. We believe that this review can benefit the future design of different types of metal hydride clusters and aid in their application in various redox reactions. |
| first_indexed | 2024-04-24T08:05:50Z |
| format | Article |
| id | doaj.art-399027c00681467e80af6209ffb663e9 |
| institution | Directory Open Access Journal |
| issn | 2957-9821 2957-9503 |
| language | English |
| last_indexed | 2024-04-24T08:05:50Z |
| publishDate | 2024-06-01 |
| publisher | Tsinghua University Press |
| record_format | Article |
| series | Polyoxometalates |
| spelling | doaj.art-399027c00681467e80af6209ffb663e92024-04-17T10:43:37ZengTsinghua University PressPolyoxometalates2957-98212957-95032024-06-0132914005010.26599/POM.2023.9140050Recent progress in atomically precise Ag/Cu-based hydride clustersYing Lv0Tingting Jiang1Qianli Zhang2Haizhu Yu3https://orcid.org/0000-0001-8259-6466Manzhou Zhu4Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Anhui University, Hefei 230601, ChinaDepartment of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Anhui University, Hefei 230601, ChinaDepartment of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Anhui University, Hefei 230601, ChinaDepartment of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Anhui University, Hefei 230601, ChinaDepartment of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Anhui University, Hefei 230601, ChinaOwing to advantages in synthesis, separation, structure determination, and low cost (compared to noble metal nanoclusters), Ag/Cu hydride clusters (and their alloys) have received increasing research interest in recent decades and have shown great potential in mediating reduction reactions and H2 storage applications. The atomic precision of the Ag/Cu hydride clusters with the combination of single-crystal X-ray diffraction, 1/2H nuclear magnetic resonance, electrospray ionization mass spectrometry, density functional theory, and particularly, single-crystal neutron diffraction, has provided pivotal information regarding its structural characteristics, facilitating a deep understanding of the inherent bonding principles therein. This review summarizes the research progress of atomically precise Ag/Cu hydride clusters (and their alloys) over the past three years (2021–2023), mainly focusing on the synthesis, structure analysis, and catalytic applications of the hydride clusters. We believe that this review can benefit the future design of different types of metal hydride clusters and aid in their application in various redox reactions.https://www.sciopen.com/article/10.26599/POM.2023.9140050ag/cu hydride clusterssynthesischaracterizationstructure analysiscatalytic application |
| spellingShingle | Ying Lv Tingting Jiang Qianli Zhang Haizhu Yu Manzhou Zhu Recent progress in atomically precise Ag/Cu-based hydride clusters Polyoxometalates ag/cu hydride clusters synthesis characterization structure analysis catalytic application |
| title | Recent progress in atomically precise Ag/Cu-based hydride clusters |
| title_full | Recent progress in atomically precise Ag/Cu-based hydride clusters |
| title_fullStr | Recent progress in atomically precise Ag/Cu-based hydride clusters |
| title_full_unstemmed | Recent progress in atomically precise Ag/Cu-based hydride clusters |
| title_short | Recent progress in atomically precise Ag/Cu-based hydride clusters |
| title_sort | recent progress in atomically precise ag cu based hydride clusters |
| topic | ag/cu hydride clusters synthesis characterization structure analysis catalytic application |
| url | https://www.sciopen.com/article/10.26599/POM.2023.9140050 |
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