Redetermination of heptapotassium nonahydrogen bis[α-hexamolybdoplatinate(IV)] undecahydrate
Previously reported at a temperature of 298 (2) K [Lee & Joo (2007). Acta Cryst. E63, i11–i13], the title compound, K7[H9α-Pt2Mo12O48]·11H2O or K7[H4.5α-PtMo6O24]2·11H2O, was redetermined at 146...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810008639 |
| _version_ | 1828855985874141184 |
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| author | Ki-Min Park Uk Lee Hea-Chung Joo |
| author_facet | Ki-Min Park Uk Lee Hea-Chung Joo |
| author_sort | Ki-Min Park |
| collection | DOAJ |
| description | Previously reported at a temperature of 298 (2) K [Lee & Joo (2007). Acta Cryst. E63, i11–i13], the title compound, K7[H9α-Pt2Mo12O48]·11H2O or K7[H4.5α-PtMo6O24]2·11H2O, was redetermined at 146 (2) K in order to determine whether the H atom in the hydrogen bond that crosses the center of symmetry was located at the center of symmetry or disordered around it as assumed in the previous study. During the present low-temperature study it was found on the center of symmetry. One water molecule shows half-occupancy. |
| first_indexed | 2024-12-13T01:05:00Z |
| format | Article |
| id | doaj.art-3990f2875b5e4e9797835d301f593506 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T01:05:00Z |
| publishDate | 2010-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-3990f2875b5e4e9797835d301f5935062022-12-22T00:04:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664i25i2510.1107/S1600536810008639Redetermination of heptapotassium nonahydrogen bis[α-hexamolybdoplatinate(IV)] undecahydrateKi-Min ParkUk LeeHea-Chung JooPreviously reported at a temperature of 298 (2) K [Lee & Joo (2007). Acta Cryst. E63, i11–i13], the title compound, K7[H9α-Pt2Mo12O48]·11H2O or K7[H4.5α-PtMo6O24]2·11H2O, was redetermined at 146 (2) K in order to determine whether the H atom in the hydrogen bond that crosses the center of symmetry was located at the center of symmetry or disordered around it as assumed in the previous study. During the present low-temperature study it was found on the center of symmetry. One water molecule shows half-occupancy.http://scripts.iucr.org/cgi-bin/paper?S1600536810008639 |
| spellingShingle | Ki-Min Park Uk Lee Hea-Chung Joo Redetermination of heptapotassium nonahydrogen bis[α-hexamolybdoplatinate(IV)] undecahydrate Acta Crystallographica Section E |
| title | Redetermination of heptapotassium nonahydrogen bis[α-hexamolybdoplatinate(IV)] undecahydrate |
| title_full | Redetermination of heptapotassium nonahydrogen bis[α-hexamolybdoplatinate(IV)] undecahydrate |
| title_fullStr | Redetermination of heptapotassium nonahydrogen bis[α-hexamolybdoplatinate(IV)] undecahydrate |
| title_full_unstemmed | Redetermination of heptapotassium nonahydrogen bis[α-hexamolybdoplatinate(IV)] undecahydrate |
| title_short | Redetermination of heptapotassium nonahydrogen bis[α-hexamolybdoplatinate(IV)] undecahydrate |
| title_sort | redetermination of heptapotassium nonahydrogen bis amp 945 hexamolybdoplatinate iv undecahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810008639 |
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