Efficacy of Catalysts in the Batch Esterification of the Fatty Acids of Thevetia Peruviana Seed Oil

The methyl, ethyl, propyl and butyl esters of the fatty acids of Thevetia peruviana seed oil were successfully prepared by the batch-esterification procedures. Various acid catalyst and various molar ratios of fatty acid to alcohol were investigated. H3PO4 was found to be ineffective to catalyze the...

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Main Authors: O O Oluwaniyi, S A Ibiyemi
Format: Article
Language:English
Published: Joint Coordination Centre of the World Bank assisted National Agricultural Research Programme (NARP) 2004-02-01
Series:Journal of Applied Sciences and Environmental Management
Online Access:https://www.ajol.info/index.php/jasem/article/view/17160
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author O O Oluwaniyi
S A Ibiyemi
author_facet O O Oluwaniyi
S A Ibiyemi
author_sort O O Oluwaniyi
collection DOAJ
description The methyl, ethyl, propyl and butyl esters of the fatty acids of Thevetia peruviana seed oil were successfully prepared by the batch-esterification procedures. Various acid catalyst and various molar ratios of fatty acid to alcohol were investigated. H3PO4 was found to be ineffective to catalyze the esterification of the free fatty acid. HCl gas and conc. H2SO4 both proved very effective in catalyzing the reaction. Concentrated H2SO4 however, proved better of the two acids. Three molar ratios 1:1, 1:3 and 1:10 were investigated, 1:3 molar ratio of the free fatty acid to the alcohol was found to be the most efficient. (Journal of Applied Sciences & Environmental Management: 2003 7(1): 15-18)
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spelling doaj.art-39b39f1c5daf4eb999e55a657aeb8bce2024-04-02T19:55:15ZengJoint Coordination Centre of the World Bank assisted National Agricultural Research Programme (NARP)Journal of Applied Sciences and Environmental Management2659-15022659-14992004-02-017110.4314/jasem.v7i1.17160Efficacy of Catalysts in the Batch Esterification of the Fatty Acids of Thevetia Peruviana Seed OilO O OluwaniyiS A IbiyemiThe methyl, ethyl, propyl and butyl esters of the fatty acids of Thevetia peruviana seed oil were successfully prepared by the batch-esterification procedures. Various acid catalyst and various molar ratios of fatty acid to alcohol were investigated. H3PO4 was found to be ineffective to catalyze the esterification of the free fatty acid. HCl gas and conc. H2SO4 both proved very effective in catalyzing the reaction. Concentrated H2SO4 however, proved better of the two acids. Three molar ratios 1:1, 1:3 and 1:10 were investigated, 1:3 molar ratio of the free fatty acid to the alcohol was found to be the most efficient. (Journal of Applied Sciences & Environmental Management: 2003 7(1): 15-18)https://www.ajol.info/index.php/jasem/article/view/17160
spellingShingle O O Oluwaniyi
S A Ibiyemi
Efficacy of Catalysts in the Batch Esterification of the Fatty Acids of Thevetia Peruviana Seed Oil
Journal of Applied Sciences and Environmental Management
title Efficacy of Catalysts in the Batch Esterification of the Fatty Acids of Thevetia Peruviana Seed Oil
title_full Efficacy of Catalysts in the Batch Esterification of the Fatty Acids of Thevetia Peruviana Seed Oil
title_fullStr Efficacy of Catalysts in the Batch Esterification of the Fatty Acids of Thevetia Peruviana Seed Oil
title_full_unstemmed Efficacy of Catalysts in the Batch Esterification of the Fatty Acids of Thevetia Peruviana Seed Oil
title_short Efficacy of Catalysts in the Batch Esterification of the Fatty Acids of Thevetia Peruviana Seed Oil
title_sort efficacy of catalysts in the batch esterification of the fatty acids of thevetia peruviana seed oil
url https://www.ajol.info/index.php/jasem/article/view/17160
work_keys_str_mv AT oooluwaniyi efficacyofcatalystsinthebatchesterificationofthefattyacidsofthevetiaperuvianaseedoil
AT saibiyemi efficacyofcatalystsinthebatchesterificationofthefattyacidsofthevetiaperuvianaseedoil