Pushing the thinness limit of silver films for flexible optoelectronic devices via ion-beam thinning-back process

Abstract Reducing the silver film to 10 nm theoretically allows higher transparency but in practice leads to degraded transparency and electrical conductivity because the ultrathin film tends to be discontinuous. Herein, we developed a thinning-back process to address this dilemma, in which silver f...

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Main Authors: Dongxu Ma, Ming Ji, Hongbo Yi, Qingyu Wang, Fu Fan, Bo Feng, Mengjie Zheng, Yiqin Chen, Huigao Duan
Format: Article
Language:English
Published: Nature Portfolio 2024-03-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-024-46467-6
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author Dongxu Ma
Ming Ji
Hongbo Yi
Qingyu Wang
Fu Fan
Bo Feng
Mengjie Zheng
Yiqin Chen
Huigao Duan
author_facet Dongxu Ma
Ming Ji
Hongbo Yi
Qingyu Wang
Fu Fan
Bo Feng
Mengjie Zheng
Yiqin Chen
Huigao Duan
author_sort Dongxu Ma
collection DOAJ
description Abstract Reducing the silver film to 10 nm theoretically allows higher transparency but in practice leads to degraded transparency and electrical conductivity because the ultrathin film tends to be discontinuous. Herein, we developed a thinning-back process to address this dilemma, in which silver film is first deposited to a larger thickness with high continuity and then thinned back to a reduced thickness with an ultrasmooth surface, both implemented by a flood ion beam. Contributed by the shallow implantation of silver atoms into the substrate during deposition, the thinness of silver films down to 4.5 nm can be obtained, thinner than ever before. The atomic-level surface smooth permits excellent visible transparency, electrical conductivity, and the lowest haze among all existing transparent conductors. Moreover, the ultrathin silver film exhibits the unique robustness of mechanical flexibility. Therefore, the ion-beam thinning-back process presents a promising solution towards the excellent transparent conductor for flexible optoelectronic devices.
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spelling doaj.art-39cc25e4ef3d4930ab881b6cd175f07c2024-03-24T12:25:24ZengNature PortfolioNature Communications2041-17232024-03-011511910.1038/s41467-024-46467-6Pushing the thinness limit of silver films for flexible optoelectronic devices via ion-beam thinning-back processDongxu Ma0Ming Ji1Hongbo Yi2Qingyu Wang3Fu Fan4Bo Feng5Mengjie Zheng6Yiqin Chen7Huigao Duan8College of Mechanical and Vehicle Engineering, Hunan UniversityIBD Technology Co., Ltd.IBD Technology Co., Ltd.College of Mechanical and Vehicle Engineering, Hunan UniversityCollege of Mechanical and Vehicle Engineering, Hunan UniversityCollege of Mechanical and Vehicle Engineering, Hunan UniversityJihua LaboratoryCollege of Mechanical and Vehicle Engineering, Hunan UniversityCollege of Mechanical and Vehicle Engineering, Hunan UniversityAbstract Reducing the silver film to 10 nm theoretically allows higher transparency but in practice leads to degraded transparency and electrical conductivity because the ultrathin film tends to be discontinuous. Herein, we developed a thinning-back process to address this dilemma, in which silver film is first deposited to a larger thickness with high continuity and then thinned back to a reduced thickness with an ultrasmooth surface, both implemented by a flood ion beam. Contributed by the shallow implantation of silver atoms into the substrate during deposition, the thinness of silver films down to 4.5 nm can be obtained, thinner than ever before. The atomic-level surface smooth permits excellent visible transparency, electrical conductivity, and the lowest haze among all existing transparent conductors. Moreover, the ultrathin silver film exhibits the unique robustness of mechanical flexibility. Therefore, the ion-beam thinning-back process presents a promising solution towards the excellent transparent conductor for flexible optoelectronic devices.https://doi.org/10.1038/s41467-024-46467-6
spellingShingle Dongxu Ma
Ming Ji
Hongbo Yi
Qingyu Wang
Fu Fan
Bo Feng
Mengjie Zheng
Yiqin Chen
Huigao Duan
Pushing the thinness limit of silver films for flexible optoelectronic devices via ion-beam thinning-back process
Nature Communications
title Pushing the thinness limit of silver films for flexible optoelectronic devices via ion-beam thinning-back process
title_full Pushing the thinness limit of silver films for flexible optoelectronic devices via ion-beam thinning-back process
title_fullStr Pushing the thinness limit of silver films for flexible optoelectronic devices via ion-beam thinning-back process
title_full_unstemmed Pushing the thinness limit of silver films for flexible optoelectronic devices via ion-beam thinning-back process
title_short Pushing the thinness limit of silver films for flexible optoelectronic devices via ion-beam thinning-back process
title_sort pushing the thinness limit of silver films for flexible optoelectronic devices via ion beam thinning back process
url https://doi.org/10.1038/s41467-024-46467-6
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