Giant dielectric properties of CaCu3Ti4O12 ceramics synthesized by solid state reaction route

CaCu3Ti4O12 (CCTO) ceramics were prepared by solid-state reaction route, calcination at 1050°C for 4 h and sintering at 1050 and 1100°C for 8 h. X-ray diffraction and Raman studies of the CCTO powders and sintered samples confirmed the formation of single phase cubic structure with small amount of C...

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Main Authors: Kajal Parida A.P., Kumar Pawan
Format: Article
Language:English
Published: University of Novi Sad 2023-12-01
Series:Processing and Application of Ceramics
Subjects:
Online Access:https://doiserbia.nb.rs/img/doi/1820-6131/2023/1820-61312304393K.pdf
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author Kajal Parida A.P.
Kumar Pawan
author_facet Kajal Parida A.P.
Kumar Pawan
author_sort Kajal Parida A.P.
collection DOAJ
description CaCu3Ti4O12 (CCTO) ceramics were prepared by solid-state reaction route, calcination at 1050°C for 4 h and sintering at 1050 and 1100°C for 8 h. X-ray diffraction and Raman studies of the CCTO powders and sintered samples confirmed the formation of single phase cubic structure with small amount of CuO in the sintered ceramics. Scanning electron microscope study revealed the average grain size between ~6 μm to ~29 μm in the CCTO ceramics sintered at 1100°C. Room temperature giant dielectric constant (εr) of the order of ~105 with relatively low dielectric loss at 100Hz frequency was obtained in the CCTO ceramics sintered at 1100°C. The present study has revealed that grain size plays an important role in enhancing the dielectric properties of CCTO ceramics.
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spelling doaj.art-39e1d738f9ab4c999a28d74592f9328d2024-02-01T13:28:04ZengUniversity of Novi SadProcessing and Application of Ceramics1820-61312406-10342023-12-0117439339910.2298/PAC2304393KGiant dielectric properties of CaCu3Ti4O12 ceramics synthesized by solid state reaction routeKajal Parida A.P.0Kumar Pawan1Department of Physics and Astronomy, National institute of Technology Rourkela, Rourkela, IndiaDepartment of Physics and Astronomy, National institute of Technology Rourkela, Rourkela, IndiaCaCu3Ti4O12 (CCTO) ceramics were prepared by solid-state reaction route, calcination at 1050°C for 4 h and sintering at 1050 and 1100°C for 8 h. X-ray diffraction and Raman studies of the CCTO powders and sintered samples confirmed the formation of single phase cubic structure with small amount of CuO in the sintered ceramics. Scanning electron microscope study revealed the average grain size between ~6 μm to ~29 μm in the CCTO ceramics sintered at 1100°C. Room temperature giant dielectric constant (εr) of the order of ~105 with relatively low dielectric loss at 100Hz frequency was obtained in the CCTO ceramics sintered at 1100°C. The present study has revealed that grain size plays an important role in enhancing the dielectric properties of CCTO ceramics.https://doiserbia.nb.rs/img/doi/1820-6131/2023/1820-61312304393K.pdfcacu3ti4o12structure characterizationdielectric properties
spellingShingle Kajal Parida A.P.
Kumar Pawan
Giant dielectric properties of CaCu3Ti4O12 ceramics synthesized by solid state reaction route
Processing and Application of Ceramics
cacu3ti4o12
structure characterization
dielectric properties
title Giant dielectric properties of CaCu3Ti4O12 ceramics synthesized by solid state reaction route
title_full Giant dielectric properties of CaCu3Ti4O12 ceramics synthesized by solid state reaction route
title_fullStr Giant dielectric properties of CaCu3Ti4O12 ceramics synthesized by solid state reaction route
title_full_unstemmed Giant dielectric properties of CaCu3Ti4O12 ceramics synthesized by solid state reaction route
title_short Giant dielectric properties of CaCu3Ti4O12 ceramics synthesized by solid state reaction route
title_sort giant dielectric properties of cacu3ti4o12 ceramics synthesized by solid state reaction route
topic cacu3ti4o12
structure characterization
dielectric properties
url https://doiserbia.nb.rs/img/doi/1820-6131/2023/1820-61312304393K.pdf
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