Superconducting Ti15Zr15Nb35Ta35 High-Entropy Alloy With Intermediate Electron-Phonon Coupling

The body-centered cubic (BCC) Ti15Zr15Nb35Ta35 high-entropy alloy showed superconducting behavior at around 8 K. The electronic specific heat coefficient γ and the lattice specific heat coefficient β were determined to be γ = 9.3 ± 0.1 mJ/mol K2 and β = 0.28 ± 0.01 mJ/mol K4, respectively. It was fo...

Full description

Bibliographic Details
Main Authors: Yuan Yuan, Yuan Wu, Huiqian Luo, Zhaosheng Wang, Xue Liang, Zhi Yang, Hui Wang, Xiongjun Liu, Zhaoping Lu
Format: Article
Language:English
Published: Frontiers Media S.A. 2018-11-01
Series:Frontiers in Materials
Subjects:
Online Access:https://www.frontiersin.org/article/10.3389/fmats.2018.00072/full
Description
Summary:The body-centered cubic (BCC) Ti15Zr15Nb35Ta35 high-entropy alloy showed superconducting behavior at around 8 K. The electronic specific heat coefficient γ and the lattice specific heat coefficient β were determined to be γ = 9.3 ± 0.1 mJ/mol K2 and β = 0.28 ± 0.01 mJ/mol K4, respectively. It was found that the electronic specific heat Ces does follow the exponential behavior of the Bardeen-Cooper-Schrieffer (BCS) theory. Nevertheless, the specific heat jump (ΔC/γTc) at the superconducting transition temperature which was determined to be 1.71 deviates appreciably from that for a weak electron-phonon coupling BCS superconductor. Within the framework of the strong-coupled theory, our analysis suggests that theTi15Zr15Nb35Ta35 HEA is an intermediate electron-phonon coupled BCS-type superconductor.
ISSN:2296-8016