CCl<sub>4</sub>-TMEDA-CuCl—A Novel Convenient Catalytic System for Dimerization of Terminal Acetylenes in Mild Conditions

CCl<sub>4</sub>-TMEDA-CuCl—A Novel Convenient Catalytic System for Dimerization of Terminal Acetylenes in Mild Conditions

A novel catalytic system for homocoupling terminal acetylenes was elaborated based on CuCl as a catalyst (10 mol%), TMEDA as a base and CCl<sub>4</sub> as an oxidant. The influence of the solvent, base, amount of catalyst and CCl<sub>4</sub> on the reaction was investigated....

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Bibliographic Details
Main Authors: Vasiliy M. Muzalevskiy, Alexey V. Shastin, Sarvinoz I. Tirkasheva, Odiljon E. Ziyadullaev, Askar B. Parmanov, Valentine G. Nenajdenko
Format: Article
Language:English
Published: MDPI AG 2023-09-01
Series:Catalysts
Subjects:
tetrachloromethane
acetylene
oxidative homocoupling
diyne
copper
Online Access:https://www.mdpi.com/2073-4344/13/10/1330

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