Mixed Carbon Nanomaterial/Epoxy Resin for Electrically Conductive Adhesives

The increasing complexity of printed circuit boards (PCBs) due to miniaturization, increased the density of electronic components, and demanding thermal management during the assembly triggered the research of innovative solder pastes and electrically conductive adhesives (ECAs). Current commercial...

Full description

Bibliographic Details
Main Authors: Paulo E. Lopes, Duarte Moura, Loic Hilliou, Beate Krause, Petra Pötschke, Hugo Figueiredo, Ricardo Alves, Emmanuel Lepleux, Louis Pacheco, Maria C. Paiva
Format: Article
Language:English
Published: MDPI AG 2020-08-01
Series:Journal of Composites Science
Subjects:
Online Access:https://www.mdpi.com/2504-477X/4/3/105
_version_ 1797560527299280896
author Paulo E. Lopes
Duarte Moura
Loic Hilliou
Beate Krause
Petra Pötschke
Hugo Figueiredo
Ricardo Alves
Emmanuel Lepleux
Louis Pacheco
Maria C. Paiva
author_facet Paulo E. Lopes
Duarte Moura
Loic Hilliou
Beate Krause
Petra Pötschke
Hugo Figueiredo
Ricardo Alves
Emmanuel Lepleux
Louis Pacheco
Maria C. Paiva
author_sort Paulo E. Lopes
collection DOAJ
description The increasing complexity of printed circuit boards (PCBs) due to miniaturization, increased the density of electronic components, and demanding thermal management during the assembly triggered the research of innovative solder pastes and electrically conductive adhesives (ECAs). Current commercial ECAs are typically based on epoxy matrices with a high load (>60%) of silver particles, generally in the form of microflakes. The present work reports the production of ECAs based on epoxy/carbon nanomaterials using carbon nanotubes (single and multi-walled) and exfoliated graphite, as well as hybrid compositions, within a range of concentrations. The composites were tested for morphology (dispersion of the conductive nanomaterials), electrical and thermal conductivity, rheological characteristics and deposition on a test PCB. Finally, the ECA’s shelf life was assessed by mixing all the components and conductive nanomaterials, and evaluating the cure of the resin before and after freezing for a time range up to nine months. The ECAs produced could be stored at −18 °C without affecting the cure reaction.
first_indexed 2024-03-10T18:01:58Z
format Article
id doaj.art-39f6e4f36ae04a12b7ac120784b2b19a
institution Directory Open Access Journal
issn 2504-477X
language English
last_indexed 2024-03-10T18:01:58Z
publishDate 2020-08-01
publisher MDPI AG
record_format Article
series Journal of Composites Science
spelling doaj.art-39f6e4f36ae04a12b7ac120784b2b19a2023-11-20T08:48:06ZengMDPI AGJournal of Composites Science2504-477X2020-08-014310510.3390/jcs4030105Mixed Carbon Nanomaterial/Epoxy Resin for Electrically Conductive AdhesivesPaulo E. Lopes0Duarte Moura1Loic Hilliou2Beate Krause3Petra Pötschke4Hugo Figueiredo5Ricardo Alves6Emmanuel Lepleux7Louis Pacheco8Maria C. Paiva9Instituto de Polímeros e Compósitos (IPC), Universidade do Minho, 4804-533 Guimarães, PortugalInstituto de Polímeros e Compósitos (IPC), Universidade do Minho, 4804-533 Guimarães, PortugalInstituto de Polímeros e Compósitos (IPC), Universidade do Minho, 4804-533 Guimarães, PortugalLeibniz Institute of Polymer Research Dresden (IPF Dresden), Hohe Str 6, D-01069 Dresden, GermanyLeibniz Institute of Polymer Research Dresden (IPF Dresden), Hohe Str 6, D-01069 Dresden, GermanyCM/MFT3 Bosch, 4705-820 Braga, PortugalCM/MFT3 Bosch, 4705-820 Braga, PortugalConcept Scientific Instruments (CSI), 1 Terre de Feu, 91940 Les Ulis, FranceConcept Scientific Instruments (CSI), 1 Terre de Feu, 91940 Les Ulis, FranceInstituto de Polímeros e Compósitos (IPC), Universidade do Minho, 4804-533 Guimarães, PortugalThe increasing complexity of printed circuit boards (PCBs) due to miniaturization, increased the density of electronic components, and demanding thermal management during the assembly triggered the research of innovative solder pastes and electrically conductive adhesives (ECAs). Current commercial ECAs are typically based on epoxy matrices with a high load (>60%) of silver particles, generally in the form of microflakes. The present work reports the production of ECAs based on epoxy/carbon nanomaterials using carbon nanotubes (single and multi-walled) and exfoliated graphite, as well as hybrid compositions, within a range of concentrations. The composites were tested for morphology (dispersion of the conductive nanomaterials), electrical and thermal conductivity, rheological characteristics and deposition on a test PCB. Finally, the ECA’s shelf life was assessed by mixing all the components and conductive nanomaterials, and evaluating the cure of the resin before and after freezing for a time range up to nine months. The ECAs produced could be stored at −18 °C without affecting the cure reaction.https://www.mdpi.com/2504-477X/4/3/105ECA electrically conductive adhesivecarbon nanotubesexfoliated graphiteelectronic packagingepoxy
spellingShingle Paulo E. Lopes
Duarte Moura
Loic Hilliou
Beate Krause
Petra Pötschke
Hugo Figueiredo
Ricardo Alves
Emmanuel Lepleux
Louis Pacheco
Maria C. Paiva
Mixed Carbon Nanomaterial/Epoxy Resin for Electrically Conductive Adhesives
Journal of Composites Science
ECA electrically conductive adhesive
carbon nanotubes
exfoliated graphite
electronic packaging
epoxy
title Mixed Carbon Nanomaterial/Epoxy Resin for Electrically Conductive Adhesives
title_full Mixed Carbon Nanomaterial/Epoxy Resin for Electrically Conductive Adhesives
title_fullStr Mixed Carbon Nanomaterial/Epoxy Resin for Electrically Conductive Adhesives
title_full_unstemmed Mixed Carbon Nanomaterial/Epoxy Resin for Electrically Conductive Adhesives
title_short Mixed Carbon Nanomaterial/Epoxy Resin for Electrically Conductive Adhesives
title_sort mixed carbon nanomaterial epoxy resin for electrically conductive adhesives
topic ECA electrically conductive adhesive
carbon nanotubes
exfoliated graphite
electronic packaging
epoxy
url https://www.mdpi.com/2504-477X/4/3/105
work_keys_str_mv AT pauloelopes mixedcarbonnanomaterialepoxyresinforelectricallyconductiveadhesives
AT duartemoura mixedcarbonnanomaterialepoxyresinforelectricallyconductiveadhesives
AT loichilliou mixedcarbonnanomaterialepoxyresinforelectricallyconductiveadhesives
AT beatekrause mixedcarbonnanomaterialepoxyresinforelectricallyconductiveadhesives
AT petrapotschke mixedcarbonnanomaterialepoxyresinforelectricallyconductiveadhesives
AT hugofigueiredo mixedcarbonnanomaterialepoxyresinforelectricallyconductiveadhesives
AT ricardoalves mixedcarbonnanomaterialepoxyresinforelectricallyconductiveadhesives
AT emmanuellepleux mixedcarbonnanomaterialepoxyresinforelectricallyconductiveadhesives
AT louispacheco mixedcarbonnanomaterialepoxyresinforelectricallyconductiveadhesives
AT mariacpaiva mixedcarbonnanomaterialepoxyresinforelectricallyconductiveadhesives