(2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmethyl)-5-phenylpent-4-enoate
The title compound, C27H30O6, was prepared by monodihydroxylation of the bis-olefin (E,E)-tert-butyl 2-acetyl-2-cinnamyl-5-phenylpent-4-enoate using standard Sharpless asymmetric dihydroxylation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-02-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808002651 |
| _version_ | 1818321834676846592 |
|---|---|
| author | Stuart Warren Daniel Sejer Pedersen David J. Fox |
| author_facet | Stuart Warren Daniel Sejer Pedersen David J. Fox |
| author_sort | Stuart Warren |
| collection | DOAJ |
| description | The title compound, C27H30O6, was prepared by monodihydroxylation of the bis-olefin (E,E)-tert-butyl 2-acetyl-2-cinnamyl-5-phenylpent-4-enoate using standard Sharpless asymmetric dihydroxylation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the phenyl rings form an intramolecular edge-to-face C—H...π contact with an interplanar angle of 56.4° and a H...centroid distance of 3.03 Å. |
| first_indexed | 2024-12-13T10:47:12Z |
| format | Article |
| id | doaj.art-3a0fb75febbb451bae0d303d862cc538 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:47:12Z |
| publishDate | 2008-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-3a0fb75febbb451bae0d303d862cc5382022-12-21T23:50:06ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642o530o53010.1107/S1600536808002651(2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmethyl)-5-phenylpent-4-enoateStuart WarrenDaniel Sejer PedersenDavid J. FoxThe title compound, C27H30O6, was prepared by monodihydroxylation of the bis-olefin (E,E)-tert-butyl 2-acetyl-2-cinnamyl-5-phenylpent-4-enoate using standard Sharpless asymmetric dihydroxylation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the phenyl rings form an intramolecular edge-to-face C—H...π contact with an interplanar angle of 56.4° and a H...centroid distance of 3.03 Å.http://scripts.iucr.org/cgi-bin/paper?S1600536808002651 |
| spellingShingle | Stuart Warren Daniel Sejer Pedersen David J. Fox (2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmethyl)-5-phenylpent-4-enoate Acta Crystallographica Section E |
| title | (2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmethyl)-5-phenylpent-4-enoate |
| title_full | (2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmethyl)-5-phenylpent-4-enoate |
| title_fullStr | (2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmethyl)-5-phenylpent-4-enoate |
| title_full_unstemmed | (2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmethyl)-5-phenylpent-4-enoate |
| title_short | (2S,4′R,5′R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmethyl)-5-phenylpent-4-enoate |
| title_sort | 2s 4 8242 r 5 8242 r e tert butyl 2 acetyl 2 2 oxo 5 phenyl 1 3 dioxolan 4 ylmethyl 5 phenylpent 4 enoate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808002651 |
| work_keys_str_mv | AT stuartwarren 2s48242r58242retertbutyl2acetyl22oxo5phenyl13dioxolan4ylmethyl5phenylpent4enoate AT danielsejerpedersen 2s48242r58242retertbutyl2acetyl22oxo5phenyl13dioxolan4ylmethyl5phenylpent4enoate AT davidjfox 2s48242r58242retertbutyl2acetyl22oxo5phenyl13dioxolan4ylmethyl5phenylpent4enoate |