Numerical Estimation of Limiting Current Density by Focusing on Mass Transfer within Porous Spacers in an Electro-Dialysis

Estimating and increasing limiting current density (LCD) levels is of fundamental importance for the development of electrodialysis (ED) systems, and it is becoming clear that the use of porous spacers can significantly increase such LCD levels. In this study, a three-dimensional numerical simulatio...

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Main Authors: Yoshihiko Sano, Kosuke Fukagawa, Fujio Kuwahara
Format: Article
Language:English
Published: MDPI AG 2019-06-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/9/7/75
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author Yoshihiko Sano
Kosuke Fukagawa
Fujio Kuwahara
author_facet Yoshihiko Sano
Kosuke Fukagawa
Fujio Kuwahara
author_sort Yoshihiko Sano
collection DOAJ
description Estimating and increasing limiting current density (LCD) levels is of fundamental importance for the development of electrodialysis (ED) systems, and it is becoming clear that the use of porous spacers can significantly increase such LCD levels. In this study, a three-dimensional numerical simulation was proposed for evaluating the mass transfer within a porous spacer unit cell and for estimating LCD levels. It was found that our proposed method is effective for estimating the minimum value of an LCD, which is a significant factor related to the safe operation of ED systems. Furthermore, it was found that increasing the minimum effective Sherwood number provides a key to increasing LCD levels. Porous spacer design guidelines were proposed based on the numerical simulation results, after which a new spacer was introduced, designed according to those guidelines. It was found that flow disturbances on the membrane caused by porous spacer structures can lead to increases in effective Sherwood numbers and that LCD levels could be increased by eliminating the flow stagnation behind the structures on the membrane. The LCD of our new spacer was found to be higher than that of the spacers with the highest LCD levels in use at present. Therefore, we can conclude that the proposed design guidelines are effective for increasing LCD levels.
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spelling doaj.art-3a2bc5f592594a3e8beefec94bf94e432023-08-02T05:15:53ZengMDPI AGMembranes2077-03752019-06-01977510.3390/membranes9070075membranes9070075Numerical Estimation of Limiting Current Density by Focusing on Mass Transfer within Porous Spacers in an Electro-DialysisYoshihiko Sano0Kosuke Fukagawa1Fujio Kuwahara2Department of Mechanical Engineering, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, JapanDepartment of Mechanical Engineering, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, JapanDepartment of Mechanical Engineering, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, JapanEstimating and increasing limiting current density (LCD) levels is of fundamental importance for the development of electrodialysis (ED) systems, and it is becoming clear that the use of porous spacers can significantly increase such LCD levels. In this study, a three-dimensional numerical simulation was proposed for evaluating the mass transfer within a porous spacer unit cell and for estimating LCD levels. It was found that our proposed method is effective for estimating the minimum value of an LCD, which is a significant factor related to the safe operation of ED systems. Furthermore, it was found that increasing the minimum effective Sherwood number provides a key to increasing LCD levels. Porous spacer design guidelines were proposed based on the numerical simulation results, after which a new spacer was introduced, designed according to those guidelines. It was found that flow disturbances on the membrane caused by porous spacer structures can lead to increases in effective Sherwood numbers and that LCD levels could be increased by eliminating the flow stagnation behind the structures on the membrane. The LCD of our new spacer was found to be higher than that of the spacers with the highest LCD levels in use at present. Therefore, we can conclude that the proposed design guidelines are effective for increasing LCD levels.https://www.mdpi.com/2077-0375/9/7/75porous spacerlimiting current densitynumerical simulationion mass transport
spellingShingle Yoshihiko Sano
Kosuke Fukagawa
Fujio Kuwahara
Numerical Estimation of Limiting Current Density by Focusing on Mass Transfer within Porous Spacers in an Electro-Dialysis
Membranes
porous spacer
limiting current density
numerical simulation
ion mass transport
title Numerical Estimation of Limiting Current Density by Focusing on Mass Transfer within Porous Spacers in an Electro-Dialysis
title_full Numerical Estimation of Limiting Current Density by Focusing on Mass Transfer within Porous Spacers in an Electro-Dialysis
title_fullStr Numerical Estimation of Limiting Current Density by Focusing on Mass Transfer within Porous Spacers in an Electro-Dialysis
title_full_unstemmed Numerical Estimation of Limiting Current Density by Focusing on Mass Transfer within Porous Spacers in an Electro-Dialysis
title_short Numerical Estimation of Limiting Current Density by Focusing on Mass Transfer within Porous Spacers in an Electro-Dialysis
title_sort numerical estimation of limiting current density by focusing on mass transfer within porous spacers in an electro dialysis
topic porous spacer
limiting current density
numerical simulation
ion mass transport
url https://www.mdpi.com/2077-0375/9/7/75
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AT fujiokuwahara numericalestimationoflimitingcurrentdensitybyfocusingonmasstransferwithinporousspacersinanelectrodialysis