Sewage Sludge Treatment by Hydrothermal Carbonization: Feasibility Study for Sustainable Nutrient Recovery and Fuel Production

Phosphorus recovery from waste biomass is becoming increasingly important, given that phosphorus is an exhaustible non-renewable resource. For the recovery of plant nutrients and production of climate-neutral fuel from wet waste streams, hydrothermal carbonization (HTC) has been suggested as a promi...

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Main Authors: Gabriel Gerner, Luca Meyer, Rahel Wanner, Thomas Keller, Rolf Krebs
Format: Article
Language:English
Published: MDPI AG 2021-05-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/14/9/2697
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author Gabriel Gerner
Luca Meyer
Rahel Wanner
Thomas Keller
Rolf Krebs
author_facet Gabriel Gerner
Luca Meyer
Rahel Wanner
Thomas Keller
Rolf Krebs
author_sort Gabriel Gerner
collection DOAJ
description Phosphorus recovery from waste biomass is becoming increasingly important, given that phosphorus is an exhaustible non-renewable resource. For the recovery of plant nutrients and production of climate-neutral fuel from wet waste streams, hydrothermal carbonization (HTC) has been suggested as a promising technology. In this study, digested sewage sludge (DSS) was used as waste material for phosphorus and nitrogen recovery. HTC was conducted at 200 °C for 4 h, followed by phosphorus stripping (PS) or leaching (PL) at room temperature. The results showed that for PS and PL around 84% and 71% of phosphorus, as well as 53% and 54% of nitrogen, respectively, could be recovered in the liquid phase (process water and/or extract). Heavy metals were mainly transferred to the hydrochar and only <1 ppm of Cd and 21–43 ppm of Zn were found to be in the liquid phase of the acid treatments. According to the economic feasibility calculation, the HTC-treatment per dry ton DSS with an industrial-scale plant would cost around 608 USD. Between 349–406 kg of sulfuric acid are required per dry ton DSS to achieve a high yield in phosphorus recovery, which causes additional costs of 96–118 USD. Compared to current sewage sludge treatment costs in Switzerland, which range between 669 USD and 1173 USD, HTC can be an economically feasible process for DSS treatment and nutrient recovery.
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spelling doaj.art-3a43b7d6e84e4e14a38de156384b20502023-11-21T18:48:56ZengMDPI AGEnergies1996-10732021-05-01149269710.3390/en14092697Sewage Sludge Treatment by Hydrothermal Carbonization: Feasibility Study for Sustainable Nutrient Recovery and Fuel ProductionGabriel Gerner0Luca Meyer1Rahel Wanner2Thomas Keller3Rolf Krebs4Institute of Natural Resource Sciences, Campus Grüental, Zurich University of Applied Sciences (ZHAW), CH-8820 Wädenswil, SwitzerlandInstitute of Natural Resource Sciences, Campus Grüental, Zurich University of Applied Sciences (ZHAW), CH-8820 Wädenswil, SwitzerlandInstitute of Natural Resource Sciences, Campus Grüental, Zurich University of Applied Sciences (ZHAW), CH-8820 Wädenswil, SwitzerlandInstitute of Chemistry and Biotechnology, Campus Reidbach, Zurich University of Applied Sciences (ZHAW), CH-8820 Wädenswil, SwitzerlandInstitute of Natural Resource Sciences, Campus Grüental, Zurich University of Applied Sciences (ZHAW), CH-8820 Wädenswil, SwitzerlandPhosphorus recovery from waste biomass is becoming increasingly important, given that phosphorus is an exhaustible non-renewable resource. For the recovery of plant nutrients and production of climate-neutral fuel from wet waste streams, hydrothermal carbonization (HTC) has been suggested as a promising technology. In this study, digested sewage sludge (DSS) was used as waste material for phosphorus and nitrogen recovery. HTC was conducted at 200 °C for 4 h, followed by phosphorus stripping (PS) or leaching (PL) at room temperature. The results showed that for PS and PL around 84% and 71% of phosphorus, as well as 53% and 54% of nitrogen, respectively, could be recovered in the liquid phase (process water and/or extract). Heavy metals were mainly transferred to the hydrochar and only <1 ppm of Cd and 21–43 ppm of Zn were found to be in the liquid phase of the acid treatments. According to the economic feasibility calculation, the HTC-treatment per dry ton DSS with an industrial-scale plant would cost around 608 USD. Between 349–406 kg of sulfuric acid are required per dry ton DSS to achieve a high yield in phosphorus recovery, which causes additional costs of 96–118 USD. Compared to current sewage sludge treatment costs in Switzerland, which range between 669 USD and 1173 USD, HTC can be an economically feasible process for DSS treatment and nutrient recovery.https://www.mdpi.com/1996-1073/14/9/2697hydrothermal carbonizationphosphorus recoverydigested sewage sludgehydrocharnutrient recoveryclimate-neutral fuel
spellingShingle Gabriel Gerner
Luca Meyer
Rahel Wanner
Thomas Keller
Rolf Krebs
Sewage Sludge Treatment by Hydrothermal Carbonization: Feasibility Study for Sustainable Nutrient Recovery and Fuel Production
Energies
hydrothermal carbonization
phosphorus recovery
digested sewage sludge
hydrochar
nutrient recovery
climate-neutral fuel
title Sewage Sludge Treatment by Hydrothermal Carbonization: Feasibility Study for Sustainable Nutrient Recovery and Fuel Production
title_full Sewage Sludge Treatment by Hydrothermal Carbonization: Feasibility Study for Sustainable Nutrient Recovery and Fuel Production
title_fullStr Sewage Sludge Treatment by Hydrothermal Carbonization: Feasibility Study for Sustainable Nutrient Recovery and Fuel Production
title_full_unstemmed Sewage Sludge Treatment by Hydrothermal Carbonization: Feasibility Study for Sustainable Nutrient Recovery and Fuel Production
title_short Sewage Sludge Treatment by Hydrothermal Carbonization: Feasibility Study for Sustainable Nutrient Recovery and Fuel Production
title_sort sewage sludge treatment by hydrothermal carbonization feasibility study for sustainable nutrient recovery and fuel production
topic hydrothermal carbonization
phosphorus recovery
digested sewage sludge
hydrochar
nutrient recovery
climate-neutral fuel
url https://www.mdpi.com/1996-1073/14/9/2697
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AT rahelwanner sewagesludgetreatmentbyhydrothermalcarbonizationfeasibilitystudyforsustainablenutrientrecoveryandfuelproduction
AT thomaskeller sewagesludgetreatmentbyhydrothermalcarbonizationfeasibilitystudyforsustainablenutrientrecoveryandfuelproduction
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