Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts
Abstract The electrochemical behavior of rhodium at low-temperature carbamide-chloride and acetamide-chloride melts was investigated. It was found that, during rhodium anodic dissolution in carbamide and acetamide containing chloride melts, mixed complexes [Rh(NH3)4Cl2]+ of quasi-octahedral symmetry...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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SpringerOpen
2017-05-01
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| Series: | Nanoscale Research Letters |
| Subjects: | |
| Online Access: | http://link.springer.com/article/10.1186/s11671-017-2108-7 |
| _version_ | 1797716174465662976 |
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| author | Svetlana Kochetova Anastasiya Savchuk Dmytro Shakhnin Viktor Malyshev |
| author_facet | Svetlana Kochetova Anastasiya Savchuk Dmytro Shakhnin Viktor Malyshev |
| author_sort | Svetlana Kochetova |
| collection | DOAJ |
| description | Abstract The electrochemical behavior of rhodium at low-temperature carbamide-chloride and acetamide-chloride melts was investigated. It was found that, during rhodium anodic dissolution in carbamide and acetamide containing chloride melts, mixed complexes [Rh(NH3)4Cl2]+ of quasi-octahedral symmetry D4h are produced. The composition and structure of nascent complex ions have been studied. During electrochemical reduction of [Rh(NH3)4Cl2]+ complexes, the synthesis of Rh nanoparticles, as well as Fe, Cu, and Mo nanocoatings, were realized. |
| first_indexed | 2024-03-12T08:17:40Z |
| format | Article |
| id | doaj.art-3a4db4e73f65461591342d0b2b9a9bc1 |
| institution | Directory Open Access Journal |
| issn | 1931-7573 1556-276X |
| language | English |
| last_indexed | 2024-03-12T08:17:40Z |
| publishDate | 2017-05-01 |
| publisher | SpringerOpen |
| record_format | Article |
| series | Nanoscale Research Letters |
| spelling | doaj.art-3a4db4e73f65461591342d0b2b9a9bc12023-09-02T18:43:13ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2017-05-011211510.1186/s11671-017-2108-7Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing MeltsSvetlana Kochetova0Anastasiya Savchuk1Dmytro Shakhnin2Viktor Malyshev3Vernadsky Institute of General and Inorganic ChemistryVernadsky Institute of General and Inorganic ChemistryVernadsky Institute of General and Inorganic ChemistryVernadsky Institute of General and Inorganic ChemistryAbstract The electrochemical behavior of rhodium at low-temperature carbamide-chloride and acetamide-chloride melts was investigated. It was found that, during rhodium anodic dissolution in carbamide and acetamide containing chloride melts, mixed complexes [Rh(NH3)4Cl2]+ of quasi-octahedral symmetry D4h are produced. The composition and structure of nascent complex ions have been studied. During electrochemical reduction of [Rh(NH3)4Cl2]+ complexes, the synthesis of Rh nanoparticles, as well as Fe, Cu, and Mo nanocoatings, were realized.http://link.springer.com/article/10.1186/s11671-017-2108-7NanoparticlesNanocoatingsRhodiumElectrochemical behaviorSynthesisLow-temperature melts |
| spellingShingle | Svetlana Kochetova Anastasiya Savchuk Dmytro Shakhnin Viktor Malyshev Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts Nanoscale Research Letters Nanoparticles Nanocoatings Rhodium Electrochemical behavior Synthesis Low-temperature melts |
| title | Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts |
| title_full | Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts |
| title_fullStr | Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts |
| title_full_unstemmed | Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts |
| title_short | Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts |
| title_sort | electrochemical behavior and electrodeposition of nanostructured rhodium from low temperature carbamide and acetamide containing melts |
| topic | Nanoparticles Nanocoatings Rhodium Electrochemical behavior Synthesis Low-temperature melts |
| url | http://link.springer.com/article/10.1186/s11671-017-2108-7 |
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