The structure directing role of 1, 3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate
1,3-Diaminopropane (DAP) was used as a structure-directing agent for the hydrothermal synthesis of an organically templated iron phosphate. During crystallization at 180 ºC, iron phosphate (FePO-DAP) with a layered structure was formed after one day. Longer crystallization yielded a mixture of FePO-...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2004-01-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2004/0352-51390403179R.pdf |
| _version_ | 1819280599148396544 |
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| author | Rajić Nevenka Z. Stojaković Đorđe R. Hanžel Darko Kaučič Venčeslav |
| author_facet | Rajić Nevenka Z. Stojaković Đorđe R. Hanžel Darko Kaučič Venčeslav |
| author_sort | Rajić Nevenka Z. |
| collection | DOAJ |
| description | 1,3-Diaminopropane (DAP) was used as a structure-directing agent for the hydrothermal synthesis of an organically templated iron phosphate. During crystallization at 180 ºC, iron phosphate (FePO-DAP) with a layered structure was formed after one day. Longer crystallization yielded a mixture of FePO-DAP and leucophosphite, raising the question whether a transformation of FePO-DAP to leucophosphite occurs, or whether DAP decomposes under hydrothermal conditions resulting in leucophosphite formation. Lattice energy and free energy calculations strongly support the supposition that a decomposition of DAP occurs prior to the formation of leucophosphite. |
| first_indexed | 2024-12-24T00:46:21Z |
| format | Article |
| id | doaj.art-3a5f38b410724d87b5c5249efef055d7 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 1820-7421 |
| language | English |
| last_indexed | 2024-12-24T00:46:21Z |
| publishDate | 2004-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-3a5f38b410724d87b5c5249efef055d72022-12-21T17:23:47ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212004-01-0169317918610.2298/JSC0403179R0352-51390403179RThe structure directing role of 1, 3-diaminopropane in the hydrothermal synthesis of iron(III) phosphateRajić Nevenka Z.0Stojaković Đorđe R.1Hanžel Darko2Kaučič Venčeslav3Faculty of Technology and Metallurgy, University of Belgrade, Belgrade, Serbia and MontenegroFaculty of Technology and Metallurgy, University of Belgrade, Belgrade, Serbia and MontenegroInstitute Jožef Štefan, Ljubljana, SloveniaNational Institute of Chemistry, 1000 Ljubljana, Slovenia and University of Ljubljana, 1000 Ljubljana, Slovenia1,3-Diaminopropane (DAP) was used as a structure-directing agent for the hydrothermal synthesis of an organically templated iron phosphate. During crystallization at 180 ºC, iron phosphate (FePO-DAP) with a layered structure was formed after one day. Longer crystallization yielded a mixture of FePO-DAP and leucophosphite, raising the question whether a transformation of FePO-DAP to leucophosphite occurs, or whether DAP decomposes under hydrothermal conditions resulting in leucophosphite formation. Lattice energy and free energy calculations strongly support the supposition that a decomposition of DAP occurs prior to the formation of leucophosphite.http://www.doiserbia.nb.rs/img/doi/0352-5139/2004/0352-51390403179R.pdffepoiron phosphatehydrothermal synthesisgulpopen-framework |
| spellingShingle | Rajić Nevenka Z. Stojaković Đorđe R. Hanžel Darko Kaučič Venčeslav The structure directing role of 1, 3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate Journal of the Serbian Chemical Society fepo iron phosphate hydrothermal synthesis gulp open-framework |
| title | The structure directing role of 1, 3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate |
| title_full | The structure directing role of 1, 3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate |
| title_fullStr | The structure directing role of 1, 3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate |
| title_full_unstemmed | The structure directing role of 1, 3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate |
| title_short | The structure directing role of 1, 3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate |
| title_sort | structure directing role of 1 3 diaminopropane in the hydrothermal synthesis of iron iii phosphate |
| topic | fepo iron phosphate hydrothermal synthesis gulp open-framework |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2004/0352-51390403179R.pdf |
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