Flame Retardant Properties and Thermal Decomposition Kinetics of Wood Treated with Boric Acid Modified Silica Sol

This paper presents experimental research on the flame-retardant properties and thermal decomposition kinetics of wood treated by boric-acid-modified silica sol. The poplar wood was impregnated with pure silica sol and boric-acid-modified silica sol. The results showed that modifiers can be observed...

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Main Authors: Qiangqiang Liu, Yubo Chai, Lin Ni, Wenhua Lyu
Format: Article
Language:English
Published: MDPI AG 2020-10-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/20/4478
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author Qiangqiang Liu
Yubo Chai
Lin Ni
Wenhua Lyu
author_facet Qiangqiang Liu
Yubo Chai
Lin Ni
Wenhua Lyu
author_sort Qiangqiang Liu
collection DOAJ
description This paper presents experimental research on the flame-retardant properties and thermal decomposition kinetics of wood treated by boric-acid-modified silica sol. The poplar wood was impregnated with pure silica sol and boric-acid-modified silica sol. The results showed that modifiers can be observed in the cell wall and cell lumen. The ignition time, second peak of the heat release rate, total heat release, and mass loss of the W-Si/B were delayed obviously. The composite silicon modification had a positive impact on carbonization. Thermogravimetric analysis showed that the residual mass of W-Si/B was enhanced and the thermal degradation rate was considerably decreased. By thermal decomposition kinetics analysis, the boric acid can catalyze the thermal degradation and carbonization of poplar wood. In other words, wood treated with boric-acid-modified silica sol showed significant improvement in terms of flame retardancy, compared with wood treated with common silica sol.
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spelling doaj.art-3a6f1f9a0d1b4c6d973095349f54c26d2023-11-20T16:30:13ZengMDPI AGMaterials1996-19442020-10-011320447810.3390/ma13204478Flame Retardant Properties and Thermal Decomposition Kinetics of Wood Treated with Boric Acid Modified Silica SolQiangqiang Liu0Yubo Chai1Lin Ni2Wenhua Lyu3Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, ChinaResearch Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, ChinaResearch Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, ChinaResearch Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, ChinaThis paper presents experimental research on the flame-retardant properties and thermal decomposition kinetics of wood treated by boric-acid-modified silica sol. The poplar wood was impregnated with pure silica sol and boric-acid-modified silica sol. The results showed that modifiers can be observed in the cell wall and cell lumen. The ignition time, second peak of the heat release rate, total heat release, and mass loss of the W-Si/B were delayed obviously. The composite silicon modification had a positive impact on carbonization. Thermogravimetric analysis showed that the residual mass of W-Si/B was enhanced and the thermal degradation rate was considerably decreased. By thermal decomposition kinetics analysis, the boric acid can catalyze the thermal degradation and carbonization of poplar wood. In other words, wood treated with boric-acid-modified silica sol showed significant improvement in terms of flame retardancy, compared with wood treated with common silica sol.https://www.mdpi.com/1996-1944/13/20/4478poplar woodsilica solboric acidcone calorimetricdecomposition kinetics
spellingShingle Qiangqiang Liu
Yubo Chai
Lin Ni
Wenhua Lyu
Flame Retardant Properties and Thermal Decomposition Kinetics of Wood Treated with Boric Acid Modified Silica Sol
Materials
poplar wood
silica sol
boric acid
cone calorimetric
decomposition kinetics
title Flame Retardant Properties and Thermal Decomposition Kinetics of Wood Treated with Boric Acid Modified Silica Sol
title_full Flame Retardant Properties and Thermal Decomposition Kinetics of Wood Treated with Boric Acid Modified Silica Sol
title_fullStr Flame Retardant Properties and Thermal Decomposition Kinetics of Wood Treated with Boric Acid Modified Silica Sol
title_full_unstemmed Flame Retardant Properties and Thermal Decomposition Kinetics of Wood Treated with Boric Acid Modified Silica Sol
title_short Flame Retardant Properties and Thermal Decomposition Kinetics of Wood Treated with Boric Acid Modified Silica Sol
title_sort flame retardant properties and thermal decomposition kinetics of wood treated with boric acid modified silica sol
topic poplar wood
silica sol
boric acid
cone calorimetric
decomposition kinetics
url https://www.mdpi.com/1996-1944/13/20/4478
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AT yubochai flameretardantpropertiesandthermaldecompositionkineticsofwoodtreatedwithboricacidmodifiedsilicasol
AT linni flameretardantpropertiesandthermaldecompositionkineticsofwoodtreatedwithboricacidmodifiedsilicasol
AT wenhualyu flameretardantpropertiesandthermaldecompositionkineticsofwoodtreatedwithboricacidmodifiedsilicasol