Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat Storage
This work aims to characterize phase change materials (PCM) for thermal energy storage in buildings (thermal comfort). Fatty acids, biobased organic PCM, are attractive candidates for integration into active or passive storage systems for targeted application. Three pure fatty acids (capric, myristi...
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MDPI AG
2021-08-01
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Online Access: | https://www.mdpi.com/1996-1944/14/16/4707 |
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author | Marie Duquesne Clément Mailhé Stefania Doppiu Jean-Luc Dauvergne Sergio Santos-Moreno Alexandre Godin Guillaume Fleury Fabien Rouault Elena Palomo del Barrio |
author_facet | Marie Duquesne Clément Mailhé Stefania Doppiu Jean-Luc Dauvergne Sergio Santos-Moreno Alexandre Godin Guillaume Fleury Fabien Rouault Elena Palomo del Barrio |
author_sort | Marie Duquesne |
collection | DOAJ |
description | This work aims to characterize phase change materials (PCM) for thermal energy storage in buildings (thermal comfort). Fatty acids, biobased organic PCM, are attractive candidates for integration into active or passive storage systems for targeted application. Three pure fatty acids (capric, myristic and palmitic acids) and two eutectic mixtures (capric-myristic and capric-palmitic acids) are studied in this paper. Although the main storage properties of pure fatty acids have already been investigated and reported in the literature, the information available on the eutectic mixtures is very limited (only melting temperature and enthalpy). This paper presents a complete experimental characterization of these pure and mixed fatty acids, including measurements of their main thermophysical properties (melting temperature and enthalpy, specific heats and densities in solid and liquid states, thermal conductivity, thermal diffusivity as well as viscosity) and the properties of interest regarding the system integrating the PCM (energy density, volume expansion). The storage performances of the studied mixtures are also compared to those of most commonly used PCM (salt hydrates and paraffins). |
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format | Article |
id | doaj.art-3a7882782d8c40d4bd5401411162a72e |
institution | Directory Open Access Journal |
issn | 1996-1944 |
language | English |
last_indexed | 2024-03-10T08:37:54Z |
publishDate | 2021-08-01 |
publisher | MDPI AG |
record_format | Article |
series | Materials |
spelling | doaj.art-3a7882782d8c40d4bd5401411162a72e2023-11-22T08:31:38ZengMDPI AGMaterials1996-19442021-08-011416470710.3390/ma14164707Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat StorageMarie Duquesne0Clément Mailhé1Stefania Doppiu2Jean-Luc Dauvergne3Sergio Santos-Moreno4Alexandre Godin5Guillaume Fleury6Fabien Rouault7Elena Palomo del Barrio8Univ. Bordeaux, CNRS, I2M Bordeaux, Bâtiment A11, 351 cours de la Libération, CEDEX, 33405 Talence, FranceUniv. Bordeaux, CNRS, I2M Bordeaux, Bâtiment A11, 351 cours de la Libération, CEDEX, 33405 Talence, FranceCentre for Cooperative Research on Alternative Energies (CICenergiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainCentre for Cooperative Research on Alternative Energies (CICenergiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainCentre for Cooperative Research on Alternative Energies (CICenergiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainAmplitude, 11 Avenue de Canteranne, Cité de la Photonique, Bâtiment MEROPA, 33600 Pessac, FranceUniv. Bordeaux, CNRS, Bordeaux INP, LCPO—UMR5629, 16 Avenue Pey Berland, CEDEX, 33607 Pessac, FranceEscuela de Construcción, Facultad de Ingeniería, Pontificia Universidad Católica de Chile, Av. Libertador Bernardo O’Higgins 340, Santiago 8331150, ChileCentre for Cooperative Research on Alternative Energies (CICenergiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainThis work aims to characterize phase change materials (PCM) for thermal energy storage in buildings (thermal comfort). Fatty acids, biobased organic PCM, are attractive candidates for integration into active or passive storage systems for targeted application. Three pure fatty acids (capric, myristic and palmitic acids) and two eutectic mixtures (capric-myristic and capric-palmitic acids) are studied in this paper. Although the main storage properties of pure fatty acids have already been investigated and reported in the literature, the information available on the eutectic mixtures is very limited (only melting temperature and enthalpy). This paper presents a complete experimental characterization of these pure and mixed fatty acids, including measurements of their main thermophysical properties (melting temperature and enthalpy, specific heats and densities in solid and liquid states, thermal conductivity, thermal diffusivity as well as viscosity) and the properties of interest regarding the system integrating the PCM (energy density, volume expansion). The storage performances of the studied mixtures are also compared to those of most commonly used PCM (salt hydrates and paraffins).https://www.mdpi.com/1996-1944/14/16/4707thermal energy storagebiobased phase change materialsfatty acidsthermophysical characterization |
spellingShingle | Marie Duquesne Clément Mailhé Stefania Doppiu Jean-Luc Dauvergne Sergio Santos-Moreno Alexandre Godin Guillaume Fleury Fabien Rouault Elena Palomo del Barrio Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat Storage Materials thermal energy storage biobased phase change materials fatty acids thermophysical characterization |
title | Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat Storage |
title_full | Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat Storage |
title_fullStr | Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat Storage |
title_full_unstemmed | Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat Storage |
title_short | Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat Storage |
title_sort | characterization of fatty acids as biobased organic materials for latent heat storage |
topic | thermal energy storage biobased phase change materials fatty acids thermophysical characterization |
url | https://www.mdpi.com/1996-1944/14/16/4707 |
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