Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat Storage

This work aims to characterize phase change materials (PCM) for thermal energy storage in buildings (thermal comfort). Fatty acids, biobased organic PCM, are attractive candidates for integration into active or passive storage systems for targeted application. Three pure fatty acids (capric, myristi...

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Main Authors: Marie Duquesne, Clément Mailhé, Stefania Doppiu, Jean-Luc Dauvergne, Sergio Santos-Moreno, Alexandre Godin, Guillaume Fleury, Fabien Rouault, Elena Palomo del Barrio
Format: Article
Language:English
Published: MDPI AG 2021-08-01
Series:Materials
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Online Access:https://www.mdpi.com/1996-1944/14/16/4707
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author Marie Duquesne
Clément Mailhé
Stefania Doppiu
Jean-Luc Dauvergne
Sergio Santos-Moreno
Alexandre Godin
Guillaume Fleury
Fabien Rouault
Elena Palomo del Barrio
author_facet Marie Duquesne
Clément Mailhé
Stefania Doppiu
Jean-Luc Dauvergne
Sergio Santos-Moreno
Alexandre Godin
Guillaume Fleury
Fabien Rouault
Elena Palomo del Barrio
author_sort Marie Duquesne
collection DOAJ
description This work aims to characterize phase change materials (PCM) for thermal energy storage in buildings (thermal comfort). Fatty acids, biobased organic PCM, are attractive candidates for integration into active or passive storage systems for targeted application. Three pure fatty acids (capric, myristic and palmitic acids) and two eutectic mixtures (capric-myristic and capric-palmitic acids) are studied in this paper. Although the main storage properties of pure fatty acids have already been investigated and reported in the literature, the information available on the eutectic mixtures is very limited (only melting temperature and enthalpy). This paper presents a complete experimental characterization of these pure and mixed fatty acids, including measurements of their main thermophysical properties (melting temperature and enthalpy, specific heats and densities in solid and liquid states, thermal conductivity, thermal diffusivity as well as viscosity) and the properties of interest regarding the system integrating the PCM (energy density, volume expansion). The storage performances of the studied mixtures are also compared to those of most commonly used PCM (salt hydrates and paraffins).
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spelling doaj.art-3a7882782d8c40d4bd5401411162a72e2023-11-22T08:31:38ZengMDPI AGMaterials1996-19442021-08-011416470710.3390/ma14164707Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat StorageMarie Duquesne0Clément Mailhé1Stefania Doppiu2Jean-Luc Dauvergne3Sergio Santos-Moreno4Alexandre Godin5Guillaume Fleury6Fabien Rouault7Elena Palomo del Barrio8Univ. Bordeaux, CNRS, I2M Bordeaux, Bâtiment A11, 351 cours de la Libération, CEDEX, 33405 Talence, FranceUniv. Bordeaux, CNRS, I2M Bordeaux, Bâtiment A11, 351 cours de la Libération, CEDEX, 33405 Talence, FranceCentre for Cooperative Research on Alternative Energies (CICenergiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainCentre for Cooperative Research on Alternative Energies (CICenergiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainCentre for Cooperative Research on Alternative Energies (CICenergiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainAmplitude, 11 Avenue de Canteranne, Cité de la Photonique, Bâtiment MEROPA, 33600 Pessac, FranceUniv. Bordeaux, CNRS, Bordeaux INP, LCPO—UMR5629, 16 Avenue Pey Berland, CEDEX, 33607 Pessac, FranceEscuela de Construcción, Facultad de Ingeniería, Pontificia Universidad Católica de Chile, Av. Libertador Bernardo O’Higgins 340, Santiago 8331150, ChileCentre for Cooperative Research on Alternative Energies (CICenergiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainThis work aims to characterize phase change materials (PCM) for thermal energy storage in buildings (thermal comfort). Fatty acids, biobased organic PCM, are attractive candidates for integration into active or passive storage systems for targeted application. Three pure fatty acids (capric, myristic and palmitic acids) and two eutectic mixtures (capric-myristic and capric-palmitic acids) are studied in this paper. Although the main storage properties of pure fatty acids have already been investigated and reported in the literature, the information available on the eutectic mixtures is very limited (only melting temperature and enthalpy). This paper presents a complete experimental characterization of these pure and mixed fatty acids, including measurements of their main thermophysical properties (melting temperature and enthalpy, specific heats and densities in solid and liquid states, thermal conductivity, thermal diffusivity as well as viscosity) and the properties of interest regarding the system integrating the PCM (energy density, volume expansion). The storage performances of the studied mixtures are also compared to those of most commonly used PCM (salt hydrates and paraffins).https://www.mdpi.com/1996-1944/14/16/4707thermal energy storagebiobased phase change materialsfatty acidsthermophysical characterization
spellingShingle Marie Duquesne
Clément Mailhé
Stefania Doppiu
Jean-Luc Dauvergne
Sergio Santos-Moreno
Alexandre Godin
Guillaume Fleury
Fabien Rouault
Elena Palomo del Barrio
Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat Storage
Materials
thermal energy storage
biobased phase change materials
fatty acids
thermophysical characterization
title Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat Storage
title_full Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat Storage
title_fullStr Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat Storage
title_full_unstemmed Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat Storage
title_short Characterization of Fatty Acids as Biobased Organic Materials for Latent Heat Storage
title_sort characterization of fatty acids as biobased organic materials for latent heat storage
topic thermal energy storage
biobased phase change materials
fatty acids
thermophysical characterization
url https://www.mdpi.com/1996-1944/14/16/4707
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