Mechanism and structure analysis of SiO2-coated CaCO3 superfine particles(SiO2包覆超细CaCO3的结构和机理分析)

合成了表面包覆SiO2的超细CaCO3。通过XPS,RD对包覆表面层结构的分析,证实了SiO2以无定形包覆于CaCO3表面,并在其表面形成了Si-O-Ca键。对SiO2包覆超细CaCO3的机理分析结果可知:Na2SiO3的加入量是影响包覆效率的重要因素,由于硅酸易自聚,控制SiO2与CaCO3的重量比约为4%~5%时为包覆的最佳点;CaCO3晶粒度大小影响分散性能,进而影响包覆效率,分散性能好的包覆效率较高。...

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Main Authors: YUELin-hai(岳林海), CAIJu-xiang(蔡菊香), HUAYi-miao(华益苗)
Format: Article
Language:zho
Published: Zhejiang University Press 2002-01-01
Series:Zhejiang Daxue xuebao. Lixue ban
Subjects:
Online Access:https://doi.org/zjup/1008-9497.2002.29.1.67-72
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author YUELin-hai(岳林海)
CAIJu-xiang(蔡菊香)
HUAYi-miao(华益苗)
author_facet YUELin-hai(岳林海)
CAIJu-xiang(蔡菊香)
HUAYi-miao(华益苗)
author_sort YUELin-hai(岳林海)
collection DOAJ
description 合成了表面包覆SiO2的超细CaCO3。通过XPS,RD对包覆表面层结构的分析,证实了SiO2以无定形包覆于CaCO3表面,并在其表面形成了Si-O-Ca键。对SiO2包覆超细CaCO3的机理分析结果可知:Na2SiO3的加入量是影响包覆效率的重要因素,由于硅酸易自聚,控制SiO2与CaCO3的重量比约为4%~5%时为包覆的最佳点;CaCO3晶粒度大小影响分散性能,进而影响包覆效率,分散性能好的包覆效率较高。
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spelling doaj.art-3a7e1f87adde45ad85dac0659be3c02d2024-03-29T01:58:18ZzhoZhejiang University PressZhejiang Daxue xuebao. Lixue ban1008-94972002-01-012916772zjup/1008-9497.2002.29.1.67-72Mechanism and structure analysis of SiO2-coated CaCO3 superfine particles(SiO2包覆超细CaCO3的结构和机理分析)YUELin-hai(岳林海)0CAIJu-xiang(蔡菊香)1HUAYi-miao(华益苗)2Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系,浙江 杭州 310027)Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系,浙江 杭州 310027)Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系,浙江 杭州 310027)合成了表面包覆SiO2的超细CaCO3。通过XPS,RD对包覆表面层结构的分析,证实了SiO2以无定形包覆于CaCO3表面,并在其表面形成了Si-O-Ca键。对SiO2包覆超细CaCO3的机理分析结果可知:Na2SiO3的加入量是影响包覆效率的重要因素,由于硅酸易自聚,控制SiO2与CaCO3的重量比约为4%~5%时为包覆的最佳点;CaCO3晶粒度大小影响分散性能,进而影响包覆效率,分散性能好的包覆效率较高。https://doi.org/zjup/1008-9497.2002.29.1.67-72包覆超细caco3sio2ps机理
spellingShingle YUELin-hai(岳林海)
CAIJu-xiang(蔡菊香)
HUAYi-miao(华益苗)
Mechanism and structure analysis of SiO2-coated CaCO3 superfine particles(SiO2包覆超细CaCO3的结构和机理分析)
Zhejiang Daxue xuebao. Lixue ban
包覆
超细caco3
sio2
ps
机理
title Mechanism and structure analysis of SiO2-coated CaCO3 superfine particles(SiO2包覆超细CaCO3的结构和机理分析)
title_full Mechanism and structure analysis of SiO2-coated CaCO3 superfine particles(SiO2包覆超细CaCO3的结构和机理分析)
title_fullStr Mechanism and structure analysis of SiO2-coated CaCO3 superfine particles(SiO2包覆超细CaCO3的结构和机理分析)
title_full_unstemmed Mechanism and structure analysis of SiO2-coated CaCO3 superfine particles(SiO2包覆超细CaCO3的结构和机理分析)
title_short Mechanism and structure analysis of SiO2-coated CaCO3 superfine particles(SiO2包覆超细CaCO3的结构和机理分析)
title_sort mechanism and structure analysis of sio2 coated caco3 superfine particles sio2包覆超细caco3的结构和机理分析
topic 包覆
超细caco3
sio2
ps
机理
url https://doi.org/zjup/1008-9497.2002.29.1.67-72
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