Gas Sensitive Characteristics of Polyaniline Decorated with Molybdenum Ditelluride Nanosheets

In this work, hydrochloric acid (HCl)-doped molybdenum ditelluride (MoTe<sub>2</sub>) nanosheets/polyaniline (PANI) nanofiber composites are prepared by in situ chemical oxidation polymerization, and then the composites are deposited on interdigital electrodes (IDEs) to fabricate a NH<...

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Main Authors: Xinpeng Chen, Xiangdong Chen, Xing Ding, Xiang Yu
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Chemosensors
Subjects:
Online Access:https://www.mdpi.com/2227-9040/10/7/264
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author Xinpeng Chen
Xiangdong Chen
Xing Ding
Xiang Yu
author_facet Xinpeng Chen
Xiangdong Chen
Xing Ding
Xiang Yu
author_sort Xinpeng Chen
collection DOAJ
description In this work, hydrochloric acid (HCl)-doped molybdenum ditelluride (MoTe<sub>2</sub>) nanosheets/polyaniline (PANI) nanofiber composites are prepared by in situ chemical oxidation polymerization, and then the composites are deposited on interdigital electrodes (IDEs) to fabricate a NH<sub>3</sub> gas sensor. Morphological analysis of the composites reveals that the PANI fibers are deposited on 2D MoTe<sub>2</sub> sheets, showing a porous mesh microstructure structure with a more continuous distribution of PANI layer. FTIR spectrum analysis indicates the interaction between the MoTe<sub>2</sub> nanosheets and the PANI in the MoTe<sub>2</sub>/PANI composites. The results demonstrate that the as-prepared MoTe<sub>2</sub>/PANI composites exhibit higher response than the pure PANI, in particular, the 8 wt.% MoTe<sub>2</sub>/PANI composites display about 4.23 times enhancement in response value toward 1000 ppm NH<sub>3</sub> gas compared with the pure PANI. The enhanced NH<sub>3</sub> gas-sensitive properties may be due to the increasing surface area of MoTe<sub>2</sub>/PANI composite films and the possible interaction of the P-N heterojunctions formed between PANI and the 2H-MoTe<sub>2</sub> nanosheets.
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spelling doaj.art-3a8a7b03cfaf4912930ad4dc4595abf32023-12-03T14:50:27ZengMDPI AGChemosensors2227-90402022-07-0110726410.3390/chemosensors10070264Gas Sensitive Characteristics of Polyaniline Decorated with Molybdenum Ditelluride NanosheetsXinpeng Chen0Xiangdong Chen1Xing Ding2Xiang Yu3School of Information Science and Technology, Southwest Jiaotong University, Chengdu 610097, ChinaSchool of Information Science and Technology, Southwest Jiaotong University, Chengdu 610097, ChinaSchool of Information Science and Technology, Southwest Jiaotong University, Chengdu 610097, ChinaSchool of Information Science and Technology, Southwest Jiaotong University, Chengdu 610097, ChinaIn this work, hydrochloric acid (HCl)-doped molybdenum ditelluride (MoTe<sub>2</sub>) nanosheets/polyaniline (PANI) nanofiber composites are prepared by in situ chemical oxidation polymerization, and then the composites are deposited on interdigital electrodes (IDEs) to fabricate a NH<sub>3</sub> gas sensor. Morphological analysis of the composites reveals that the PANI fibers are deposited on 2D MoTe<sub>2</sub> sheets, showing a porous mesh microstructure structure with a more continuous distribution of PANI layer. FTIR spectrum analysis indicates the interaction between the MoTe<sub>2</sub> nanosheets and the PANI in the MoTe<sub>2</sub>/PANI composites. The results demonstrate that the as-prepared MoTe<sub>2</sub>/PANI composites exhibit higher response than the pure PANI, in particular, the 8 wt.% MoTe<sub>2</sub>/PANI composites display about 4.23 times enhancement in response value toward 1000 ppm NH<sub>3</sub> gas compared with the pure PANI. The enhanced NH<sub>3</sub> gas-sensitive properties may be due to the increasing surface area of MoTe<sub>2</sub>/PANI composite films and the possible interaction of the P-N heterojunctions formed between PANI and the 2H-MoTe<sub>2</sub> nanosheets.https://www.mdpi.com/2227-9040/10/7/264MoTe<sub>2</sub> nanosheetspolyanilineNH<sub>3</sub> gas sensorP-N heterojunctionsammonia
spellingShingle Xinpeng Chen
Xiangdong Chen
Xing Ding
Xiang Yu
Gas Sensitive Characteristics of Polyaniline Decorated with Molybdenum Ditelluride Nanosheets
Chemosensors
MoTe<sub>2</sub> nanosheets
polyaniline
NH<sub>3</sub> gas sensor
P-N heterojunctions
ammonia
title Gas Sensitive Characteristics of Polyaniline Decorated with Molybdenum Ditelluride Nanosheets
title_full Gas Sensitive Characteristics of Polyaniline Decorated with Molybdenum Ditelluride Nanosheets
title_fullStr Gas Sensitive Characteristics of Polyaniline Decorated with Molybdenum Ditelluride Nanosheets
title_full_unstemmed Gas Sensitive Characteristics of Polyaniline Decorated with Molybdenum Ditelluride Nanosheets
title_short Gas Sensitive Characteristics of Polyaniline Decorated with Molybdenum Ditelluride Nanosheets
title_sort gas sensitive characteristics of polyaniline decorated with molybdenum ditelluride nanosheets
topic MoTe<sub>2</sub> nanosheets
polyaniline
NH<sub>3</sub> gas sensor
P-N heterojunctions
ammonia
url https://www.mdpi.com/2227-9040/10/7/264
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AT xiangdongchen gassensitivecharacteristicsofpolyanilinedecoratedwithmolybdenumditelluridenanosheets
AT xingding gassensitivecharacteristicsofpolyanilinedecoratedwithmolybdenumditelluridenanosheets
AT xiangyu gassensitivecharacteristicsofpolyanilinedecoratedwithmolybdenumditelluridenanosheets