Preparation of Microcrystalline Cellulose/N-(2-aminoethyl)-3- Aminopropyl Methyl Dimethoxysilane Composite Aerogel and Adsorption Properties for Formaldehyde

Air pollution is related to the development of the national economy and people’s livelihoods. Formaldehyde, as one of the main pollutants in the air, affects people’s physical and mental health. In order to remove formaldehyde and better protect the health of residents, it is necessary to develop ef...

Full description

Bibliographic Details
Main Authors: Yaning Li, Zhongzheng Liu, Chuanxi Chi, Bin Yuan, Yang Zhang, Guiquan Jiang, Jianxi Song
Format: Article
Language:English
Published: MDPI AG 2023-07-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/15/15/3155
_version_ 1797586150093750272
author Yaning Li
Zhongzheng Liu
Chuanxi Chi
Bin Yuan
Yang Zhang
Guiquan Jiang
Jianxi Song
author_facet Yaning Li
Zhongzheng Liu
Chuanxi Chi
Bin Yuan
Yang Zhang
Guiquan Jiang
Jianxi Song
author_sort Yaning Li
collection DOAJ
description Air pollution is related to the development of the national economy and people’s livelihoods. Formaldehyde, as one of the main pollutants in the air, affects people’s physical and mental health. In order to remove formaldehyde and better protect the health of residents, it is necessary to develop efficient adsorption materials. In this study, APMDS-modified cellulose composite aerogel microcrystalline was investigated. The adsorption of formaldehyde by the MCC/APMDS (Microcrystalline Cellulose/N-(2-aminoethyl)-3- Aminopropyl Methyl Dimethoxysilane) composite aerogel mainly relied upon the reaction of the protonated –NH<sub>3</sub><sup>+</sup> group in APMDS with formaldehyde to form a Schiff base to achieve the effect of deformaldehyde. Meanwhile, the modification of the aerogel reduced the pore volume and specific surface area, and the average pore size increased to 14.56 nm, which enhanced the adsorption capacity of formaldehyde, and the adsorption amount reached 9.52 mg/g. This study provides valuable information for the preparation of adsorbent materials with high formaldehyde adsorption capacity for air purification.
first_indexed 2024-03-11T00:18:15Z
format Article
id doaj.art-3a9d0ac990bc462983b363e5d5233931
institution Directory Open Access Journal
issn 2073-4360
language English
last_indexed 2024-03-11T00:18:15Z
publishDate 2023-07-01
publisher MDPI AG
record_format Article
series Polymers
spelling doaj.art-3a9d0ac990bc462983b363e5d52339312023-11-18T23:27:20ZengMDPI AGPolymers2073-43602023-07-011515315510.3390/polym15153155Preparation of Microcrystalline Cellulose/N-(2-aminoethyl)-3- Aminopropyl Methyl Dimethoxysilane Composite Aerogel and Adsorption Properties for FormaldehydeYaning Li0Zhongzheng Liu1Chuanxi Chi2Bin Yuan3Yang Zhang4Guiquan Jiang5Jianxi Song6Key Laboratory of Wooden Materials Science and Engineering of Jilin Province, Beihua University, Jilin City 132013, ChinaKey Laboratory of Wooden Materials Science and Engineering of Jilin Province, Beihua University, Jilin City 132013, ChinaKey Laboratory of Wooden Materials Science and Engineering of Jilin Province, Beihua University, Jilin City 132013, ChinaKey Laboratory of Wooden Materials Science and Engineering of Jilin Province, Beihua University, Jilin City 132013, ChinaKey Laboratory of Wooden Materials Science and Engineering of Jilin Province, Beihua University, Jilin City 132013, ChinaKey Laboratory of Wooden Materials Science and Engineering of Jilin Province, Beihua University, Jilin City 132013, ChinaKey Laboratory of Wooden Materials Science and Engineering of Jilin Province, Beihua University, Jilin City 132013, ChinaAir pollution is related to the development of the national economy and people’s livelihoods. Formaldehyde, as one of the main pollutants in the air, affects people’s physical and mental health. In order to remove formaldehyde and better protect the health of residents, it is necessary to develop efficient adsorption materials. In this study, APMDS-modified cellulose composite aerogel microcrystalline was investigated. The adsorption of formaldehyde by the MCC/APMDS (Microcrystalline Cellulose/N-(2-aminoethyl)-3- Aminopropyl Methyl Dimethoxysilane) composite aerogel mainly relied upon the reaction of the protonated –NH<sub>3</sub><sup>+</sup> group in APMDS with formaldehyde to form a Schiff base to achieve the effect of deformaldehyde. Meanwhile, the modification of the aerogel reduced the pore volume and specific surface area, and the average pore size increased to 14.56 nm, which enhanced the adsorption capacity of formaldehyde, and the adsorption amount reached 9.52 mg/g. This study provides valuable information for the preparation of adsorbent materials with high formaldehyde adsorption capacity for air purification.https://www.mdpi.com/2073-4360/15/15/3155celluloseaerogeladsorptionformaldehyde
spellingShingle Yaning Li
Zhongzheng Liu
Chuanxi Chi
Bin Yuan
Yang Zhang
Guiquan Jiang
Jianxi Song
Preparation of Microcrystalline Cellulose/N-(2-aminoethyl)-3- Aminopropyl Methyl Dimethoxysilane Composite Aerogel and Adsorption Properties for Formaldehyde
Polymers
cellulose
aerogel
adsorption
formaldehyde
title Preparation of Microcrystalline Cellulose/N-(2-aminoethyl)-3- Aminopropyl Methyl Dimethoxysilane Composite Aerogel and Adsorption Properties for Formaldehyde
title_full Preparation of Microcrystalline Cellulose/N-(2-aminoethyl)-3- Aminopropyl Methyl Dimethoxysilane Composite Aerogel and Adsorption Properties for Formaldehyde
title_fullStr Preparation of Microcrystalline Cellulose/N-(2-aminoethyl)-3- Aminopropyl Methyl Dimethoxysilane Composite Aerogel and Adsorption Properties for Formaldehyde
title_full_unstemmed Preparation of Microcrystalline Cellulose/N-(2-aminoethyl)-3- Aminopropyl Methyl Dimethoxysilane Composite Aerogel and Adsorption Properties for Formaldehyde
title_short Preparation of Microcrystalline Cellulose/N-(2-aminoethyl)-3- Aminopropyl Methyl Dimethoxysilane Composite Aerogel and Adsorption Properties for Formaldehyde
title_sort preparation of microcrystalline cellulose n 2 aminoethyl 3 aminopropyl methyl dimethoxysilane composite aerogel and adsorption properties for formaldehyde
topic cellulose
aerogel
adsorption
formaldehyde
url https://www.mdpi.com/2073-4360/15/15/3155
work_keys_str_mv AT yaningli preparationofmicrocrystallinecellulosen2aminoethyl3aminopropylmethyldimethoxysilanecompositeaerogelandadsorptionpropertiesforformaldehyde
AT zhongzhengliu preparationofmicrocrystallinecellulosen2aminoethyl3aminopropylmethyldimethoxysilanecompositeaerogelandadsorptionpropertiesforformaldehyde
AT chuanxichi preparationofmicrocrystallinecellulosen2aminoethyl3aminopropylmethyldimethoxysilanecompositeaerogelandadsorptionpropertiesforformaldehyde
AT binyuan preparationofmicrocrystallinecellulosen2aminoethyl3aminopropylmethyldimethoxysilanecompositeaerogelandadsorptionpropertiesforformaldehyde
AT yangzhang preparationofmicrocrystallinecellulosen2aminoethyl3aminopropylmethyldimethoxysilanecompositeaerogelandadsorptionpropertiesforformaldehyde
AT guiquanjiang preparationofmicrocrystallinecellulosen2aminoethyl3aminopropylmethyldimethoxysilanecompositeaerogelandadsorptionpropertiesforformaldehyde
AT jianxisong preparationofmicrocrystallinecellulosen2aminoethyl3aminopropylmethyldimethoxysilanecompositeaerogelandadsorptionpropertiesforformaldehyde