Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigment

It has been shown that the precipitation of bismuth orthovanadate from a fly ash leachate is a promising method of vanadium recovery. BiVO4 obtained after appropriate heat treatment can be sold as a pigment. The yield of recovery of solubilised vanadium is equal to 68% and the precipitate is free fr...

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Main Authors: P. Kwolek, K. Czubajewski, M. Wojnicki
Format: Article
Language:English
Published: Polish Academy of Sciences 2020-05-01
Series:Archives of Metallurgy and Materials
Subjects:
Online Access:https://journals.pan.pl/Content/116074/PDF/AMM-2020-2-51-Wojnicki.pdf
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author P. Kwolek
K. Czubajewski
M. Wojnicki
author_facet P. Kwolek
K. Czubajewski
M. Wojnicki
author_sort P. Kwolek
collection DOAJ
description It has been shown that the precipitation of bismuth orthovanadate from a fly ash leachate is a promising method of vanadium recovery. BiVO4 obtained after appropriate heat treatment can be sold as a pigment. The yield of recovery of solubilised vanadium is equal to 68% and the precipitate is free from nickel impurity. The precipitate is insoluble in the solutions with pH ≥ 3. In more acidic media the solubility of precipitate increases with the decreasing pH. The solubility of the precipitate increases also with the increasing concentration of chloride ions.
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spelling doaj.art-3abbc3c6d4d84484ae3a534a44eb97962022-12-22T02:48:51ZengPolish Academy of SciencesArchives of Metallurgy and Materials2300-19092020-05-01vol. 65No 2901909https://doi.org/10.24425/amm.2020.132837Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic PigmentP. KwolekK. CzubajewskiM. WojnickiIt has been shown that the precipitation of bismuth orthovanadate from a fly ash leachate is a promising method of vanadium recovery. BiVO4 obtained after appropriate heat treatment can be sold as a pigment. The yield of recovery of solubilised vanadium is equal to 68% and the precipitate is free from nickel impurity. The precipitate is insoluble in the solutions with pH ≥ 3. In more acidic media the solubility of precipitate increases with the decreasing pH. The solubility of the precipitate increases also with the increasing concentration of chloride ions.https://journals.pan.pl/Content/116074/PDF/AMM-2020-2-51-Wojnicki.pdfrecoveryinorganic pigmentssolubilityvanadiumbismuthimmobilisation
spellingShingle P. Kwolek
K. Czubajewski
M. Wojnicki
Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigment
Archives of Metallurgy and Materials
recovery
inorganic pigments
solubility
vanadium
bismuth
immobilisation
title Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigment
title_full Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigment
title_fullStr Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigment
title_full_unstemmed Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigment
title_short Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigment
title_sort separation and immobilization of vanadium from industrial fly ash as an insoluble inorganic pigment
topic recovery
inorganic pigments
solubility
vanadium
bismuth
immobilisation
url https://journals.pan.pl/Content/116074/PDF/AMM-2020-2-51-Wojnicki.pdf
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AT kczubajewski separationandimmobilizationofvanadiumfromindustrialflyashasaninsolubleinorganicpigment
AT mwojnicki separationandimmobilizationofvanadiumfromindustrialflyashasaninsolubleinorganicpigment