Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigment
It has been shown that the precipitation of bismuth orthovanadate from a fly ash leachate is a promising method of vanadium recovery. BiVO4 obtained after appropriate heat treatment can be sold as a pigment. The yield of recovery of solubilised vanadium is equal to 68% and the precipitate is free fr...
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Format: | Article |
Language: | English |
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Polish Academy of Sciences
2020-05-01
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Series: | Archives of Metallurgy and Materials |
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Online Access: | https://journals.pan.pl/Content/116074/PDF/AMM-2020-2-51-Wojnicki.pdf |
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author | P. Kwolek K. Czubajewski M. Wojnicki |
author_facet | P. Kwolek K. Czubajewski M. Wojnicki |
author_sort | P. Kwolek |
collection | DOAJ |
description | It has been shown that the precipitation of bismuth orthovanadate from a fly ash leachate is a promising method of vanadium recovery. BiVO4 obtained after appropriate heat treatment can be sold as a pigment. The yield of recovery of solubilised vanadium is equal to 68% and the precipitate is free from nickel impurity. The precipitate is insoluble in the solutions with pH ≥ 3. In more acidic media the solubility of precipitate increases with the decreasing pH. The solubility of the precipitate increases also with the increasing concentration of chloride ions. |
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format | Article |
id | doaj.art-3abbc3c6d4d84484ae3a534a44eb9796 |
institution | Directory Open Access Journal |
issn | 2300-1909 |
language | English |
last_indexed | 2024-04-13T11:19:43Z |
publishDate | 2020-05-01 |
publisher | Polish Academy of Sciences |
record_format | Article |
series | Archives of Metallurgy and Materials |
spelling | doaj.art-3abbc3c6d4d84484ae3a534a44eb97962022-12-22T02:48:51ZengPolish Academy of SciencesArchives of Metallurgy and Materials2300-19092020-05-01vol. 65No 2901909https://doi.org/10.24425/amm.2020.132837Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic PigmentP. KwolekK. CzubajewskiM. WojnickiIt has been shown that the precipitation of bismuth orthovanadate from a fly ash leachate is a promising method of vanadium recovery. BiVO4 obtained after appropriate heat treatment can be sold as a pigment. The yield of recovery of solubilised vanadium is equal to 68% and the precipitate is free from nickel impurity. The precipitate is insoluble in the solutions with pH ≥ 3. In more acidic media the solubility of precipitate increases with the decreasing pH. The solubility of the precipitate increases also with the increasing concentration of chloride ions.https://journals.pan.pl/Content/116074/PDF/AMM-2020-2-51-Wojnicki.pdfrecoveryinorganic pigmentssolubilityvanadiumbismuthimmobilisation |
spellingShingle | P. Kwolek K. Czubajewski M. Wojnicki Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigment Archives of Metallurgy and Materials recovery inorganic pigments solubility vanadium bismuth immobilisation |
title | Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigment |
title_full | Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigment |
title_fullStr | Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigment |
title_full_unstemmed | Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigment |
title_short | Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigment |
title_sort | separation and immobilization of vanadium from industrial fly ash as an insoluble inorganic pigment |
topic | recovery inorganic pigments solubility vanadium bismuth immobilisation |
url | https://journals.pan.pl/Content/116074/PDF/AMM-2020-2-51-Wojnicki.pdf |
work_keys_str_mv | AT pkwolek separationandimmobilizationofvanadiumfromindustrialflyashasaninsolubleinorganicpigment AT kczubajewski separationandimmobilizationofvanadiumfromindustrialflyashasaninsolubleinorganicpigment AT mwojnicki separationandimmobilizationofvanadiumfromindustrialflyashasaninsolubleinorganicpigment |