Effects of Three-Dimensional Graphene–Carbon Nanotube Hybrid on the Mechanical Properties and Microstructure of Cement Paste

This work experimentally studies the mechanical properties and microstructure of cementitious composites reinforced with a three-dimensional graphene–carbon nanotube (CNT) hybrid. Firstly, the graphene–CNT (GC) hybrid is dispersed in cement pastes using ultrasonication and surfactant, and then, the...

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Main Authors: Xin Zhao, Li Qiu, Deyu Kong, Yangfei Huang, Jintao Liu
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/19/6571
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author Xin Zhao
Li Qiu
Deyu Kong
Yangfei Huang
Jintao Liu
author_facet Xin Zhao
Li Qiu
Deyu Kong
Yangfei Huang
Jintao Liu
author_sort Xin Zhao
collection DOAJ
description This work experimentally studies the mechanical properties and microstructure of cementitious composites reinforced with a three-dimensional graphene–carbon nanotube (CNT) hybrid. Firstly, the graphene–CNT (GC) hybrid is dispersed in cement pastes using ultrasonication and surfactant, and then, the effect of the GC hybrid on the early hydration of the cement pastes is investigated. The experimental results show that adding the GC hybrid shortens the setting stage of cement hydration and accelerates the early hydration process. Moreover, the macro- and micro-mechanical properties of each group are evaluated. The 7- and 28-day strength of the cement pastes improves with addition of the GC hybrid. Finally, the microstructural analysis demonstrates that the GC hybrid is reasonably well distributed in cement and forms a spatial network, which could bridge the cracks and compact the cementitious matrix.
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spelling doaj.art-3ae9328fbdea499ba4ba148030f3d7302023-11-19T14:41:43ZengMDPI AGMaterials1996-19442023-10-011619657110.3390/ma16196571Effects of Three-Dimensional Graphene–Carbon Nanotube Hybrid on the Mechanical Properties and Microstructure of Cement PasteXin Zhao0Li Qiu1Deyu Kong2Yangfei Huang3Jintao Liu4Department Disaster Mitigation Structure, College of Civil Engineering, Tongji University, Shanghai 200092, ChinaChina Railway Eryuan Engineering Group, East China Survey and Design Co., Ltd., Hangzhou 310009, ChinaCollege of Civil Engineering, Zhejiang University of Technology, Hangzhou 310018, ChinaCollege of Civil Engineering and Architecture, Zhejiang University of Science and Technology, Hangzhou 310018, ChinaCollege of Civil Engineering, Zhejiang University of Technology, Hangzhou 310018, ChinaThis work experimentally studies the mechanical properties and microstructure of cementitious composites reinforced with a three-dimensional graphene–carbon nanotube (CNT) hybrid. Firstly, the graphene–CNT (GC) hybrid is dispersed in cement pastes using ultrasonication and surfactant, and then, the effect of the GC hybrid on the early hydration of the cement pastes is investigated. The experimental results show that adding the GC hybrid shortens the setting stage of cement hydration and accelerates the early hydration process. Moreover, the macro- and micro-mechanical properties of each group are evaluated. The 7- and 28-day strength of the cement pastes improves with addition of the GC hybrid. Finally, the microstructural analysis demonstrates that the GC hybrid is reasonably well distributed in cement and forms a spatial network, which could bridge the cracks and compact the cementitious matrix.https://www.mdpi.com/1996-1944/16/19/6571graphenecarbon nanotubesmicrohardnessmicrostructurehydration
spellingShingle Xin Zhao
Li Qiu
Deyu Kong
Yangfei Huang
Jintao Liu
Effects of Three-Dimensional Graphene–Carbon Nanotube Hybrid on the Mechanical Properties and Microstructure of Cement Paste
Materials
graphene
carbon nanotubes
microhardness
microstructure
hydration
title Effects of Three-Dimensional Graphene–Carbon Nanotube Hybrid on the Mechanical Properties and Microstructure of Cement Paste
title_full Effects of Three-Dimensional Graphene–Carbon Nanotube Hybrid on the Mechanical Properties and Microstructure of Cement Paste
title_fullStr Effects of Three-Dimensional Graphene–Carbon Nanotube Hybrid on the Mechanical Properties and Microstructure of Cement Paste
title_full_unstemmed Effects of Three-Dimensional Graphene–Carbon Nanotube Hybrid on the Mechanical Properties and Microstructure of Cement Paste
title_short Effects of Three-Dimensional Graphene–Carbon Nanotube Hybrid on the Mechanical Properties and Microstructure of Cement Paste
title_sort effects of three dimensional graphene carbon nanotube hybrid on the mechanical properties and microstructure of cement paste
topic graphene
carbon nanotubes
microhardness
microstructure
hydration
url https://www.mdpi.com/1996-1944/16/19/6571
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