Bis(μ-diphenylphosphanyl)bis[(trimethylphosphane)cobalt(I)](Co—Co)
The title compound, [Co2{P(C6H5)2}2(C3H9P)4], was obtained by the addition of diphenylphosphane to a solution of Co(CH3)(C3H9P)4. The dinuclear complex molecule exhibits inversion symmetry with the inversion centre located between the two CoI atoms. The short Co—Co distance of 2.3670&#...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813027384 |
| _version_ | 1818321446195167232 |
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| author | Robert Beck Hans-Friedrich Klein |
| author_facet | Robert Beck Hans-Friedrich Klein |
| author_sort | Robert Beck |
| collection | DOAJ |
| description | The title compound, [Co2{P(C6H5)2}2(C3H9P)4], was obtained by the addition of diphenylphosphane to a solution of Co(CH3)(C3H9P)4. The dinuclear complex molecule exhibits inversion symmetry with the inversion centre located between the two CoI atoms. The short Co—Co distance of 2.3670 (8) Å lies within the range of metal–metal double bonds. As a result of inversion symmetry, the four-membered Co2P2 core is rigorously planar, and the two bridging P(C6H5)2-ligands and the terminal C3H9P ligands are arranged in a pseudo-tetrahedral fashion about the CoI atom. |
| first_indexed | 2024-12-13T10:41:02Z |
| format | Article |
| id | doaj.art-3b09654070f3416c971380787c9b7bce |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:41:02Z |
| publishDate | 2013-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-3b09654070f3416c971380787c9b7bce2022-12-21T23:50:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-11-016911m604m60410.1107/S1600536813027384Bis(μ-diphenylphosphanyl)bis[(trimethylphosphane)cobalt(I)](Co—Co)Robert BeckHans-Friedrich KleinThe title compound, [Co2{P(C6H5)2}2(C3H9P)4], was obtained by the addition of diphenylphosphane to a solution of Co(CH3)(C3H9P)4. The dinuclear complex molecule exhibits inversion symmetry with the inversion centre located between the two CoI atoms. The short Co—Co distance of 2.3670 (8) Å lies within the range of metal–metal double bonds. As a result of inversion symmetry, the four-membered Co2P2 core is rigorously planar, and the two bridging P(C6H5)2-ligands and the terminal C3H9P ligands are arranged in a pseudo-tetrahedral fashion about the CoI atom.http://scripts.iucr.org/cgi-bin/paper?S1600536813027384 |
| spellingShingle | Robert Beck Hans-Friedrich Klein Bis(μ-diphenylphosphanyl)bis[(trimethylphosphane)cobalt(I)](Co—Co) Acta Crystallographica Section E |
| title | Bis(μ-diphenylphosphanyl)bis[(trimethylphosphane)cobalt(I)](Co—Co) |
| title_full | Bis(μ-diphenylphosphanyl)bis[(trimethylphosphane)cobalt(I)](Co—Co) |
| title_fullStr | Bis(μ-diphenylphosphanyl)bis[(trimethylphosphane)cobalt(I)](Co—Co) |
| title_full_unstemmed | Bis(μ-diphenylphosphanyl)bis[(trimethylphosphane)cobalt(I)](Co—Co) |
| title_short | Bis(μ-diphenylphosphanyl)bis[(trimethylphosphane)cobalt(I)](Co—Co) |
| title_sort | bis 956 diphenylphosphanyl bis trimethylphosphane cobalt i co 8212 co |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813027384 |
| work_keys_str_mv | AT robertbeck bis956diphenylphosphanylbistrimethylphosphanecobaltico8212co AT hansfriedrichklein bis956diphenylphosphanylbistrimethylphosphanecobaltico8212co |