2,4-Dibromo-6-{(E)-[(R)-1-phenylethyl]iminomethyl}phenol
In the title Schiff base, C15H13Br2NO, the benzene and phenyl rings form a dihedral angle of 75.18 (13)°. The N=C bond length of 1.263 (6) Å is shorter than of the N—C bond [1.476 (5) &a...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2009-12-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809044638 |
_version_ | 1818283695818145792 |
---|---|
author | Ke-Wei Lei Ya-Fen Ye Dong-Guo Xia |
author_facet | Ke-Wei Lei Ya-Fen Ye Dong-Guo Xia |
author_sort | Ke-Wei Lei |
collection | DOAJ |
description | In the title Schiff base, C15H13Br2NO, the benzene and phenyl rings form a dihedral angle of 75.18 (13)°. The N=C bond length of 1.263 (6) Å is shorter than of the N—C bond [1.476 (5) Å], indicating a double bond. In the crystal, there is some pseudosymmetry. This occurs because most of the two molecules are centrosymmetrically related. The molecular structure is stabilized by intramolecular O—H...N hydrogen bonds. |
first_indexed | 2024-12-13T00:41:00Z |
format | Article |
id | doaj.art-3b0d2279ef664b18954ad74411e4626c |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-13T00:41:00Z |
publishDate | 2009-12-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-3b0d2279ef664b18954ad74411e4626c2022-12-22T00:05:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512o3168o316810.1107/S16005368090446382,4-Dibromo-6-{(E)-[(R)-1-phenylethyl]iminomethyl}phenolKe-Wei LeiYa-Fen YeDong-Guo XiaIn the title Schiff base, C15H13Br2NO, the benzene and phenyl rings form a dihedral angle of 75.18 (13)°. The N=C bond length of 1.263 (6) Å is shorter than of the N—C bond [1.476 (5) Å], indicating a double bond. In the crystal, there is some pseudosymmetry. This occurs because most of the two molecules are centrosymmetrically related. The molecular structure is stabilized by intramolecular O—H...N hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536809044638 |
spellingShingle | Ke-Wei Lei Ya-Fen Ye Dong-Guo Xia 2,4-Dibromo-6-{(E)-[(R)-1-phenylethyl]iminomethyl}phenol Acta Crystallographica Section E |
title | 2,4-Dibromo-6-{(E)-[(R)-1-phenylethyl]iminomethyl}phenol |
title_full | 2,4-Dibromo-6-{(E)-[(R)-1-phenylethyl]iminomethyl}phenol |
title_fullStr | 2,4-Dibromo-6-{(E)-[(R)-1-phenylethyl]iminomethyl}phenol |
title_full_unstemmed | 2,4-Dibromo-6-{(E)-[(R)-1-phenylethyl]iminomethyl}phenol |
title_short | 2,4-Dibromo-6-{(E)-[(R)-1-phenylethyl]iminomethyl}phenol |
title_sort | 2 4 dibromo 6 e r 1 phenylethyl iminomethyl phenol |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536809044638 |
work_keys_str_mv | AT keweilei 24dibromo6er1phenylethyliminomethylphenol AT yafenye 24dibromo6er1phenylethyliminomethylphenol AT dongguoxia 24dibromo6er1phenylethyliminomethylphenol |