Rheological Properties and Structural Build-Up of Cement Based Materials with Addition of Nanoparticles: A Review

Nanoparticles improve the mechanical properties and durability of cement-based materials. However, owing to the high surface energy and specific surface areas of nanoparticles, the packing characteristic of cementitious particles will be affected. With the action of the electrostatic attraction and...

Full description

Bibliographic Details
Main Authors: Qiuchao Li, Yingfang Fan, Surendra P. Shah
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Buildings
Subjects:
Online Access:https://www.mdpi.com/2075-5309/12/12/2219
_version_ 1797461069560545280
author Qiuchao Li
Yingfang Fan
Surendra P. Shah
author_facet Qiuchao Li
Yingfang Fan
Surendra P. Shah
author_sort Qiuchao Li
collection DOAJ
description Nanoparticles improve the mechanical properties and durability of cement-based materials. However, owing to the high surface energy and specific surface areas of nanoparticles, the packing characteristic of cementitious particles will be affected. With the action of the electrostatic attraction and Van der Waals force, the cementitious particles are agglomerated into flocculation structures, and the free water is entrapped. Furthermore, as the water consumption of cement-based materials increases, the flowability gets worse, which is thought to be one of the reasons limiting its application in practical engineering. In addition, nanoparticles increase the viscosity and thixotropy of fresh cement-based materials and provide more nucleation sites in cement paste, accelerating the cement hydration process in early hydration. In this paper, the research progress on the rheological properties and structural build-up of cement-based materials with the addition of nanoparticles was reviewed. The applicability of rheological test methods and rheological models was summarized. The variation of rheological parameters of fresh cement-based materials affected by nanoparticles species, contents, dispersion method, superplasticizer, etc., were discussed. Based on the packing density, water film thickness, and flocculation structures, the action mechanism of nanoparticles on the rheological properties of cement-based materials was analyzed. Further research topics on the rheology and structural build-up of nano-modified cement-based materials are suggested as well.
first_indexed 2024-03-09T17:15:05Z
format Article
id doaj.art-3b2b495828964d9e9f7217384485a314
institution Directory Open Access Journal
issn 2075-5309
language English
last_indexed 2024-03-09T17:15:05Z
publishDate 2022-12-01
publisher MDPI AG
record_format Article
series Buildings
spelling doaj.art-3b2b495828964d9e9f7217384485a3142023-11-24T13:43:49ZengMDPI AGBuildings2075-53092022-12-011212221910.3390/buildings12122219Rheological Properties and Structural Build-Up of Cement Based Materials with Addition of Nanoparticles: A ReviewQiuchao Li0Yingfang Fan1Surendra P. Shah2Institute of Road and Bridge Engineering, Dalian Maritime University, Dalian 116026, ChinaInstitute of Road and Bridge Engineering, Dalian Maritime University, Dalian 116026, ChinaDepartment of Civil and Environmental Engineering, Northwestern University, Evanston, IL 60208, USANanoparticles improve the mechanical properties and durability of cement-based materials. However, owing to the high surface energy and specific surface areas of nanoparticles, the packing characteristic of cementitious particles will be affected. With the action of the electrostatic attraction and Van der Waals force, the cementitious particles are agglomerated into flocculation structures, and the free water is entrapped. Furthermore, as the water consumption of cement-based materials increases, the flowability gets worse, which is thought to be one of the reasons limiting its application in practical engineering. In addition, nanoparticles increase the viscosity and thixotropy of fresh cement-based materials and provide more nucleation sites in cement paste, accelerating the cement hydration process in early hydration. In this paper, the research progress on the rheological properties and structural build-up of cement-based materials with the addition of nanoparticles was reviewed. The applicability of rheological test methods and rheological models was summarized. The variation of rheological parameters of fresh cement-based materials affected by nanoparticles species, contents, dispersion method, superplasticizer, etc., were discussed. Based on the packing density, water film thickness, and flocculation structures, the action mechanism of nanoparticles on the rheological properties of cement-based materials was analyzed. Further research topics on the rheology and structural build-up of nano-modified cement-based materials are suggested as well.https://www.mdpi.com/2075-5309/12/12/2219nanoparticlescement-based materialsrheologystructural build-upaction mechanism
spellingShingle Qiuchao Li
Yingfang Fan
Surendra P. Shah
Rheological Properties and Structural Build-Up of Cement Based Materials with Addition of Nanoparticles: A Review
Buildings
nanoparticles
cement-based materials
rheology
structural build-up
action mechanism
title Rheological Properties and Structural Build-Up of Cement Based Materials with Addition of Nanoparticles: A Review
title_full Rheological Properties and Structural Build-Up of Cement Based Materials with Addition of Nanoparticles: A Review
title_fullStr Rheological Properties and Structural Build-Up of Cement Based Materials with Addition of Nanoparticles: A Review
title_full_unstemmed Rheological Properties and Structural Build-Up of Cement Based Materials with Addition of Nanoparticles: A Review
title_short Rheological Properties and Structural Build-Up of Cement Based Materials with Addition of Nanoparticles: A Review
title_sort rheological properties and structural build up of cement based materials with addition of nanoparticles a review
topic nanoparticles
cement-based materials
rheology
structural build-up
action mechanism
url https://www.mdpi.com/2075-5309/12/12/2219
work_keys_str_mv AT qiuchaoli rheologicalpropertiesandstructuralbuildupofcementbasedmaterialswithadditionofnanoparticlesareview
AT yingfangfan rheologicalpropertiesandstructuralbuildupofcementbasedmaterialswithadditionofnanoparticlesareview
AT surendrapshah rheologicalpropertiesandstructuralbuildupofcementbasedmaterialswithadditionofnanoparticlesareview