Bis[tris(1H-pyrazol-1-yl-κN2)methane]nickel(II) bis{[tris(1H-pyrazol-1-yl-κN2)methane]tris(thiocyanato-κN)nickelate(II)} methanol disolvate
Attempts to prepare the mononuclear [(tpm)NiIIL3]−1 [tpm = tris(1H-pyrazol-1-yl)methane and L = thiocyanate] anion yielded the methanol-solvated salt, [(tpm)2NiII][(tpm)NiII(NCS)3]2·2CH3OH or [Ni(C10H10N6)2][Ni(NCS)3(C10H10N6)]2·2CH3OH. The asymmetric unit con...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811045144 |
| _version_ | 1818085599037358080 |
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| author | Ganna Lyubartseva Sean Parkin Uma Prasad Mallik |
| author_facet | Ganna Lyubartseva Sean Parkin Uma Prasad Mallik |
| author_sort | Ganna Lyubartseva |
| collection | DOAJ |
| description | Attempts to prepare the mononuclear [(tpm)NiIIL3]−1 [tpm = tris(1H-pyrazol-1-yl)methane and L = thiocyanate] anion yielded the methanol-solvated salt, [(tpm)2NiII][(tpm)NiII(NCS)3]2·2CH3OH or [Ni(C10H10N6)2][Ni(NCS)3(C10H10N6)]2·2CH3OH. The asymmetric unit consists of half a centrosymmetric bis[tris(1H-pyrazol-1-yl)methane]nickel(II) cation and an octahedral nickelate(II) anion bound to one tpm and three L ligands, and a methanol solvent molecule. One of the L ligands is disordered over two positions with occupancy factors of 0.650 (3) and 0.350 (3). There are O—H...S interactions between the methanol and the disordered thiocyanate anion, and a weak C—H...O hydrogen bond between the cation and the methanol O atom. |
| first_indexed | 2024-12-10T20:12:20Z |
| format | Article |
| id | doaj.art-3b3e938745334fb4a1a8eff1c05d192e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T20:12:20Z |
| publishDate | 2011-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-3b3e938745334fb4a1a8eff1c05d192e2022-12-22T01:35:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1656m165710.1107/S1600536811045144Bis[tris(1H-pyrazol-1-yl-κN2)methane]nickel(II) bis{[tris(1H-pyrazol-1-yl-κN2)methane]tris(thiocyanato-κN)nickelate(II)} methanol disolvateGanna LyubartsevaSean ParkinUma Prasad MallikAttempts to prepare the mononuclear [(tpm)NiIIL3]−1 [tpm = tris(1H-pyrazol-1-yl)methane and L = thiocyanate] anion yielded the methanol-solvated salt, [(tpm)2NiII][(tpm)NiII(NCS)3]2·2CH3OH or [Ni(C10H10N6)2][Ni(NCS)3(C10H10N6)]2·2CH3OH. The asymmetric unit consists of half a centrosymmetric bis[tris(1H-pyrazol-1-yl)methane]nickel(II) cation and an octahedral nickelate(II) anion bound to one tpm and three L ligands, and a methanol solvent molecule. One of the L ligands is disordered over two positions with occupancy factors of 0.650 (3) and 0.350 (3). There are O—H...S interactions between the methanol and the disordered thiocyanate anion, and a weak C—H...O hydrogen bond between the cation and the methanol O atom.http://scripts.iucr.org/cgi-bin/paper?S1600536811045144 |
| spellingShingle | Ganna Lyubartseva Sean Parkin Uma Prasad Mallik Bis[tris(1H-pyrazol-1-yl-κN2)methane]nickel(II) bis{[tris(1H-pyrazol-1-yl-κN2)methane]tris(thiocyanato-κN)nickelate(II)} methanol disolvate Acta Crystallographica Section E |
| title | Bis[tris(1H-pyrazol-1-yl-κN2)methane]nickel(II) bis{[tris(1H-pyrazol-1-yl-κN2)methane]tris(thiocyanato-κN)nickelate(II)} methanol disolvate |
| title_full | Bis[tris(1H-pyrazol-1-yl-κN2)methane]nickel(II) bis{[tris(1H-pyrazol-1-yl-κN2)methane]tris(thiocyanato-κN)nickelate(II)} methanol disolvate |
| title_fullStr | Bis[tris(1H-pyrazol-1-yl-κN2)methane]nickel(II) bis{[tris(1H-pyrazol-1-yl-κN2)methane]tris(thiocyanato-κN)nickelate(II)} methanol disolvate |
| title_full_unstemmed | Bis[tris(1H-pyrazol-1-yl-κN2)methane]nickel(II) bis{[tris(1H-pyrazol-1-yl-κN2)methane]tris(thiocyanato-κN)nickelate(II)} methanol disolvate |
| title_short | Bis[tris(1H-pyrazol-1-yl-κN2)methane]nickel(II) bis{[tris(1H-pyrazol-1-yl-κN2)methane]tris(thiocyanato-κN)nickelate(II)} methanol disolvate |
| title_sort | bis tris 1h pyrazol 1 yl amp 954 n2 methane nickel ii bis tris 1h pyrazol 1 yl amp 954 n2 methane tris thiocyanato amp 954 n nickelate ii methanol disolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811045144 |
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