Small-Angle Scattering from Fractional Brownian Surfaces

Recent developments in nanotechnology have allowed the fabrication of a new generation of advanced materials with various fractal-like geometries. Fractional Brownian surfaces (fBs) are often used as models to simulate and characterize these complex geometries, such as the surface of particles in di...

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Main Author: Eugen Mircea Anitas
Format: Article
Language:English
Published: MDPI AG 2021-10-01
Series:Symmetry
Subjects:
Online Access:https://www.mdpi.com/2073-8994/13/11/2042
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author Eugen Mircea Anitas
author_facet Eugen Mircea Anitas
author_sort Eugen Mircea Anitas
collection DOAJ
description Recent developments in nanotechnology have allowed the fabrication of a new generation of advanced materials with various fractal-like geometries. Fractional Brownian surfaces (fBs) are often used as models to simulate and characterize these complex geometries, such as the surface of particles in dilute particulate systems (e.g., colloids) or the interfaces in non-particulate two-phase systems (e.g., semicrystalline polymers with crystalline and amorphous phases). However, for such systems, a realistic simulation involves parameters averaged over a macroscopic volume. Here, a method based on small-angle scattering technique is proposed to extract the main structural parameters of surfaces/interfaces from experimental data. It involves the analysis of scattering intensities and the corresponding pair distance distribution functions. This allows the extraction of information with respect to the overall size, fractal dimension, Hurst and spectral exponents. The method is applied to several classes of fBs, and it is shown that the obtained numerical values of the structural parameters are in very good agreement with theoretical ones.
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spelling doaj.art-3b5fbe1ad2634a248878cf10c49775ac2023-11-23T01:43:55ZengMDPI AGSymmetry2073-89942021-10-011311204210.3390/sym13112042Small-Angle Scattering from Fractional Brownian SurfacesEugen Mircea Anitas0Joint Institute for Nuclear Research, 141980 Dubna, RussiaRecent developments in nanotechnology have allowed the fabrication of a new generation of advanced materials with various fractal-like geometries. Fractional Brownian surfaces (fBs) are often used as models to simulate and characterize these complex geometries, such as the surface of particles in dilute particulate systems (e.g., colloids) or the interfaces in non-particulate two-phase systems (e.g., semicrystalline polymers with crystalline and amorphous phases). However, for such systems, a realistic simulation involves parameters averaged over a macroscopic volume. Here, a method based on small-angle scattering technique is proposed to extract the main structural parameters of surfaces/interfaces from experimental data. It involves the analysis of scattering intensities and the corresponding pair distance distribution functions. This allows the extraction of information with respect to the overall size, fractal dimension, Hurst and spectral exponents. The method is applied to several classes of fBs, and it is shown that the obtained numerical values of the structural parameters are in very good agreement with theoretical ones.https://www.mdpi.com/2073-8994/13/11/2042small-angle scatteringfractional Brownian surfacesfractal dimensionHurst exponentspectral exponent
spellingShingle Eugen Mircea Anitas
Small-Angle Scattering from Fractional Brownian Surfaces
Symmetry
small-angle scattering
fractional Brownian surfaces
fractal dimension
Hurst exponent
spectral exponent
title Small-Angle Scattering from Fractional Brownian Surfaces
title_full Small-Angle Scattering from Fractional Brownian Surfaces
title_fullStr Small-Angle Scattering from Fractional Brownian Surfaces
title_full_unstemmed Small-Angle Scattering from Fractional Brownian Surfaces
title_short Small-Angle Scattering from Fractional Brownian Surfaces
title_sort small angle scattering from fractional brownian surfaces
topic small-angle scattering
fractional Brownian surfaces
fractal dimension
Hurst exponent
spectral exponent
url https://www.mdpi.com/2073-8994/13/11/2042
work_keys_str_mv AT eugenmirceaanitas smallanglescatteringfromfractionalbrowniansurfaces