Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing Method
The increasing use of renewable energy sources increases the need for electricity storage systems. In this work, the possibility of renewing worn-out battery Pb electrodes by applying Ar and O<sub>2</sub> gas plasma in a magnetron vacuum system was investigated. As shown by the SEM resul...
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MDPI AG
2023-04-01
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author | Žydrūnas Kavaliauskas Igor Šajev Giedrius Blažiūnas Giedrius Gecevičius |
author_facet | Žydrūnas Kavaliauskas Igor Šajev Giedrius Blažiūnas Giedrius Gecevičius |
author_sort | Žydrūnas Kavaliauskas |
collection | DOAJ |
description | The increasing use of renewable energy sources increases the need for electricity storage systems. In this work, the possibility of renewing worn-out battery Pb electrodes by applying Ar and O<sub>2</sub> gas plasma in a magnetron vacuum system was investigated. As shown by the SEM results of the surface of Pb electrodes, after exposure to O<sub>2</sub> plasma, the surface of Pb electrodes consists of irregularly shaped microstructures. Analyzing the XRD results revealed that the spectrum peaks of the Pb<sub>4</sub>O<sub>3</sub>SO<sub>4</sub> compound are more pronounced in the case of the electrodes of the worn battery than those electrodes that were exposed to Ar and O<sub>2</sub> gas plasma. It was observed that the process of renewing Pb electrodes in Ar and O<sub>2</sub> plasma has a positive effect. This effect is also confirmed by the results of EDS studies, as the chemical compounds that inhibit the charge/discharge process are reduced, and the percentage of pure lead increases from 68.2% (in the case of worn electrodes) to 81–82% (when the worn electrodes were processed using Ar and O<sub>2</sub> plasma). |
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institution | Directory Open Access Journal |
issn | 2076-3417 |
language | English |
last_indexed | 2024-03-11T04:24:03Z |
publishDate | 2023-04-01 |
publisher | MDPI AG |
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spelling | doaj.art-3b66864df95340759ec454c5f43a38bd2023-11-17T22:34:20ZengMDPI AGApplied Sciences2076-34172023-04-01139546310.3390/app13095463Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing MethodŽydrūnas Kavaliauskas0Igor Šajev1Giedrius Blažiūnas2Giedrius Gecevičius3Department of Industrial Engineering and Robotics, Kauno Kolegija Higher Education Institution, Pramonės Ave. 20, LT-50468 Kaunas, LithuaniaDepartment of Industrial Engineering and Robotics, Kauno Kolegija Higher Education Institution, Pramonės Ave. 20, LT-50468 Kaunas, LithuaniaDepartment of Industrial Engineering and Robotics, Kauno Kolegija Higher Education Institution, Pramonės Ave. 20, LT-50468 Kaunas, LithuaniaDepartment of Industrial Engineering and Robotics, Kauno Kolegija Higher Education Institution, Pramonės Ave. 20, LT-50468 Kaunas, LithuaniaThe increasing use of renewable energy sources increases the need for electricity storage systems. In this work, the possibility of renewing worn-out battery Pb electrodes by applying Ar and O<sub>2</sub> gas plasma in a magnetron vacuum system was investigated. As shown by the SEM results of the surface of Pb electrodes, after exposure to O<sub>2</sub> plasma, the surface of Pb electrodes consists of irregularly shaped microstructures. Analyzing the XRD results revealed that the spectrum peaks of the Pb<sub>4</sub>O<sub>3</sub>SO<sub>4</sub> compound are more pronounced in the case of the electrodes of the worn battery than those electrodes that were exposed to Ar and O<sub>2</sub> gas plasma. It was observed that the process of renewing Pb electrodes in Ar and O<sub>2</sub> plasma has a positive effect. This effect is also confirmed by the results of EDS studies, as the chemical compounds that inhibit the charge/discharge process are reduced, and the percentage of pure lead increases from 68.2% (in the case of worn electrodes) to 81–82% (when the worn electrodes were processed using Ar and O<sub>2</sub> plasma).https://www.mdpi.com/2076-3417/13/9/5463batteriesplasma processingPb electrodes renewalmagnetron system |
spellingShingle | Žydrūnas Kavaliauskas Igor Šajev Giedrius Blažiūnas Giedrius Gecevičius Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing Method Applied Sciences batteries plasma processing Pb electrodes renewal magnetron system |
title | Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing Method |
title_full | Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing Method |
title_fullStr | Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing Method |
title_full_unstemmed | Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing Method |
title_short | Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing Method |
title_sort | renewal of lead battery electrodes using a plasma chemical processing method |
topic | batteries plasma processing Pb electrodes renewal magnetron system |
url | https://www.mdpi.com/2076-3417/13/9/5463 |
work_keys_str_mv | AT zydrunaskavaliauskas renewalofleadbatteryelectrodesusingaplasmachemicalprocessingmethod AT igorsajev renewalofleadbatteryelectrodesusingaplasmachemicalprocessingmethod AT giedriusblaziunas renewalofleadbatteryelectrodesusingaplasmachemicalprocessingmethod AT giedriusgecevicius renewalofleadbatteryelectrodesusingaplasmachemicalprocessingmethod |