Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing Method

The increasing use of renewable energy sources increases the need for electricity storage systems. In this work, the possibility of renewing worn-out battery Pb electrodes by applying Ar and O<sub>2</sub> gas plasma in a magnetron vacuum system was investigated. As shown by the SEM resul...

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Main Authors: Žydrūnas Kavaliauskas, Igor Šajev, Giedrius Blažiūnas, Giedrius Gecevičius
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/13/9/5463
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author Žydrūnas Kavaliauskas
Igor Šajev
Giedrius Blažiūnas
Giedrius Gecevičius
author_facet Žydrūnas Kavaliauskas
Igor Šajev
Giedrius Blažiūnas
Giedrius Gecevičius
author_sort Žydrūnas Kavaliauskas
collection DOAJ
description The increasing use of renewable energy sources increases the need for electricity storage systems. In this work, the possibility of renewing worn-out battery Pb electrodes by applying Ar and O<sub>2</sub> gas plasma in a magnetron vacuum system was investigated. As shown by the SEM results of the surface of Pb electrodes, after exposure to O<sub>2</sub> plasma, the surface of Pb electrodes consists of irregularly shaped microstructures. Analyzing the XRD results revealed that the spectrum peaks of the Pb<sub>4</sub>O<sub>3</sub>SO<sub>4</sub> compound are more pronounced in the case of the electrodes of the worn battery than those electrodes that were exposed to Ar and O<sub>2</sub> gas plasma. It was observed that the process of renewing Pb electrodes in Ar and O<sub>2</sub> plasma has a positive effect. This effect is also confirmed by the results of EDS studies, as the chemical compounds that inhibit the charge/discharge process are reduced, and the percentage of pure lead increases from 68.2% (in the case of worn electrodes) to 81–82% (when the worn electrodes were processed using Ar and O<sub>2</sub> plasma).
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spelling doaj.art-3b66864df95340759ec454c5f43a38bd2023-11-17T22:34:20ZengMDPI AGApplied Sciences2076-34172023-04-01139546310.3390/app13095463Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing MethodŽydrūnas Kavaliauskas0Igor Šajev1Giedrius Blažiūnas2Giedrius Gecevičius3Department of Industrial Engineering and Robotics, Kauno Kolegija Higher Education Institution, Pramonės Ave. 20, LT-50468 Kaunas, LithuaniaDepartment of Industrial Engineering and Robotics, Kauno Kolegija Higher Education Institution, Pramonės Ave. 20, LT-50468 Kaunas, LithuaniaDepartment of Industrial Engineering and Robotics, Kauno Kolegija Higher Education Institution, Pramonės Ave. 20, LT-50468 Kaunas, LithuaniaDepartment of Industrial Engineering and Robotics, Kauno Kolegija Higher Education Institution, Pramonės Ave. 20, LT-50468 Kaunas, LithuaniaThe increasing use of renewable energy sources increases the need for electricity storage systems. In this work, the possibility of renewing worn-out battery Pb electrodes by applying Ar and O<sub>2</sub> gas plasma in a magnetron vacuum system was investigated. As shown by the SEM results of the surface of Pb electrodes, after exposure to O<sub>2</sub> plasma, the surface of Pb electrodes consists of irregularly shaped microstructures. Analyzing the XRD results revealed that the spectrum peaks of the Pb<sub>4</sub>O<sub>3</sub>SO<sub>4</sub> compound are more pronounced in the case of the electrodes of the worn battery than those electrodes that were exposed to Ar and O<sub>2</sub> gas plasma. It was observed that the process of renewing Pb electrodes in Ar and O<sub>2</sub> plasma has a positive effect. This effect is also confirmed by the results of EDS studies, as the chemical compounds that inhibit the charge/discharge process are reduced, and the percentage of pure lead increases from 68.2% (in the case of worn electrodes) to 81–82% (when the worn electrodes were processed using Ar and O<sub>2</sub> plasma).https://www.mdpi.com/2076-3417/13/9/5463batteriesplasma processingPb electrodes renewalmagnetron system
spellingShingle Žydrūnas Kavaliauskas
Igor Šajev
Giedrius Blažiūnas
Giedrius Gecevičius
Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing Method
Applied Sciences
batteries
plasma processing
Pb electrodes renewal
magnetron system
title Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing Method
title_full Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing Method
title_fullStr Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing Method
title_full_unstemmed Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing Method
title_short Renewal of Lead Battery Electrodes Using a Plasma—Chemical Processing Method
title_sort renewal of lead battery electrodes using a plasma chemical processing method
topic batteries
plasma processing
Pb electrodes renewal
magnetron system
url https://www.mdpi.com/2076-3417/13/9/5463
work_keys_str_mv AT zydrunaskavaliauskas renewalofleadbatteryelectrodesusingaplasmachemicalprocessingmethod
AT igorsajev renewalofleadbatteryelectrodesusingaplasmachemicalprocessingmethod
AT giedriusblaziunas renewalofleadbatteryelectrodesusingaplasmachemicalprocessingmethod
AT giedriusgecevicius renewalofleadbatteryelectrodesusingaplasmachemicalprocessingmethod