Metal–Organic Frameworks and Gas Hydrate Synergy: A Pandora’s Box of Unanswered Questions and Revelations
Recent research on the role of nanomaterials in gas hydrate science and a few review papers have highlighted the positive synergies between gas hydrates and metal–organic frameworks (MOFs) for gas separation and storage. Metal–organic frameworks consist of metal nodes and organic linkers connected b...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-12-01
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| Series: | Energies |
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| Online Access: | https://www.mdpi.com/1996-1073/16/1/111 |
| _version_ | 1827760801587396608 |
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| author | Jyoti Shanker Pandey Nicolas von Solms |
| author_facet | Jyoti Shanker Pandey Nicolas von Solms |
| author_sort | Jyoti Shanker Pandey |
| collection | DOAJ |
| description | Recent research on the role of nanomaterials in gas hydrate science and a few review papers have highlighted the positive synergies between gas hydrates and metal–organic frameworks (MOFs) for gas separation and storage. Metal–organic frameworks consist of metal nodes and organic linkers connected by coordination bonds to form programmable modular structures that are symmetric and have tunable properties. Metal–organic frameworks, also known as microporous or nanoporous materials, provide a large pore volume and surface area suitable for capturing, separating and storing gases through physisorption mechanisms. However, water and water interactions within the nanopores, open metal sites, coordination bonds and surface make metal–organic framework usage in water-based technologies an exciting research topic. Water-based gas hydrate technology could be potential technology that can take advantage of MOF tunable properties, such as a large surface area and a high pore volume, to improve its efficiency and formation mechanism. For the authors of this review, the synergy of MOFs and gas hydrates resembles a Pandora’s box of unanswered questions and revelations. Therefore, this review examines the current state of the art, including present research on gas storage and separation using gas hydrates in the presence of a MOF. In addition, critical technical aspects, such as the water stability of MOFs, the nano confinement effect and water properties in the nanopores, are presented to stimulate critical thinking among scientists in hydrate research to fully exploit the synergies between MOFs and hydrates. This review ends with the authors’ opinion on potential research areas, unanswered questions and practical implications and prospects. |
| first_indexed | 2024-03-11T10:02:47Z |
| format | Article |
| id | doaj.art-3b698691c8914aeb984bc3dcd7f7f3fb |
| institution | Directory Open Access Journal |
| issn | 1996-1073 |
| language | English |
| last_indexed | 2024-03-11T10:02:47Z |
| publishDate | 2022-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Energies |
| spelling | doaj.art-3b698691c8914aeb984bc3dcd7f7f3fb2023-11-16T15:14:40ZengMDPI AGEnergies1996-10732022-12-0116111110.3390/en16010111Metal–Organic Frameworks and Gas Hydrate Synergy: A Pandora’s Box of Unanswered Questions and RevelationsJyoti Shanker Pandey0Nicolas von Solms1Center for Energy Resource Engineering (CERE), Department of Chemical Engineering, Technical University of Denmark, 2800 Kgs. Lyngby, DenmarkCenter for Energy Resource Engineering (CERE), Department of Chemical Engineering, Technical University of Denmark, 2800 Kgs. Lyngby, DenmarkRecent research on the role of nanomaterials in gas hydrate science and a few review papers have highlighted the positive synergies between gas hydrates and metal–organic frameworks (MOFs) for gas separation and storage. Metal–organic frameworks consist of metal nodes and organic linkers connected by coordination bonds to form programmable modular structures that are symmetric and have tunable properties. Metal–organic frameworks, also known as microporous or nanoporous materials, provide a large pore volume and surface area suitable for capturing, separating and storing gases through physisorption mechanisms. However, water and water interactions within the nanopores, open metal sites, coordination bonds and surface make metal–organic framework usage in water-based technologies an exciting research topic. Water-based gas hydrate technology could be potential technology that can take advantage of MOF tunable properties, such as a large surface area and a high pore volume, to improve its efficiency and formation mechanism. For the authors of this review, the synergy of MOFs and gas hydrates resembles a Pandora’s box of unanswered questions and revelations. Therefore, this review examines the current state of the art, including present research on gas storage and separation using gas hydrates in the presence of a MOF. In addition, critical technical aspects, such as the water stability of MOFs, the nano confinement effect and water properties in the nanopores, are presented to stimulate critical thinking among scientists in hydrate research to fully exploit the synergies between MOFs and hydrates. This review ends with the authors’ opinion on potential research areas, unanswered questions and practical implications and prospects.https://www.mdpi.com/1996-1073/16/1/111metal–organic frameworknano confinementphase equilibriumgas hydrate formation and dissociation |
| spellingShingle | Jyoti Shanker Pandey Nicolas von Solms Metal–Organic Frameworks and Gas Hydrate Synergy: A Pandora’s Box of Unanswered Questions and Revelations Energies metal–organic framework nano confinement phase equilibrium gas hydrate formation and dissociation |
| title | Metal–Organic Frameworks and Gas Hydrate Synergy: A Pandora’s Box of Unanswered Questions and Revelations |
| title_full | Metal–Organic Frameworks and Gas Hydrate Synergy: A Pandora’s Box of Unanswered Questions and Revelations |
| title_fullStr | Metal–Organic Frameworks and Gas Hydrate Synergy: A Pandora’s Box of Unanswered Questions and Revelations |
| title_full_unstemmed | Metal–Organic Frameworks and Gas Hydrate Synergy: A Pandora’s Box of Unanswered Questions and Revelations |
| title_short | Metal–Organic Frameworks and Gas Hydrate Synergy: A Pandora’s Box of Unanswered Questions and Revelations |
| title_sort | metal organic frameworks and gas hydrate synergy a pandora s box of unanswered questions and revelations |
| topic | metal–organic framework nano confinement phase equilibrium gas hydrate formation and dissociation |
| url | https://www.mdpi.com/1996-1073/16/1/111 |
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