Preparation and Application of Polyrotaxane Cross-Linking Agent Based on Cyclodextrin in Gel Materials Field

The cross-linking point of a conventional chemical cross-linking agent is fixed. Therefore, gels that are prepared with a conventional cross-linking agent have poor deformability, strength, shear resistance, and further properties. Some researchers have prepared a new cross-linking agent using cyclo...

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Main Authors: Siyuan Liu, Jingxi Zheng, Jiaqin Wang, Shanghao Liu, Xianli Zhang, Dan Bao, Peng Zhang
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Gels
Subjects:
Online Access:https://www.mdpi.com/2310-2861/9/11/854
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author Siyuan Liu
Jingxi Zheng
Jiaqin Wang
Shanghao Liu
Xianli Zhang
Dan Bao
Peng Zhang
author_facet Siyuan Liu
Jingxi Zheng
Jiaqin Wang
Shanghao Liu
Xianli Zhang
Dan Bao
Peng Zhang
author_sort Siyuan Liu
collection DOAJ
description The cross-linking point of a conventional chemical cross-linking agent is fixed. Therefore, gels that are prepared with a conventional cross-linking agent have poor deformability, strength, shear resistance, and further properties. Some researchers have prepared a new cross-linking agent using cyclodextrin (CD). In a polyrotaxane cross-linking agent, the cross-linking points can slide freely along the molecule chain. The special “slide ring” structure can provide better elongation, strength, and other properties to gels, which can effectively expand the application of the gel’s materials. This paper summarizes the preparation methods and applications from different types of CD and compares the improvements of properties (swelling, viscoelastic properties, etc.). In addition, the current results of our group are presented, and some ideas are provided for the development of polyrotaxane cross-linking agents.
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spelling doaj.art-3b7ac82abeac43d4b9bfa318e14b75ac2023-11-24T14:43:17ZengMDPI AGGels2310-28612023-10-0191185410.3390/gels9110854Preparation and Application of Polyrotaxane Cross-Linking Agent Based on Cyclodextrin in Gel Materials FieldSiyuan Liu0Jingxi Zheng1Jiaqin Wang2Shanghao Liu3Xianli Zhang4Dan Bao5Peng Zhang6School of Chemistry and Chemical Engineering, Chongqing University of Science and Technology, Chongqing 401331, ChinaSchool of Chemistry and Chemical Engineering, Chongqing University of Science and Technology, Chongqing 401331, ChinaSchool of Chemistry and Chemical Engineering, Chongqing University of Science and Technology, Chongqing 401331, ChinaSchool of Chemistry and Chemical Engineering, Chongqing University of Science and Technology, Chongqing 401331, ChinaSchool of Chemistry and Chemical Engineering, Chongqing University of Science and Technology, Chongqing 401331, ChinaSchool of Chemistry and Chemical Engineering, Chongqing University of Science and Technology, Chongqing 401331, ChinaSchool of Chemistry and Chemical Engineering, Chongqing University of Science and Technology, Chongqing 401331, ChinaThe cross-linking point of a conventional chemical cross-linking agent is fixed. Therefore, gels that are prepared with a conventional cross-linking agent have poor deformability, strength, shear resistance, and further properties. Some researchers have prepared a new cross-linking agent using cyclodextrin (CD). In a polyrotaxane cross-linking agent, the cross-linking points can slide freely along the molecule chain. The special “slide ring” structure can provide better elongation, strength, and other properties to gels, which can effectively expand the application of the gel’s materials. This paper summarizes the preparation methods and applications from different types of CD and compares the improvements of properties (swelling, viscoelastic properties, etc.). In addition, the current results of our group are presented, and some ideas are provided for the development of polyrotaxane cross-linking agents.https://www.mdpi.com/2310-2861/9/11/854cyclodextrinpolyrotaxane cross-linking agentpreparationapplication“slide ring” structure
spellingShingle Siyuan Liu
Jingxi Zheng
Jiaqin Wang
Shanghao Liu
Xianli Zhang
Dan Bao
Peng Zhang
Preparation and Application of Polyrotaxane Cross-Linking Agent Based on Cyclodextrin in Gel Materials Field
Gels
cyclodextrin
polyrotaxane cross-linking agent
preparation
application
“slide ring” structure
title Preparation and Application of Polyrotaxane Cross-Linking Agent Based on Cyclodextrin in Gel Materials Field
title_full Preparation and Application of Polyrotaxane Cross-Linking Agent Based on Cyclodextrin in Gel Materials Field
title_fullStr Preparation and Application of Polyrotaxane Cross-Linking Agent Based on Cyclodextrin in Gel Materials Field
title_full_unstemmed Preparation and Application of Polyrotaxane Cross-Linking Agent Based on Cyclodextrin in Gel Materials Field
title_short Preparation and Application of Polyrotaxane Cross-Linking Agent Based on Cyclodextrin in Gel Materials Field
title_sort preparation and application of polyrotaxane cross linking agent based on cyclodextrin in gel materials field
topic cyclodextrin
polyrotaxane cross-linking agent
preparation
application
“slide ring” structure
url https://www.mdpi.com/2310-2861/9/11/854
work_keys_str_mv AT siyuanliu preparationandapplicationofpolyrotaxanecrosslinkingagentbasedoncyclodextriningelmaterialsfield
AT jingxizheng preparationandapplicationofpolyrotaxanecrosslinkingagentbasedoncyclodextriningelmaterialsfield
AT jiaqinwang preparationandapplicationofpolyrotaxanecrosslinkingagentbasedoncyclodextriningelmaterialsfield
AT shanghaoliu preparationandapplicationofpolyrotaxanecrosslinkingagentbasedoncyclodextriningelmaterialsfield
AT xianlizhang preparationandapplicationofpolyrotaxanecrosslinkingagentbasedoncyclodextriningelmaterialsfield
AT danbao preparationandapplicationofpolyrotaxanecrosslinkingagentbasedoncyclodextriningelmaterialsfield
AT pengzhang preparationandapplicationofpolyrotaxanecrosslinkingagentbasedoncyclodextriningelmaterialsfield