Heavy Metal Distribution in the Bottom Sediments Along Tietê River Basin

Analysis of heavy metals in fluvial sediments has been used to better understand the potential hazards and criticaltoxicity of heavy metals mainly related to the anthropogenic influences of urban sewage, industrial effluents and agriculturalactivity. The present study analyzed the heavy metals, such...

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Main Authors: Jefferson Mortatti, Christophe Hissler, Jean-Luc Probst
Format: Article
Language:English
Published: Universidade de São Paulo 2010-07-01
Series:Geologia USP. Série Científica
Subjects:
Online Access:http://ppegeo-local.igc.usp.br/pdf/guspsc/v10n2/01.pdf
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author Jefferson Mortatti
Christophe Hissler
Jean-Luc Probst
author_facet Jefferson Mortatti
Christophe Hissler
Jean-Luc Probst
author_sort Jefferson Mortatti
collection DOAJ
description Analysis of heavy metals in fluvial sediments has been used to better understand the potential hazards and criticaltoxicity of heavy metals mainly related to the anthropogenic influences of urban sewage, industrial effluents and agriculturalactivity. The present study analyzed the heavy metals, such as Cr, Cu, Ni, Zn and Pb, in the bottom sediments along the TietêRiver basin, a polluted watershed in the Southeast region of Brazil. The distribution of the concentrations of heavy metals inthe upper basin decreased in the following order: Zn > Cr > Pb > Ni > Cu, whereas, in the middle part of the basin (whichis under strong urban and industrial influences), high concentrations of Zn, Cu and Cr were observed, measuring 648, 200and 183 μg g-1, respectively. The sequential chemical extraction in relation to the total concentration was used to assessthe potential bioavailability of heavy metals. In the upper part of the basin, the heavy metals extracted from the bottomsediments were mainly related to the residual fraction, whereas, in the middle part of the basin, the bioavailability of Zn, Crand Ni was higher than 60%, and these metals were mainly related to the iron oxide phase. The high concentration of heavymetals observed in the middle basin of the Tietê river (after the metropolitan area of São Paulo), when compared with theaverage concentration found in the geochemical bottom, showed that, in terms of enrichment factor and geoaccumulationindex, the degree of pollution by Zn is high and by Ni is high to moderate in the downstream direction.
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spelling doaj.art-3bd42872de2d4214be9c7055d0c976882022-12-22T01:36:58ZengUniversidade de São PauloGeologia USP. Série Científica1519-874X2010-07-01102311Heavy Metal Distribution in the Bottom Sediments Along Tietê River BasinJefferson MortattiChristophe HisslerJean-Luc ProbstAnalysis of heavy metals in fluvial sediments has been used to better understand the potential hazards and criticaltoxicity of heavy metals mainly related to the anthropogenic influences of urban sewage, industrial effluents and agriculturalactivity. The present study analyzed the heavy metals, such as Cr, Cu, Ni, Zn and Pb, in the bottom sediments along the TietêRiver basin, a polluted watershed in the Southeast region of Brazil. The distribution of the concentrations of heavy metals inthe upper basin decreased in the following order: Zn > Cr > Pb > Ni > Cu, whereas, in the middle part of the basin (whichis under strong urban and industrial influences), high concentrations of Zn, Cu and Cr were observed, measuring 648, 200and 183 μg g-1, respectively. The sequential chemical extraction in relation to the total concentration was used to assessthe potential bioavailability of heavy metals. In the upper part of the basin, the heavy metals extracted from the bottomsediments were mainly related to the residual fraction, whereas, in the middle part of the basin, the bioavailability of Zn, Crand Ni was higher than 60%, and these metals were mainly related to the iron oxide phase. The high concentration of heavymetals observed in the middle basin of the Tietê river (after the metropolitan area of São Paulo), when compared with theaverage concentration found in the geochemical bottom, showed that, in terms of enrichment factor and geoaccumulationindex, the degree of pollution by Zn is high and by Ni is high to moderate in the downstream direction.http://ppegeo-local.igc.usp.br/pdf/guspsc/v10n2/01.pdfTietê RiverHeavy metalBottom sedimentSequential extractionEFIgeo
spellingShingle Jefferson Mortatti
Christophe Hissler
Jean-Luc Probst
Heavy Metal Distribution in the Bottom Sediments Along Tietê River Basin
Geologia USP. Série Científica
Tietê River
Heavy metal
Bottom sediment
Sequential extraction
EF
Igeo
title Heavy Metal Distribution in the Bottom Sediments Along Tietê River Basin
title_full Heavy Metal Distribution in the Bottom Sediments Along Tietê River Basin
title_fullStr Heavy Metal Distribution in the Bottom Sediments Along Tietê River Basin
title_full_unstemmed Heavy Metal Distribution in the Bottom Sediments Along Tietê River Basin
title_short Heavy Metal Distribution in the Bottom Sediments Along Tietê River Basin
title_sort heavy metal distribution in the bottom sediments along tiete river basin
topic Tietê River
Heavy metal
Bottom sediment
Sequential extraction
EF
Igeo
url http://ppegeo-local.igc.usp.br/pdf/guspsc/v10n2/01.pdf
work_keys_str_mv AT jeffersonmortatti heavymetaldistributioninthebottomsedimentsalongtieteriverbasin
AT christophehissler heavymetaldistributioninthebottomsedimentsalongtieteriverbasin
AT jeanlucprobst heavymetaldistributioninthebottomsedimentsalongtieteriverbasin