Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN4}bis(2,4,5-tricarboxybenzoato-κO1)cadmium dihydrate
In the title complex, [Cd(C10H5O8)2(C10H9N5)2(H2O)2]·2H2O, the CdII ion lies on an inversion center and is coordinated by two N atoms from two symmetry-related 1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole ligands and two O atoms from two monodeprotonated 2,4,5-tricarboxybenzoate a...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812000384 |
| _version_ | 1818958592980549632 |
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| author | Lei Zhao Bingtao Liu Guanghua Jin Xiangru Meng |
| author_facet | Lei Zhao Bingtao Liu Guanghua Jin Xiangru Meng |
| author_sort | Lei Zhao |
| collection | DOAJ |
| description | In the title complex, [Cd(C10H5O8)2(C10H9N5)2(H2O)2]·2H2O, the CdII ion lies on an inversion center and is coordinated by two N atoms from two symmetry-related 1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole ligands and two O atoms from two monodeprotonated 2,4,5-tricarboxybenzoate anions in equatorial positions and by two water O atoms in axial positions, leading to a distorted octahedral environment. In the crystal, complex molecules and solvent water molecules are linked through intermolecular O—H...O, O—H...N and N—H...O hydrogen bonds into a three-dimensional network. Intramolecular O—H...O hydrogen bonds are also present. |
| first_indexed | 2024-12-20T11:28:12Z |
| format | Article |
| id | doaj.art-3be3b17a483442cd803baa176ee3285d |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:28:12Z |
| publishDate | 2012-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-3be3b17a483442cd803baa176ee3285d2022-12-21T19:42:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m139m14010.1107/S1600536812000384Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN4}bis(2,4,5-tricarboxybenzoato-κO1)cadmium dihydrateLei ZhaoBingtao LiuGuanghua JinXiangru MengIn the title complex, [Cd(C10H5O8)2(C10H9N5)2(H2O)2]·2H2O, the CdII ion lies on an inversion center and is coordinated by two N atoms from two symmetry-related 1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole ligands and two O atoms from two monodeprotonated 2,4,5-tricarboxybenzoate anions in equatorial positions and by two water O atoms in axial positions, leading to a distorted octahedral environment. In the crystal, complex molecules and solvent water molecules are linked through intermolecular O—H...O, O—H...N and N—H...O hydrogen bonds into a three-dimensional network. Intramolecular O—H...O hydrogen bonds are also present.http://scripts.iucr.org/cgi-bin/paper?S1600536812000384 |
| spellingShingle | Lei Zhao Bingtao Liu Guanghua Jin Xiangru Meng Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN4}bis(2,4,5-tricarboxybenzoato-κO1)cadmium dihydrate Acta Crystallographica Section E |
| title | Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN4}bis(2,4,5-tricarboxybenzoato-κO1)cadmium dihydrate |
| title_full | Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN4}bis(2,4,5-tricarboxybenzoato-κO1)cadmium dihydrate |
| title_fullStr | Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN4}bis(2,4,5-tricarboxybenzoato-κO1)cadmium dihydrate |
| title_full_unstemmed | Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN4}bis(2,4,5-tricarboxybenzoato-κO1)cadmium dihydrate |
| title_short | Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN4}bis(2,4,5-tricarboxybenzoato-κO1)cadmium dihydrate |
| title_sort | diaquabis 1 1h benzimidazol 2 yl methyl 1h 1 2 4 triazole amp 954 n4 bis 2 4 5 tricarboxybenzoato amp 954 o1 cadmium dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812000384 |
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